Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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FDM 3D Printing of Environmental Friendly and High Strength Bio-based PC Filaments for Baby Toys

  • Park, Seong Je (Micro/Nano Scale Manufacturing R&D Group, Korea Institute of Industrial Technology) ;
  • Lee, Ji Eun (Micro/Nano Scale Manufacturing R&D Group, Korea Institute of Industrial Technology) ;
  • Park, Jean Ho (Micro/Nano Scale Manufacturing R&D Group, Korea Institute of Industrial Technology) ;
  • Lyu, Min-Young (Department of Mechanical System Design Engineering, Seoul National University of Science and Technology) ;
  • Park, Keun (Department of Mechanical System Design Engineering, Seoul National University of Science and Technology) ;
  • Koo, Myung Sool (Chemincal Research Center, Samyang Co.) ;
  • Jin, Sun Chul (Chemincal Research Center, Samyang Co.) ;
  • Kim, Ki Yong (Chemincal Research Center, Samyang Co.) ;
  • Son, Yong (Micro/Nano Scale Manufacturing R&D Group, Korea Institute of Industrial Technology)
  • Received : 2017.04.18
  • Accepted : 2017.05.08
  • Published : 2017.06.30
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Abstract

Due to the depletion of fossil oil and the increasing oil price, bio-plastic is currently topical. Bio-based plastics are synthesized from plant resources, unlike conventional petroleum-based counterparts. Therefore, the former minimizes global warming and reduces carbon dioxide emission. Fossil polycarbonate (PC)has good mechanical and optical properties, but its synthesis requires bisphenol-A and phosgene gas, which are toxic to humans. To address these problems, the fused deposition 3D printing process (hereafter, FDM) is studied using environmentally-friendly and high-strength bio-based PC. A comparisonof the environmental impact and tensile strength of fossil PC versus bio-based PC is presented herein, demonstrating that bio-based PC is more environmentally-friendly with higher tensile strength than fossil PC. The advantages of bio-based PC are applied in the FDM process for the fabrication of environmentally-friendly baby toys.

Keywords

References

  1. M.-Y. Lyu and H. Y. Kim, "Introduction to polymer shaping processes and their principles", Polymer Science and Technology, 20, 157 (2009).
  2. D. H. Cho and H. J. Kim, "Naturally cyclable biocomposites", Elastomers and Composites, 44, 13 (2009).
  3. H. Storz and K.-D. Vorlop, "Bio-based plastics: Status, challenges and trends." Landbauforschung Applied Agricultural and Forestry Research, 63, 321 (2013).
  4. S. Khoramnejadian, J. J. Zavareh, and S. Khoramnejadian, "Bio-based plastic a way for reduce municipal solid waste", Procedia Engineering, 21, 489 (2011). https://doi.org/10.1016/j.proeng.2011.11.2042
  5. Y. K. Jung and S. Y. Lee, "Efficient production of polylactic acid and its copolymers by metabolically engineered escherichia coli", Journal of Biotechnology, 151, 94 (2011). https://doi.org/10.1016/j.jbiotec.2010.11.009
  6. W. G. Kim, Y. W. Suh, D. M. Kim, and S. K. Yang, "Recent development of polycarbonate" Polymer Science and Technology, 8, 391 (1997).
  7. S. L. Ma, Y. S. Kim, J. H. Lee, J. S. Kim, I. S. Kim, and J. C. Won, "Synthesis and property of colorless polyimide and its nanocomposite for plastic display substrate", Polymer (Korea), 29, 204 (2005).
  8. C. K. Kim, "Polycarbonate blends and their application", Polymer Science and Technology, 4, 439 (1993). https://doi.org/10.1002/pat.1993.220040707
  9. D. Y. Kwon, J. I. Kim, H. J. Kang, D. Y. Kim, J. H. Kim, B. Lee, and M. S. Kim, "Recent development to generate carbon dioxide-based cyclic carbonate and polycarbonate", Clean Technology, 17, 201 (2011).
  10. M. R. Kim and H. C. Kim, "Analysis of adult behavior to decrease exposure to endocrine in dietary life", Journal of the East Asian Society of Dietory Life, 21, 451 (2011).
  11. T. Setoyama, "The Contribution of catalysis for the realization of GSC in the twenty-first century", Catalysis Surveys from Asia, 18, 183 (2014). https://doi.org/10.1007/s10563-014-9180-0
  12. S. H. Lee, "Prospect for 3D printing technology in medical, dental, and pediatric dental field", Journal of The Korean academy of Pediatric Dentistry, 43, 93 (2016). https://doi.org/10.5933/JKAPD.2016.43.1.93
  13. ASTM F2792-12a: Standard Terminology for Additive Manufacturing Technologies
  14. S. Kumar and J.-P. Kruth, "Composites by rapid prototyping technology", Material and Design, 31, 850 (2010). https://doi.org/10.1016/j.matdes.2009.07.045
  15. S. J Park, J. H. Park, K. H. Lee, and M.-Y. Lyu, "Deposition strength of specimens manufactured using fused deposition modeling type 3D printer", Polymer (Korea), 40, 846 (2016). https://doi.org/10.7317/pk.2016.40.6.846
  16. J.-G. Kang, J.-I. Son, J.-S. Min, M.-J. Jang, Y. H. Kwon, H.-N. Yoo, Y.-J. Ko, J.-H. Kwon, T.-W. Jeon, and S.-K. Shin, "Analyzing methods for biomass content in the solid/gas phase", Journal of Korea Society of Waste Management, 33, 810 (2016). https://doi.org/10.9786/kswm.2016.33.8.810
  17. ASTM D6866-16 Method B: Standard Test Methods for Determining the Biobased content of Solid, Liquid and Gaseous Samples Using Radiocarbon Analysis.
  18. S. A. Park, J. H. Choi, S. B. Ju, J. G. Jegal, K. M. Lee, S. Y. Hwang, D. Y. X. Oh, and J. Y. Park, "Copolycarbonates of bio-based rigid isosorbide and flexible 1,4-cyclohexanedimethanol: Merits over bisphenol-A based polycarbonates, Polymer, 116, 153 (2017). https://doi.org/10.1016/j.polymer.2017.03.077
  19. F. Fenouillot, A. Rousseau, G. Colomines, R. S.-Loup, and J.-P. Pascault, "Polymers from renewable 1,4:3,6-dianhydrohexitols (isosorbide, isomannide and isoidide): A review", Progress in Polymer Science, 35, 578 (2010). https://doi.org/10.1016/j.progpolymsci.2009.10.001
  20. B. Jarzabek, E. S. Balcerzak, T. Chamenko, D. Sek, J. Cisowski, and A. Volozhin, "Optical properties of new aliphaticaromatic co-polyimides", Journal of Non-Crystalline Solids, 299, 1057 (2002).
  21. Q. Sun, G. M. Rizvi, C. T. Bellehumeur, and P. Gu, "Effect of processing conditions on the bonding quality of FDM polymer filaments", Rapid Prototyping Journal, 14, 72 (2008). https://doi.org/10.1108/13552540810862028
  22. S. J. Park, J. H. Park, M.-Y. Lyu, M. S. Koo, H. J. Rho, and S. H. Cho, "Comparison of bulk strength, weldline strength, and deposition strength of 3D printing-manufactured article in fossil PCs and bio-based PCs", Polymer (Korea), 41, 531 (2017). https://doi.org/10.7317/pk.2017.41.3.531