Composites Research

  • 제30권3호
  • /
  • Pages.193-201
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  • 2017
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  • 2288-2103(pISSN)
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  • 2288-2111(eISSN)
한국복합재료학회 (The Korean Society for Composite Materials)
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탄소나노튜브/폴리에스터 복합재의 역학적 거동과 하중전달에 관한 분자 동역학 전산모사 : 그래프팅 가공의 영향

Molecular Dynamics Study on Mechanical Behavior and Load Transfer of CNT/PET Nanocomposites : the Effects of Covalent Grafting

  • Jin, Juho (School of Energy Systems Engineering, Chung-Ang University) ;
  • Yang, Seunghwa (School of Energy Systems Engineering, Chung-Ang University)
  • 투고 : 2017.04.03
  • 심사 : 2017.06.30
  • 발행 : 2017.06.30
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초록

탄소나노튜브와 폴리에스터 계면 간 그래프팅이 나노복합재의 역학적 거동과 하중전달에 미치는 영향을 고찰하기 위해 분자동역학 전산모사를 수행하고 그 결과를 Mori-Tanaka 모델 예측해와 비교하였다. 각 방향으로의 인장과 전단 전산모사를 통해 응력-변형률 선도를 도출한 후, 가교 유무에 따른 탄성거동 변화를 관찰하였다. 또한 가로등방성 강성행렬을 방향 평균하여 나노튜브가 랜덤분포하는 경우의 등방성 영률과 전단계수를 구하였다. 그 결과 가로방향 영률과 전단계수는 그래프팅 가공에 의해 향상되었으나, 길이방향 영률의 경우 나노튜브의 물성감소로 인해 오히려 물성이 저하되었다. 나노튜브의 랜덤분포를 고려한 예측 결과에서는 그래프팅 가공에 의해 물성이 약간 감소하였다.

Molecular dynamics simulation and the Mori-Tanaka micromechanics study are performed to investigate the effect of the covalent grafting between CNT and polyester on the mechanical behavior and load transfer of nanocomposites. The transversely isotropic stress-strain curves are determined through the tension and shear simulations according to the covalent grafting. Also, isotropic properties of randomly dispersed nanocomposites are obtained by orientation averaging the transversely isotropic stiffness matrix. By addressing the grafting, the transverse Young's modulus and shear moduli of the nanocomposites are improved, while the longitudinal Young's modulus decreases due to the degradation of the grafted CNT.

키워드

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