반도체디스플레이기술학회지 (Journal of the Semiconductor & Display Technology)

한국반도체디스플레이기술학회 (The Korean Society Of Semiconductor & Display Technology)
권호 표지

플라스틱 디스플레이 기판용UV 하드 코팅 용액의 합성

Synthesis of Hard Coating Solution for Plastic Display Plate

  • 백성균 (한국기술교육대학교 응용화학공학부) ;
  • 장선호 (한국기술교육대학교 응용화학공학부) ;
  • 조을룡 (한국기술교육대학교 응용화학공학부)
  • Back, Sung Kyun (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Jang, Sun Ho (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Cho, Ur Ryong (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education)
  • 투고 : 2017.03.11
  • 심사 : 2017.03.26
  • 발행 : 2017.03.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Poly(urethane acrylate) siloxane oligomers with Interpenetrating polymer netwoked nanoparticles were prepared to synthesize hard coating solution by reaction with diisocyanates. The diisocyanate combined siloxane hard coating solution showed more flexibility than the siloxane solution. In addition, diisocyanate resulted in improvement of curl property and surface hardness in the siloxane solution. Of the used diisocyanates, isophorone diisocyanate and acryloyloxy ethyl diisocyanate were good for UV hard coating solution. This effect will decrease brittleness in the siloxane solution using for plastic display plate.

키워드

참고문헌

  1. H. S. Do, Y. J. Park, S. M. Kim and H. J. Kim, "Technological Status of Environmental-Friendly Adhesion and Pressure Sensitive Adhesive", Korean Industrial and Engineering Chemistry, Vol.7, No.4, pp.14-32, 2004.
  2. R. E. knight, "Chemistry & Technology of UV &EB Formulation For Coating", Inks & Paints, Vol.1, pp.162-164, 1991.
  3. J. W. Yu and D. S. Kim, "UV Curing and Mechanical Properties of Urethan-Acrylate Resins", Polymer(Korea, Vol.23, No. 3, pp.376-383, 1999.
  4. M. Woutens, D. Wolfs, M Van der linde, J. Hovens, and A. Tinnemans, "Synthesis of a latex with bimodal particle size distribution for coating application using acrylic monomers", Prog. Org. Coat., Vol.51, pp.312-319, 2004. https://doi.org/10.1016/j.porgcoat.2004.07.020
  5. Y. Y. Yu and W.C. Chen, "Transparent organic-inorganic hybrid thin films prepared from acrylic polymer and aqueous monodispersed colloidal silica", Mater. Chem. & Phys., Vol.82, pp.388-395, 2003. https://doi.org/10.1016/S0254-0584(03)00259-1
  6. D. P. Kang, H. Y. Park, M. S. Ahn, and I. H. Myung, "Properties of Sol-Gel Materials Synthesized from Colloidal Silica and Alkoxy Silanes", Polymer(Korea), Vol.29, pp.242-247, 2005.
  7. Soppera, C. Croutxe-barghorn, "Real-time fourier transform infrared study of the free radical ultravioletinduced polymerization of a bybrid sol-gel", J. Polym Sci., Vol.41, pp.831-840, 2002.
  8. H. Schmidt, "Multifunctional inorganic-organic composite sol-gel coatings for glass surfaces", J. Non-Crystalline Solid, Vol.178, pp.302-312, 1994. https://doi.org/10.1016/0022-3093(94)90299-2
  9. J. V. Crivello and Z. Mao, "Preparation and Cationic Photopolymerization of Organic−Inorganic Hybrid Matrixes", Chem. Mater.,Vol. 9, pp.1562-1569, 1997. https://doi.org/10.1021/cm960595q
  10. J. Chen, R. Chareonsak, V. Puengpipat, and S. Marturunkal, "Organic/inorganic Composite Materials for Coating Applications", J. Appl. Polym. Sci., Vol.74, pp.1341-1345, 1999. https://doi.org/10.1002/(SICI)1097-4628(19991107)74:6<1341::AID-APP3>3.0.CO;2-4
  11. E. Rubio, J. Almaral, R. Ramirez-Bon, V. Castano, and V. Rodriguez, "Organic-inorganic Hybrid Coating (poly(methyl methacrylate)/monodisperse silica)", Opt. Mater., Vol.27, pp.1266-1269, 2005. https://doi.org/10.1016/j.optmat.2004.11.022
  12. J. M Urreaga, M. C. Matias, V. Lorenzo, and M. U. de la Orden, "Abrasion Resistance in the Tumble Test of sol-gel Hybrid Coatings for Ophthalmic Plastic lenses", Mater. Lett., Vol.45, pp.293-297, 2000. https://doi.org/10.1016/S0167-577X(00)00120-8
  13. D. H. Kim and D. W. Lee, "Scratch Resistant and Transparent UV-Protective Coating on Polycarbonate", J. Sol-Gel Sci. Tech., Vol.26, pp.783-787, 2003. https://doi.org/10.1023/A:1020774927773
  14. U. R. Cho, J. H. Oh, and H. J. Jung, "A Study on the synthesis and Properties of Environmental Friendly Pressure Sensitive Adhesive for Manufacturing Electronic Products", Journal of the Semiconductor & Display Technology., Vol.15, pp.12-15, 2016.
  15. M. S. Kim, and U. R. Cho, "A Study on pattern Formation of Ultra Definition Display Panel Applying Phosphoric Acid", Journal of the Semiconductor & Display Technology., Vol.13, pp. 13-15, 2014.