DOI QR코드

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Evaluation of refused tea waste activated carbon for color removal: Equilibrium and kinetic studies

  • 투고 : 2016.03.26
  • 심사 : 2017.02.24
  • 발행 : 2017.03.25

초록

New technologies or improvement of the existing technologies are required to enhance the efficiency of removal of pollutants from wastewater. In this study we attempted to produce and test the activated carbon produced from the refused tea waste for the removal of dyes from wastewater. The objectives of this investigation were to produce activated carbon from refused tea waste by chemical activation, evaluate its performance for the removal of color produced from Acid Yellow 36, and the modeling of its dye removal with the kinetic study. The activation was performed in two steps namely carbonization at $375{\pm}25^{\circ}C$ and chemical activation with HCl at $800^{\circ}C$ under the absence of Oxygen. Adsorption isotherms and kinetic studies were performed with a textile dye, Acid Yellow 36, at different concentrations (20-80 mg/L). The maximum dye removal (~90%) observed at 80 mg/L dye concentration and it reduced at low dye concentrations. Maximum adsorption (71.97 mg/g) was recorded at 96 h at $29{\pm}1^{\circ}C$. Low pH increased the dye adsorption (pH=2; 78.27 mg/g) while adsorption reduced at high pH levels indicating that the competition occurs in between OH- ions and AY36 molecules for the adsorption sites in RTAC. The Langmuir isotherm model clearly explained the dye adsorption, favorably, by RTAC. Moreover, kinetic studied performed showed that the pseudo second order kinetic model clearly describes the dye adsorption. Based on the results obtained in this study, it can be concluded that RTAC can be used for the removal of textile dyes.

키워드

참고문헌

  1. AL-Aoh, H.A.R., Yahya, M.J.M. and Abas, M.R.B. (2013), "Adsorption of methylene blue on activated carbon fiber prepared from coconut husk: Isotherm, kinetics and thermodynamics studies", Desal. Wat. Treat., 52(34-36), 6720-6732.
  2. Aljeboree, A.M., Alkaim, A.F. and Al-Dujaili, A.H. (2014), "Adsorption isotherm, kinetic modeling and thermodynamics of crystal violet dye on coconut husk-based activated carbon", Desal. Wat. Treat., 53(13), 3656-3667. https://doi.org/10.1080/19443994.2013.877854
  3. Angin, D. (2014), "Utilization of activated carbon produced from fruit juice industry solid waste for the adsorption of yellow 18 from aqueous solutions", Biores. Technol., 168, 259-266. https://doi.org/10.1016/j.biortech.2014.02.100
  4. APHA (1995), Standard Methods for the Examination of Water and Wastewater, Washington, U.S.A.
  5. Attia, H.G. (2012), "A comparison between cooking tea-waste and commercial activated carbon for removal of chromium from artificial wastewater", J. Eng. Develop., 16, 307-325.
  6. Auta, M. (2012), "Batch adsorption of reactive red 120 from waste waters using activated carbon from waste tea", J. Adv. Eng. Technol., 3, 24-28.
  7. Ayanda, O.S., Fatoki, O.S., Adekola, F.A., Ximba, B.J. and Petrik, L.F. (2015), "Kinetics, isotherm and thermodynamics of tributyltin removal by adsorption onto activated carbon, silica and composite material of silica and activated carbon", Desal. Water Treat., 53(5), 1361-1370.
  8. Bansal, R.C. and Goyal, M. (2005), Activated Carbon Adsorption, CRC Press, Taylor & Francis Group.
  9. Baseri, J.R., Palanisamy, P.N. and Sivakumar, P. (2012), "Adsorption of reactive dye by a novel activated carbon prepared from Thevetia Peruviana", J. Chem. Res., 3(2), 36-41.
  10. Behnamfard, A. and Salarirad, M.M. (2013), "Characterization of coconut shell-based activated carbon and its application in the removal of Zn(II) from its aqueous solution by adsorption", Desal. Wat. Treat., 52(37-39), 7180-7195.
  11. Chen, Y., Zhai, S.R., Liu, N., Song, Y., An, Q.D. and Song, X.W. (2013), "Dye removal of activated carbons prepared from NaOH-pretreated rice husks by low-temperature solution-processed carbonization and H3PO4 activation", Biores. Technol., 144, 401-409. https://doi.org/10.1016/j.biortech.2013.07.002
  12. Cheraghi, M., Lorestani, B., Merrikhpour, H. and Mosaed, H.P. (2013), "Assessment efficiency of tea wastes in arsenic removal from aqueous solution", Desal. Wat. Treat., 52(37-39), 7235-7240.
  13. Demiral, H., Demiral, I., Karabacakoglu, B. and Tumsek, F. (2008), "Adsorption of textile dye onto activated carbon prepared from industrial waste by ZnCl activation", J. Environ. Appl. Sci., 3(3), 381-389.
  14. Figueiredo, J.L., Pereira, M.F.R., Freitas, M.M.A. and Orfao, J.J.M. (1999), "Modification of the surface chemistry of activated carbons", Carbon, 37(9), 1379-1389. https://doi.org/10.1016/S0008-6223(98)00333-9
  15. Foo, K.Y. and Hameed, B.H. (2010), "An overview of dye removal via activated carbon adsorption process", Desal. Wat. Treat., 19(1-3), 255-274. https://doi.org/10.5004/dwt.2010.1214
  16. Garg, V.K., Gupta, R., Yadav, A.B. and Kumar, R. (2003), "Dye removal from aqueous solution by adsorption on treated sawdust", Biores. Technol., 89(2), 121-124. https://doi.org/10.1016/S0960-8524(03)00058-0
  17. Gercel, O. and Gercel, H.F. (2009), "Removal of acid dyes from aqueous solutions using chemically activated carbon", Separ. Sci. Technol., 44(9), 2078-2095. https://doi.org/10.1080/01496390902885338
  18. Hameed, B.H., Din, A.T.M. and Ahmad, A.L. (2007), "Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies", J. Hazard. Mater., 141(3), 819-825. https://doi.org/10.1016/j.jhazmat.2006.07.049
  19. Ho, Y.S. and McKay, G. (1999), "The sorption of lead(II) ions on peat", Wat. Res., 33(2), 578-584. https://doi.org/10.1016/S0043-1354(98)00207-3
  20. Ioannidou, O. and Zabaniotou, A. (2007), "Agricultural residues as precursors for activated carbon production-A review", Renew. Sustain. Energy Rev., 11(9), 1966-2005. https://doi.org/10.1016/j.rser.2006.03.013
  21. Kadirvelu, K., Kavipriya, M., Karthika, C., Radhika, M., Vennilamani, N. and Pattabhi, S. (2003), "Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions", Biores. Technol., 87(1), 129-132. https://doi.org/10.1016/S0960-8524(02)00201-8
  22. Khalaf, H.A. (2013), "Batch and fixed-bed study for basic blue 9 separations using synthetic activated carbon", Separ. Sci. Technol., 49(4), 523-532. https://doi.org/10.1080/01496395.2013.853084
  23. Khosla, E., Kaur, S. and Dave, P.N. (2013), "Tea waste as adsorbent for ionic dyes", Desal. Wat. Treat., 51(34-36), 6552-6561. https://doi.org/10.1080/19443994.2013.791776
  24. Kunwar, P., Singh, D.M., Sarita, S., Tondon, G.S. and Devlina, G. (2003), "Color removal from wastewater using low-cost activated carbon derived from agricultural waste material", Ind. Eng. Chem. Res., 42(9), 1965-1976. https://doi.org/10.1021/ie020800d
  25. Lin, L., Zhai, S.R., Xiao, Z.Y., Song, Y., An, Q.D. and Song, X.Y. (2013), "Dye adsorption of mesoporous activated carbons produced from NaOH-pretreated rice husks", Biores. Technol., 136, 437-443. https://doi.org/10.1016/j.biortech.2013.03.048
  26. Maiti, S., Purakayastha, S. and Ghosh, B. (2007), "Production of low-cost carbon adsorbents from agricultural wastes and their impact on dye adsorption", Chem. Eng. Commun., 195(4), 386-403. https://doi.org/10.1080/00986440701707917
  27. Malkoc, E. and Nuhoglu, Y. (2007), "Potential of tea factory waste for chromium(VI) removal from aqueous solutions: Thermodynamic and kinetic studies", Separ. Purific. Technol., 54(3), 291-298. https://doi.org/10.1016/j.seppur.2006.09.017
  28. Ozbas, E.E., O ngen, A. and Gokce, C.E. (2013), "Removal of astrazon red 6B from aqueous solution using waste tea and spent tea bag", Desal. Wat. Treat., 51(40-42), 7523-7535. https://doi.org/10.1080/19443994.2013.792161
  29. Ozer, C., Imamoglu, M., Turhan, Y. and Boysan, F. (2012), "Removal of methylene blue from aqueous solutions using phosphoric acid activated carbon produced from hazelnut husks", Toxicol. Environ. Chem., 94(7), 1283-1293. https://doi.org/10.1080/02772248.2012.707656
  30. Pepper, I.L., Gerba, C.P. and Brusseau, M.L. (2006), Environmental and Pollution Science, U.S.A., U.K.
  31. Phana, N.H., Riob, S., Faurd, C., Coqb, L.L., Cloirecb, P.L. and Nguyena, T.H. (2006), "Production of fibrous activated carbons from natural cellulose (jute, coconut) fibers for water treatment applications", Carbon, 44(12), 2569-2577. https://doi.org/10.1016/j.carbon.2006.05.048
  32. Reddy, K.S.K., Rashid, K., Shoaibi, A.A. and Srinivasakannan, C. (2013), "Production and characterization of porous carbon from date palm seeds by chemical activation with H3PO4: Process optimization for maximizing adsorption of methylene blue", Chem. Eng. Commun., 201(8), 1021-1040. https://doi.org/10.1080/00986445.2013.797896
  33. Saib, N.B., Mekarzia, A., Bouzid, B., Mohammedi, O., Khelifa, A., Benrachedi, K. and Belhaneche, N. (2013), "Removal of malathion from polluted water by adsorption onto chemically activated carbons produced from coffee grounds", Desal. Wat. Treat., 52(25-27), 4920-4927.
  34. Santra, A.K., Pal, T.K. and Datta, S. (2008), "Removal of metanil yellow from its aqueous solution by fly ash and activated carbon produced from different sources", Separ. Sci. Technol., 43(6), 1434-1458. https://doi.org/10.1080/01496390701885729
  35. Senaratna, D., Atapattu, N.S.B.M. and Belpagodagamage, D.U. (2007), "Saw dust and refuse tea as alternative litter materials from broilers", Tropic. Agricult. Res., 19, 283-289.
  36. Senthilkumaar, S., Kalaamani, P., Porkodi, K., Varadarajan, P.R. and Subburaam, C.V. (2006), "Adsorption of dissolved reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste", Biores. Technol., 97(14), 1618-1625. https://doi.org/10.1016/j.biortech.2005.08.001
  37. Singh, K.P., Mohan, D., Sinha, S., Tondon, G.S. and Gosh, D. (2003), "Color removal from wastewater using low-cost activated carbon derived from agricultural waste material", Ind. Eng. Chem. Res., 42(9), 1965-1976. https://doi.org/10.1021/ie020800d
  38. Tee, T.W. and Khan, A.R.M. (1988), "Removal of lead, cadmium and zinc by waste tea leaves", Environ. Technol. Lett., 9(11), 1223-1232. https://doi.org/10.1080/09593338809384685
  39. TMAC (1986), Test Methods for Activated Carbon, European Council of Chemical Manufacturer's Federations.
  40. Tofighy, M.A. and Mohammadi, T. (2013), "Methylene blue adsorption onto granular activated carbon prepared from harmal seeds residue", Desal. Wat. Treat., 52(13-15), 2643-2653.
  41. Tsai, W.T., Chang, C.Y., Lin, M.C., Chien, S.F., Sun, H.F. and Hsieh, M.F. (2001), "Characterization of activated carbons prepared from sugarcane bagasse by ZnCl2 activation", J. Environ. Sci. Health, Part B: Pestic. Food Contamin. Agricult. Was., 36(3), 365-378. https://doi.org/10.1081/PFC-100103576
  42. Uzun, B.B., Apaydin-Varol, E., Ates, F., O zbay. N. and Putun, A.E. (2010), "Synthetic fuel production from tea waste: Characterisation of bio-oil and bio-char", Fuel, 89(1), 176-184. https://doi.org/10.1016/j.fuel.2009.08.040
  43. Zhang, W., Li, H., Kan, X., Dong, L., Yan, H., Jiang, Z., Yang, H., Li, A. and Cheng, R. (2012), "Adsorption of anionic dyes from aqueous solutions using chemically modified straw", Biores. Technol., 117, 40-47. https://doi.org/10.1016/j.biortech.2012.04.064
  44. Zuorro, A. and Lavecchia, R. (2010), "Adsorption of Pb(II) on spent leaves of green and black tea", Am. J. Appl. Sci., 7(2), 153-159. https://doi.org/10.3844/ajassp.2010.153.159

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