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A Study on the Adhesion Properties of the Polyurethane Resin and Polyketone Fabrics with MDI Treatment Conditions

MDI 처리 조건에 따른 폴리우레탄 수지와 폴리케톤 직물 사이의 접착특성에 관한 연구

  • Jo, Hani (Department of Organic Materials Engineering, Chungnam National University) ;
  • Yang, Jee-Woo (Department of Organic Materials Engineering, Chungnam National University) ;
  • Lim, Hyeon Soo (Department of Organic Materials Engineering, Chungnam National University) ;
  • Lee, Seung Goo (Department of Organic Materials Engineering, Chungnam National University)
  • 조하니 (충남대학교 공과대학 유기재료공학과) ;
  • 양지우 (충남대학교 공과대학 유기재료공학과) ;
  • 임현수 (충남대학교 공과대학 유기재료공학과) ;
  • 이승구 (충남대학교 공과대학 유기재료공학과)
  • Received : 2017.03.02
  • Accepted : 2017.04.17
  • Published : 2017.04.30

Abstract

Recently developed POK fibers are eco-friendly and economical material compared with other industrial fibers. POK fabric can be applied to awning materials because of its excellent mechanical properties and chemical resistance. In this study, the adhesive strength between polyketone (POK) fabric and polyurethane (PU) resin was investigated by treatment with MDI (methylene diphenyl diisocyanate) which acts as a chain extender on the fabric surface. The MDI treatment conditions of the POK fabric to improve the adhesion of the PU resin were investigated in terms of the amount of materials used and the heat treatment temperature. The changes in chemical structure were analyzed by FTIR. The microstructures of MDI-treated fiber surfaces and fractured surface were observed by FE-SEM. The surface free energy was calculated using contact angles measured with a sessile drop method. The adhesive strength was also analyzed by the T-peel test. Conclusively, by treating the isocyanate groups on the surface of the POK fabric, the bond strength between the POK fabric and the PU resin was more than doubled.

Keywords

References

  1. N. S. Murthy, H. Minor, and R. A. Latif, "Effect of Annealing on the Structure and Morphology of Nylon 6 Fibers", J. Macromol. Sci., Part B: Phys., 1987, 26, 427-446. https://doi.org/10.1080/00222348708223946
  2. D. G. Oriani, L. Alberto, and A. L. Simal, "Structure of Heat- Treated Nylon 6 Fibers, 1: Application of the Arrhenius Equation", J. Appl. Polym. Sci., 1992, 46, 1973-1985. https://doi.org/10.1002/app.1992.070461110
  3. S. R. Wu, G. S. Sheu, and S. S. Shyu, "Kevlar Fibre-Epoxy Adhesion and Its Effect on Composite Mechanical and Fracture Properties by Plasma and Chemical Treatment", J. Appl. Polym. Sci., 1996, 62, 1347-1360. https://doi.org/10.1002/(SICI)1097-4628(19961128)62:9<1347::AID-APP5>3.0.CO;2-H
  4. G. Reinert, F. Fuso, R. Hilfiker, and E. Schmidt, "UV-Protecting Properties of Textile Fabrics and their Improvement", Textile Chemist & Colorist, 1997, 29, 36-43.
  5. N. Morimura and M. Ojima, American Dyestuff Reporter, 1985, 74, 28-36.
  6. P. Lekpittaya, N. Yanumet, B. P. Grady, and E. A. O'Rear, "Resistivity of Conductive Polymer-coated Fabric", J. Appl. Polym. Sci., 2004, 92, 2629-2636. https://doi.org/10.1002/app.20270
  7. R. L. Danforth, J. M. Machado, and J. C. M. Jordaan, "Aliphatic Polyketones: A New Family of Engineering Thermoplastics", Plast. Eng., 1996, 52, 77-79.
  8. Y. Chatani, T. Takizawa, S. Murahashi, Y. Sakata, and Y. Nishimura, "Crystal Structure of Polyketone (1:1 Ethylene/ Carbon Monoxide Copolymer)", J. Polym. Sci., 1961, 55, 811-819. https://doi.org/10.1002/pol.1961.1205516233
  9. E. Marklund, U. W. Geddea, M. S. Hedenqvist, and G. Wiberg, "Properties of Polyketone/Polypropylene Blends", Polymer, 2001, 42, 3153-3160. https://doi.org/10.1016/S0032-3861(00)00605-4
  10. O. Ohsawa, K. H. Lee, B. S. Kim, S. Lee, and I. S. Kim, "Preparation and Characterization of Polyketone(PK) Fibrous Membrane via Electrospinning", Polymer, 2010, 51, 2007-2012. https://doi.org/10.1016/j.polymer.2010.02.045
  11. E. Almansa, S. Heumann, A. Eberl, G. Fischer-Colbrie, L. Martinkova, J. Marek, and G. M. Guebitz, "Enzymatic Surface Hydrolysis of PET Enhances Bonding in PVC Coating", Biocatalysis and Biotransformation, 2008, 26, 365-370. https://doi.org/10.1080/10242420802357613
  12. S. Chen, X. Ding, and H. Yi, "On the Anisotropic Tensile Behaviors of Flexible Polyvinyl Chloride-Coated Fabrics", Text. Res. J., 2007, 77, 369-374. https://doi.org/10.1177/0040517507078791
  13. G. Akovali, Ed., "Advances in Polymer Coated Textiles", Smithers Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire, SY4 4NR, United Kingdom, 2012, 1, pp.22-23.
  14. R. R. Grant, "Coating Techniques for the Manufacture of Continuous Web Products", J. Coated Fabrics, 1978, 8, 171-182. https://doi.org/10.1177/152808377800800205
  15. P. Katangur, P. K. Patra, and S. B. Warner, "Nanostructured Ultraviolet Resistant Polymer Coatings", Polym. Degrad. Stabil., 2006, 91, 2437-2442. https://doi.org/10.1016/j.polymdegradstab.2006.03.018
  16. N. Kobayashi, "Life Support of Artificial Liver: Development of a Bioartificial Liver to Treat Liver Failure", Journal of Hepato- Biliary-Pancreatic Surgery, 2009, 16, 113-117. https://doi.org/10.1007/s00534-008-0022-1
  17. D. K. Chattopadhyay and K. V. S. N. Raju, "Structural Engineering of Polyurethane Coatings for High Performance Applications", Prog. Polym. Sci., 2007, 32, 352-418. https://doi.org/10.1016/j.progpolymsci.2006.05.003
  18. X. D. Liu, D. K. Sheng, X. M. Gao, T. B. Li, and Y. M. Yang, "UV-assisted Surface Modification of PET Fiber for Adhesion Improvement", Appl. Surface Sci., 2013, 264, 61-69. https://doi.org/10.1016/j.apsusc.2012.09.107
  19. D. Hegemann, H. Brunner, and C. Oehr, "Plasma Treatment of Polymers for Surface and Adhesion Improvement", Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2003, 208, 281-286. https://doi.org/10.1016/S0168-583X(03)00644-X
  20. E. M. Liston, L. Martinu, and M. R. Wertheimer, "Plasma Surface Modification of Polymers for Improved Adhesion: a Critical Review", J. Adhesion Sci. Technol., 1993, 7, 1091-1127. https://doi.org/10.1163/156856193X00600
  21. C. Baley, F. Busnel, Y. Grohens, and O. Sire, "Influence of Chemical Treatments on Surface Properties and Adhesion of Flax Fibre-Polyester Resin", Compos. Part A: Appl. Sci. Manuf., 2006, 37, 1626-1637. https://doi.org/10.1016/j.compositesa.2005.10.014
  22. B. Park and K. Koo, "Properties of Silicone-coated Fabric for Membrane Treated by Oxygen Low Temperature Plasma", Textile Coloration and Finishing, 2011, 23, 195-200. https://doi.org/10.5764/TCF.2011.23.3.195
  23. R. P. Woodward, "Prediction of Adhesion and Wetting from Lewis Acid Base Measurements", TPOs in Automotive, 2000, pp.1-6.
  24. D. Y. Kwok and A. W. Neumann, "Contact Angle Measurement and Contact Angle Interpretation", Adv. Colloid. Interface Sci., 1999, 81, 167-249. https://doi.org/10.1016/S0001-8686(98)00087-6