한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제33권2호
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  • Pages.124-138
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  • 2017
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  • 1598-7132(pISSN)
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  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
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한반도 서부유입권역에서 대기 중 에어로졸 성분의 물리·화학적 특성 연구 III. 화학적 거동 및 장거리 이동

Physico-chemical Characteristics of Submicron Aerosol at West Inflow Regions in the Korean Peninsula III. Physical-Chemical Behavior and Long-range Transport of PM1

  • 박태현 (한국외국어대학교 환경학과) ;
  • 안준영 (국립환경과학원 대기환경연구과) ;
  • 최진수 (국립환경과학원 대기환경연구과) ;
  • 임용재 (국립환경과학원 대기질통합예보센터) ;
  • 박진수 (국립환경과학원 대기환경연구과) ;
  • 김정호 (에이피엠 엔지니어링(주)) ;
  • 오준 (국립환경과학원 대기환경연구과) ;
  • 이용환 (한국외국어대학교 환경학과) ;
  • 홍유덕 (국립환경과학원 대기환경연구과) ;
  • 홍지형 (국립환경과학원 대기환경연구과) ;
  • 최용주 (한국외국어대학교 환경학과) ;
  • 이태형 (한국외국어대학교 환경학과)
  • Park, Taehyun (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Ahn, Junyoung (Air Quality Research Division, National Institute of Environmental Research) ;
  • Choi, Jinsoo (Air Quality Research Division, National Institute of Environmental Research) ;
  • Lim, Yongjae (Air Quality Forecasting Division, National Institute of Environmental Research) ;
  • Park, Jinsoo (Air Quality Research Division, National Institute of Environmental Research) ;
  • Kim, Jeongho (APM Engineering Co., Ltd.) ;
  • Oh, Jun (Air Quality Research Division, National Institute of Environmental Research) ;
  • Lee, Yonghwan (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Hong, Youdeog (Air Quality Research Division, National Institute of Environmental Research) ;
  • Hong, Jihyung (Air Quality Research Division, National Institute of Environmental Research) ;
  • Choi, Yongjoo (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Lee, Taehyoung (Department of Environmental Science, Hankuk University of Foreign Studies)
  • 투고 : 2017.02.01
  • 심사 : 2017.03.09
  • 발행 : 2017.04.30
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초록

Physico-chemical measurement of non-refractory submicron particles($NR-PM_1$) was conducted in Baengnyeong Island, Korea using Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) from 2012 to 2014. Organics and ammoniated sulfate were dominant species in $NR-PM_1$. The organics was found to have similar fractions(approximate 40%) of $NR-PM_1$ during the summer and winter, while the sulfate fractions of $NR-PM_1$ were calculated to be approximately 47% and 31% for the summer and winter, respectively, suggesting the possibility that particles provide non-acidic surfaces for condensation of nitric acid in the winter. The nitrate fractions of approximate 4% and 20% of $NR-PM_1$ were observed in August (summer) and November (winter), respectively, resulting that the relatively low concentration of sulfate in $NR-PM_1$ provided a non-acidic surface for nitric acid condensation and formation of particulate ammoniated nitrate is favored thermodynamically in winter. The new particle formation (NPF) event and particle growth rate were analyzed for each month in 2014 using Scanning Mobility Particle Sizer(SMPS). The Percent of NPF events was the highest in winter, but NPF event was not observed during summer due to relatively high temperature and frequent rainfall. The average particle growth rate was 3.5 nm/h and the highest particle growth rate was 5.5 nm/h in May. We observed the long-range transport of the anthropogenic sulfate from the East Asia during the intensive monitoring period of November between Qingdao and Baengnyeong Island in 2013. The relatively high concentrations of m/z 60 measured in HR-ToF-AMS was observed in May and June at Baengnyeong Island, suggesting the possibility of the influence of biomass burning from the East Asia to the Korean Peninsula.

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피인용 문헌

  1. Spacial Distribution of PM1.0 Major Compounds from Long Range Transport at the Baegryungdo Super Site: Relationship between PSCF and Cluster Analysis vol.33, pp.4, 2017, https://doi.org/10.5572/KOSAE.2017.33.4.411