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Quantitative Approaches for the Determination of Volatile Organic Compounds (VOC) and Its Performance Assessment in Terms of Solvent Types and the Related Matrix Effects

  • Ullah, Md. Ahsan (Department of Civil & Environmental Engineering, Hanyang University) ;
  • Kim, Ki-Hyun (Department of Civil & Environmental Engineering, Hanyang University) ;
  • Szulejko, Jan E. (Department of Civil & Environmental Engineering, Hanyang University) ;
  • Choi, Dal Woong (Department of Public Health Science, Korea University)
  • 투고 : 2016.07.03
  • 심사 : 2016.12.07
  • 발행 : 2017.03.31

초록

For the quantitative analysis of volatile organic compounds (VOC), the use of a proper solvent is crucial to reduce the chance of biased results or effect of interference either in direct analysis by a gas chromatograph (GC) or with thermal desorption analysis due to matrix effects, e.g., the existence of a broad solvent peak tailing that overlaps early eluters. In this work, the relative performance of different solvents has been evaluated using standards containing 19 VOCs in three different solvents (methanol, pentane, and hexane). Comparison of the response factor of the detected VOCs confirms their means for methanol and hexane higher than that of pentane by 84% and 27%, respectively. In light of the solvent vapor pressure at the initial GC column temperature ($35^{\circ}C$), the enhanced sensitivity in methanol suggests the potential role of solvent vapor expansion in the hot injector (split ON) which leads to solvent trapping on the column. In contrast, if the recurrent relationships between homologues were evaluated using an effective carbon number (ECN) additivity approach, the comparability assessed in terms of percent difference improved on the order of methanol (26.5%), hexane (6.73%), and pentane (5.24%). As such, the relative performance of GC can be affected considerably in the direct injection-based analysis of VOC due to the selection of solvent.

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참고문헌

  1. Ahn, J.-W., Pandey, S.K., Kim, K.-H. (2011) Comparison of GC-MS calibration properties of volatile organic compounds and relative quantification without calibration standards. Journal of Chromatographic Science 49, 19-28. https://doi.org/10.1093/chrsci/49.1.19
  2. Beauchamp, R.O., Bus, J.S., Popp, J.A., Boreiko, C.J., Goldberg, L., McKenna, M.J. (1983) A Critical Review of the Literature on Carbon Disulfide Toxicity. Critical Reviews in Toxicology 11(3), 169-278. https://doi.org/10.3109/10408448309128255
  3. Binder, R.G., Flath, R.A., Mon, T.R. (1989) Volatile components of bittermelon. Journal of Agricultural and Food Chemistry 37, 418-420. https://doi.org/10.1021/jf00086a032
  4. Binder, R.G., Turner, C.E., Flath, R.A. (1990) Volatile components of purple starthistle. Journal of Agricultural and Food Chemistry 38, 1053-1055. https://doi.org/10.1021/jf00094a030
  5. Boeglin, M.L., Wessels, D., Henshel, D. (2006) An investigation of the relationship between air emissions of volatile organic compounds and the incidence of cancer in Indiana counties. Environmental Research 100, 242-254. https://doi.org/10.1016/j.envres.2005.04.004
  6. Cavalcante, R.M., de Andrade, M.V.F., Marins, R.V., Oliveira, L.D.M. (2010) Development of a headspacegas chromatography (HS-GC-PID-FID) method for the determination of VOCs in environmental aqueous matrices: Optimization, verification and elimination of matrix effect and VOC distribution on the Fortaleza coast, Brazil. Microchemical Journal 96, 337-343. https://doi.org/10.1016/j.microc.2010.05.014
  7. Chida, M., Sone, Y., Tamura, H. (2004) Aroma characteristics of stored tobacco cut leaves analyzed by a high vacuum distillation and canister system. Journal of Agricultural and Food Chemistry 52, 7918-7924. https://doi.org/10.1021/jf049223p
  8. Cremades, L.V. (2004) Simulation of the dispersion of VOC from an MSW landfill via a lagrangian particle model: Efficiency of a solid barrier. Environmental Engineering Science 21, 291-302. https://doi.org/10.1089/109287504323066932
  9. Cullere, L., Escudero, A., Cacho, J., Ferreira, V. (2004) Gas chromatography-olfactometry and chemical quantitative study of the aroma of six premium quality Spanish aged red wines. Journal of Agricultural and Food Chemistry 52, 1653-1660. https://doi.org/10.1021/jf0350820
  10. Evtyugina, M.G., Nunes, T., Alves, C., Marques, M.C. (2009) Photochemical pollution in a rural mountainous area in the northeast of Portugal. Atmospheric Research 92, 151-158. https://doi.org/10.1016/j.atmosres.2008.09.006
  11. Faiola, C., Erickson, M., Fricaud, V., Jobson, B., Van-Reken, T. (2012) Quantification of biogenic volatile organic compounds with a flame ionization detector using the effective carbon number concept. Atmospheric Measurement Techniques 5, 2415-2447. https://doi.org/10.5194/amtd-5-2415-2012
  12. Gonzalez, F.R., Nardillo, A.M. (1999) Retention index in temperature-programmed gas chromatography. Journal of Chromatography A 842, 29-49. https://doi.org/10.1016/S0021-9673(99)00158-2
  13. Goodner, K.L. (2008) Practical retention index models of OV-101, DB-1, DB-5, and DB-Wax for flavor and fragrance compounds. LWT-Food Science and Technology 41, 951-958. https://doi.org/10.1016/j.lwt.2007.07.007
  14. Grob, K. (2001) Split and splitless injection for quantitative gas chromatography, 4th ed. WILEY-VCH Verlag GmbH, Weinheim (Germany), p. 37.
  15. Guthrie, J.P. (1975) Carbonyl addition reactions: Factors affecting the hydrate-hemiacetal and hemiacetal-acetal equilibrium constants. Canadian Journal of Chemistry 53, 898-906. https://doi.org/10.1139/v75-125
  16. Harper, M. (2000) Sorbent trapping of volatile organic compounds from air. Journal of Chromatography A 885, 129-151. https://doi.org/10.1016/S0021-9673(00)00363-0
  17. Heberger, K., Görgenyi, M. (1999) Principal component analysis of Kováts indices for carbonyl compounds in capillary gas chromatography. Journal of Chromatography A 845, 21-31. https://doi.org/10.1016/S0021-9673(99)00323-4
  18. Hyötylainen, T., Grob, K., Riekkola, M.L. (1997) Reversed phase HPLC coupled on-line to GC by the vaporizer/precolumn solvent split/gas discharge interface; analysis of phthalates in water. HRC-Journal of High Resolution Chromatography 20, 410-416. https://doi.org/10.1002/jhrc.1240200803
  19. Jia, C., Batterman, S., Chernyak, S. (2006) Development and comparison of methods using MS scan and selective ion monitoring modes for a wide range of airborne VOCs. Journal of Environmental Monitoring 8, 1029-1042. https://doi.org/10.1039/b607042f
  20. Jones, F.W. (1998) Estimation of flame-ionization detector relative response factors for oligomers of alkyl and aryl ether polyethoxylates using the effective carbon number concept. Journal of Chromatographic Science 36, 223-226. https://doi.org/10.1093/chromsci/36.5.223
  21. Kállai, M., Veres, Z., Balla, J. (2001) Response of flame ionization detectors to different homologous series. Chromatographia 54, 511-517. https://doi.org/10.1007/BF02491209
  22. Kavouras, I.G., DuBois, D.W., Etyemezian, V., Nikolich, G. (2013) Spatiotemporal variability of ground-level ozone and influence of smoke in Treasure Valley, Idaho. Atmospheric Research 124, 44-52. https://doi.org/10.1016/j.atmosres.2012.12.005
  23. Kim, K.H., Susaya, J., Sohn, J.R., Brown, R.J.C. (2011) A study of relative performance between direct injection and thermal desorption for several volatile organic acids and reference VOCs by gas chromatographymass spectrometry. Fresenius Environmental Bulletin 20, 2875-2882.
  24. KMOE (2010) Korean ministry of environment, annual report of ambient air quality in Korea.
  25. Lal, S., Sahu, L.K., Venkataramani, S., Mallik, C. (2012) Light non-methane hydrocarbons at two sites in the Indo-Gangetic Plain. Journal of Environmental Monitoring 14(4), 1158-1165. https://doi.org/10.1039/c2em10682e
  26. Le Guen, S., Prost, C., Demaimay, M. (2000) Characterization of odorant compounds of mussels Mytilus edulis) according to their origin using gas chromatographyolfactometry and gas chromatography-mass spectrometry. Journal of Chromatography A 896, 361-371. https://doi.org/10.1016/S0021-9673(00)00729-9
  27. Lilja, J., Aumo, J., Salmi, T., Murzin, D.Y., Maki-Arvela, P., Sundell, M., Ekman, K., Peltonen, R., Vainio, H. (2002) Kinetics of esterification of propanoic acid with methanol over a fibrous polymer-supported sulphonic acid catalyst. Applied Catalysis A: General 228, 253-267. https://doi.org/10.1016/S0926-860X(01)00981-4
  28. Linstrom, P.J., Mallard, W.G. (2013) NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, USA (available at: http://webbook.nist.gov).
  29. Morris, R.A., Chapman, R.L. (1961) Flame lonization hydrocarbon analyzer. Journal of the Air Pollution Control Association 11, 467-489. https://doi.org/10.1080/00022470.1961.10468025
  30. Namiesnik, J., Zygmunt, B., Jastrzebska, A. (2000) Application of solid-phase microextraction for determination of organic vapours in gaseous matrices. Journal of Chromatography A 885, 405-418. https://doi.org/10.1016/S0021-9673(99)01157-7
  31. Pal, R., Kim, K.-H. (2008) Gas chromatographic approach for the determination of carbonyl compounds in ambient air. Microchemical Journal 90, 147-158. https://doi.org/10.1016/j.microc.2008.05.007
  32. Pang, X., Lewis, A.C., Hamilton, J.F. (2011) Determination of airborne carbonyls via pentafluorophenylhydrazine derivatisation by GC-MS and its comparison with HPLC method. Talanta 85, 406-414. https://doi.org/10.1016/j.talanta.2011.03.072
  33. Qian, M., Reineccius, G. (2003) Potent aroma compounds in Parmigiano Reggiano cheese studied using a dynamic headspace (purge-trap) method. Flavour and Fragrance Journal 18, 252-259. https://doi.org/10.1002/ffj.1194
  34. Rahman, M.M., Kim, K.-H. (2013) Parallel analysis of volatile fatty acids, indole, skatole, phenol, and trimethylamine from waste-related source environments. Journal of Chromatography A 1314, 241-248. https://doi.org/10.1016/j.chroma.2013.09.035
  35. Ras, M.R., Borrull, F., Marce, R.M. (2009) Sampling and preconcentration techniques for determination of volatile organic compounds in air samples. TrAC Trends in Analytical Chemistry 28(3), 347-361. https://doi.org/10.1016/j.trac.2008.10.009
  36. Sahu, L.K. (2012) Volatile organic compounds and their measurements in the troposphere Current Science 102(12), 1645-1649.
  37. Sahu, L.K., Lal, S. (2006) Distributions of C2-C5 NMHCs and related trace gases at a tropical urban site in India. Atmospheric Environment 40(5), 880-891. https://doi.org/10.1016/j.atmosenv.2005.10.021
  38. Sahu, L.K. Saxena, P. (2015) High time and mass resolved PTR-TOF-MS measurements of VOCs at an urban site of India during winter: Role of anthropogenic, biomass burning, biogenic and photochemical sources. Atmospheric Research 164-165, 84-94. https://doi.org/10.1016/j.atmosres.2015.04.021
  39. Sanz, C., Ansorena, D., Bello, J., Cid, C. (2001) Optimizing headspace temperature and time sampling for identification of volatile compounds in ground roasted arabica coffee. Journal of Agricultural and Food Chemistry 49, 1364-1369. https://doi.org/10.1021/jf001100r
  40. Szulejko, J.E., Kim, Y.-H., Kim, K.-H. (2013) Method to predict gas chromatographic response factors for trace level analysis of volatile organic compounds based on Effective Carbon Number concept. Journal of Separation Science 36, 3356-3365.
  41. US-EPA (1986) Definition and procedure for the determination of the method detection limit - revision 1.11, code of federal regulations, title 40, part 136, appendix b, 1984. Fed. Regist., 51, 23703.
  42. Wang, P., Zhao, W. (2008) Assessment of ambient volatile organic compounds (VOCs) near major roads in urban Nanjing. Atmospheric Research 89, 289-297. https://doi.org/10.1016/j.atmosres.2008.03.013
  43. White, L.D., Taylor, D.G., Mauer, P.A., Kupel, R.E. (1970) A convenient optimized method for the analysis of selected solvent vapors in the industrial atmosphere. American Industrial Hygiene Association Journal 31, 225-232. https://doi.org/10.1080/0002889708506234
  44. Yanagimoto, K., Ochi, H., Lee, K.-G., Shibamoto, T. (2004) Antioxidative activities of fractions obtained from brewed coffee. Journal of Agricultural and Food Chemistry 52, 592-596. https://doi.org/10.1021/jf030317t
  45. Yassaa, N., Ciccioli, P., Brancaleoni, E., Frattoni, M., Meklati, B.Y. (2011) Ambient measurements of selected VOCs in populated and remote sites of the Sahara desert. Atmospheric Research 100, 141-146. https://doi.org/10.1016/j.atmosres.2011.01.001
  46. Zhang, S., Cai, L., Koziel, J.A., Hoff, S.J., Schmidt, D.R., Clanton, C.J., Jacobson, L.D., Parker, D.B., Heber, A.J. (2010) Field air sampling and simultaneous chemical and sensory analysis of livestock odorants with sorbent tubes and GC-MS/olfactometry. Sensors and Actuators B: Chemical 146, 427-432. https://doi.org/10.1016/j.snb.2009.11.028

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