The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
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Residual Characteristics and Safety Assessments of Bifenthrin, Carbendazim and Metconazole in Angelica gigas Nakai

당귀 중 bifenthrin, carbendazim, metconazole의 잔류 특성 및 안전성 평가

  • Jeong, Hye Rim (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Noh, Hyun Ho (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Lee, Jae Yun (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Park, Hyo Kyoung (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Jin, Me Jee (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Kim, Jin Chan (Hanearlscience Co. Ltd.) ;
  • Hong, Su Myeong (Chemical Safety Division, National Academy of Agricultural Science, Rural Development Administration) ;
  • Kyung, Kee Sung (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University)
  • 정혜림 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 노현호 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 이재윤 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 박효경 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 진미지 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 김진찬 ((주)한얼싸이언스 부설연구소) ;
  • 홍수명 (국립농업과학원 화학물질안전과) ;
  • 경기성 (충북대학교 농업생명환경대학 환경생명화학과)
  • Received : 2017.03.09
  • Accepted : 2017.03.24
  • Published : 2017.03.31
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Abstract

This study was carried out to determine residual characteristics and to evaluate safety of bifenthrin, carbendazim and metconazole in minor crop, Angelica gigas Nakai. The test pesticides were sprayed onto the crop according to the combinations of spray days before harvest and frequency and then sampling was performed at the harvest day. Non-systemic pesticide bifenthrin was not detected in all samples, whereas systemic pesticides, carbendazim and metconazole, were detected from the crop in the range of from 0.14 to 0.49 and from 0.19 to 0.26, respectively. These results indicated that residual characteristics of the test pesticides in Angelica gigas Nakai were affected by their systemic properties. Also, residual concentration of carbendazim and metconazole in the crop was increased as more spraying frequency and spraying more closer to harvest day. And residual concentration of carbendazim in the crop on the last spraying day was 2.1 times higher than that of metconazole because nominal spraying dose of carbendazim was higher than that of metconazole by 1.9 times. The residue levels of the test pesticides in the crop were evaluated to be safe, considering their %ADIs were less than 0.9%.

소면적 재배 작물인 당귀 중 bifenthrin, carbendazim 및 metconazole의 잔류 특성을 구명하고 안전성을 평가하기 위하여 이 연구를 수행하였다. 시험 약제는 수확전 약제 살포일과 횟수를 달리하여 살포하였으며, 최종 약제 살포 당일과 수확 예정일에 시료를 채취하였다. 당귀 중 시험 농약의 검출한계는 모두 0.04 mg/kg이었으며, 회수율은 72.8-85.5%로 양호하였다. 당귀 중 비침투성 농약인 bifenthrin의 잔류량은 모든 처리구에서 검출한계 미만이었으나 침투성 농약인 carbendazim과 metconazole은 각각 0.14-0.49 및 0.19-0.26 mg/kg이 검출되어 당귀 중 시험농약의 잔류에 침투성 여부에 따라 영향을 받는 것으로 판단되었다. 또한 carbendazim과 metconazole의 잔류량은 살포 횟수가 많고 수확일에 인접하여 살포할수록 높은 경향이었다. 약제 살포 3시간 후 carbendazim의 잔류량은 metconazole 잔류량의 약 2.1배 높았는데 이는 최종 약제 살포일에 이론적으로 살포된 농약의 양은 carbendazim이 metconazole의 약 1.9배 높았기 때문으로 판단되며, 이론적 살포량과 살포 당일의 잔류량의 비율이 유사하였다. 약제 살포 당일에 채취한 시료의 잔류량과 수확 예정일에 채취한 시료의 잔류량을 비교하였을 때 carbendazim과 metconazole은 수확 예정일에 채취한 시료 중 잔류량이 감소한 경향이었다. 당귀 중 시험 농약의 일일섭취허용량 대비 일일섭취추정량은 모두 0.9% 미만으로 당귀 중 carbendazim과 metconazole은 안전한 수준으로 평가되었다.

Keywords

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