DOI QR코드

DOI QR Code

Improvement in Mechanical Properties of Cast Magnesium Alloy through Solid-solution Hardening and Grain Refinement

고용 강화 및 결정립 미세화를 통한 마그네슘 합금 주조재의 기계적 물성 향상

  • Kim, Sang-Hoon (School of Materials Science and Engineering, Kyungpook National University) ;
  • Moon, Byoung-Gi (Implementation Research Division, Korea Institute of Materials Science) ;
  • You, Bong-Sun (Implementation Research Division, Korea Institute of Materials Science) ;
  • Park, Sung-Hyuk (School of Materials Science and Engineering, Kyungpook National University)
  • 김상훈 (경북대학교 신소재공학부) ;
  • 문병기 (재료연구소 실용화연구단) ;
  • 유봉선 (재료연구소 실용화연구단) ;
  • 박성혁 (경북대학교 신소재공학부)
  • Received : 2017.12.01
  • Accepted : 2017.12.17
  • Published : 2017.12.31

Abstract

This study investigated the effects of the addition of Zn, Ca, and SiC on the microstructure and mechanical properties of Mg-Al alloys. The tensile properties of homogenized Mg-xAl (x = 6, 7, 8, and 9 wt.%) alloys increased with increasing Zn content by the solid-solution strengthening effect. However, when the added Zn content exceeded the solubility limit, the strength and ductility of the alloys decreased greatly owing to premature fracture caused by undissolved coarse particles or local melting. Among the Mg-xAl-yZn alloys tested in this study, the AZ74 alloy showed the best tensile properties. However, from the viewpoints of the thermal stability, castability, and tensile properties, the AZ92 alloy was deemed to be the most suitable cast alloy. Moreover, the addition of a small amount (0.17 wt.%) of SiC reduced the average grain size of the AZ91 alloy significantly, from $430{\mu}m$ to $73{\mu}m$. As a result, both the strength and the elongation of the AZ91 alloy increased considerably by the grain-boundary hardening effect and the suppression of twinning behavior, respectively. On the other hand, the addition of Ca (0.5-1.5 wt.%) and a combined addition of Ca (0.5-1.5 wt.%) and SiC (0.17 wt.%) increased the average grain size of the AZ91 alloy, which resulted in a decrease in its tensile properties. The SiC-added AZ92 alloy exhibited excellent tensile properties (YS 125 MPa, UTS 282 MPa, and EL 12.3%), which were much higher than those of commercial AZ91 alloy (YS 93 MPa, UTS 192 MPa, and EL 7.0%). The fluidity of the SiC-added AZ92 alloy was slightly lower than that of the AZ91 alloy because of the expansion of the solid-liquid coexistence region in the former. However, the SiC-added AZ92 alloy showed better hot-tearing resistance than the AZ91 alloy owing to its refined grain structure.

Keywords

References

  1. Mordike BL and Ebert T, Mater. Sci. Eng. A, "Magnesium: Properties - applications - potential", 302 (2001) 37-45. https://doi.org/10.1016/S0921-5093(00)01351-4
  2. Lu L, Dahle AK and StJohn DH, Scr. Mater., "Grain refinement efficiency and mechanism of aluminium carbide in Mg-Al alloys", 53 (2005) 517-522. https://doi.org/10.1016/j.scriptamat.2005.05.008
  3. Kulekei MK, Int. J. Adv. Manuf. Tech., "Magnesium and its alloys applications in automotive industry", 39 (2008) 851-865. https://doi.org/10.1007/s00170-007-1279-2
  4. Luo AA, JOM, "Magnesium: Current and potential automotive applications", 54 (2002) 42-48.
  5. Celotto S, Acta Mater., "TEM study of continuous precipitation in Mg-9wt%Al-1wt%Zn alloy", 48 (2000) 1775-1787. https://doi.org/10.1016/S1359-6454(00)00004-5
  6. Akhtar A and Teghtsoonian E, Acta Metall., "Solid solution strengthening of magnesium single crystals-I alloying behaviour in basal slip", 17 (1969) 1339-1349. https://doi.org/10.1016/0001-6160(69)90151-5
  7. Mann G, Griffiths JR and Caceres CH, J. Alloys Compd., "Hall-Petch parameters in tension and compression in cast Mg-2Zn alloys", 378 (2004) 188-191. https://doi.org/10.1016/j.jallcom.2003.12.052
  8. Nie JF, Metall. Mater. Trans. A, "Precipitation and Hardening in Magnesium Alloys", 43A (2012) 3891-3939.
  9. Ye HZ and Liu XY, J. Mater. Sci., "Review of recent studies in magnesium matrix composites", 39 (2004) 6153-6171. https://doi.org/10.1023/B:JMSC.0000043583.47148.31
  10. Caceres CH and Blake A, Phys. Stat. Sol., "The strength of concentrated Mg-Zn solid solutions", 194 (2002) 147-158. https://doi.org/10.1002/1521-396X(200211)194:1<147::AID-PSSA147>3.0.CO;2-L
  11. Liao J, Hotta M, Kaneko K and Kondoh K, Scr. Mater., "Enhanced impact toughness of magnesium alloy by grain refinement", 61 (2009) 208-211. https://doi.org/10.1016/j.scriptamat.2009.03.044
  12. StJohn DH, Qian M, Easton MA, Cao P and Hildebrand Z, Metall. Mater. Trans. A, "Grain Refinement of Magnesium Alloys", 36A (2005) 1669-1679.
  13. Li SS, Tang B and Zeng DB, J. Alloys Compd., "Effects and mechanism of Ca on refinement of AZ91D alloy", 437 (2007) 317-321. https://doi.org/10.1016/j.jallcom.2006.07.117
  14. Jin Q, Eom JP, Lim SG, Park WW and You BS, Scr. Mater., "Grain refining mechanism of a carbon addition method in a Mg-Al magnesium alloy", 49 (2003) 1129-1132. https://doi.org/10.1016/j.scriptamat.2003.07.001
  15. Wang Y, Xia M, Fan Z, Zhou X and Thompson GE, Intermetallics, "The effect of $Al_8Mn_5$ intermetallic particles on grain size of as-cast Mg-Al-Zn AZ91D alloy", 18 (2010) 1683-1689. https://doi.org/10.1016/j.intermet.2010.05.004
  16. Wang Q, Chen W, Zeng X, Lu Y, Ding W, Zhu Y and Xu X, J. Mater. Sci., "Effects of Ca addition on the microstructure and mechanical properties of AZ91magnesium alloy", 36 (2001) 3035-3040. https://doi.org/10.1023/A:1017927109291
  17. Wu G, Fan Y, Gao, H, Zhai C and Zhu YP, Mater. Sci. Eng. A, "The effect of Ca and rare earth elements on the microstructure, mechanical properties and corrosion behavior of AZ91D", 408 (2005) 255-263. https://doi.org/10.1016/j.msea.2005.08.011
  18. Yuan W, Panigrahi SK, Su JQ and Mishra RS, Scr. Mater., "Influence of grain size and texture on Hall-Petch relationship for a magnesium alloy", 65 (2011) 994-997. https://doi.org/10.1016/j.scriptamat.2011.08.028
  19. Chen TJ, Jiang XD, Ma Y, Li YD and Hao Y, J. Alloys Compd., "Grain refinement of AZ91D magnesium alloy by SiC", 496 (2010) 218-225. https://doi.org/10.1016/j.jallcom.2010.03.002
  20. Barnett MR, Keshavarz Z, Beer AG and Ma X, Acta Mater., "Non-Schmid behaviour during secondary twinning in a polycrystalline magnesium alloy", 56 (2008) 5-15. https://doi.org/10.1016/j.actamat.2007.08.034
  21. Xu SW, Kamado S, Matsumoto N, Honma T and Kojima Y, Mater. Sci. Eng. A, "Recrystallization mechanism of as-cast AZ91 magnesium alloy during hot compressive deformation", 527 (2009) 52-60. https://doi.org/10.1016/j.msea.2009.08.062
  22. Ghaderi A and Barnett MR, Acta Mater., "Sensitivity of deformation twinning to grain size in titanium and magnesium", 59 (2011) 7824-7839. https://doi.org/10.1016/j.actamat.2011.09.018
  23. Oh SH and Kim HJ, J. Korea Foundry Society, "Effect of Minor Additives on Casting Properties of AC4A Aluminum Casting Alloys", 37 (2017) 148-156.
  24. Flemings MC, Solidification Processing, McGraw-Hill, New York (1974) 214-262.
  25. Wang Y, Wang Q, WU G, Zhu Y and Ding W, Mater. Lett., "Hot-tearing susceptibility of Mg-9Al-xZn alloy", 57 (2002) 929-934. https://doi.org/10.1016/S0167-577X(02)00898-4
  26. Wang Z, Huang Y, Srinivasan A, Liu Z, Beckmann F, Kainer KU and Hort N, Mater. Des., "Hot tearing susceptibility of binary Mg-Y alloy castings", 47 (2013) 90-100. https://doi.org/10.1016/j.matdes.2012.12.044