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서스펜션 플라즈마 스프레이 코팅법으로 제조된 Ytterbium Silicate 환경차폐코팅의 상형성 및 구조에 미치는 증착인자 및 원료혼합 공정의 영향

Effect of Deposition Parameter and Mixing Process of Raw Materials on the Phase and Structure of Ytterbium Silicate Environmental Barrier Coatings by Suspension Plasma Spray Method

  • 류호림 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 최선아 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 이성민 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 한윤수 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 최균 (한국세라믹기술원 엔지니어링 세라믹 센터) ;
  • 남산 (고려대학교 신소재공학과) ;
  • 오윤석 (한국세라믹기술원 엔지니어링 세라믹 센터)
  • Ryu, Ho-lim (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Choi, Seon-A (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Sung-Min (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Han, Yoon-Soo (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Choi, Kyun (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Nahm, Sahn (Department of Materials Science and Engineering, Korea University) ;
  • Oh, Yoon-Suk (Engineering Ceramic Center, Korea Institute of Ceramic Engineering and Technology)
  • 투고 : 2017.12.01
  • 심사 : 2017.12.21
  • 발행 : 2017.12.28

초록

SiC-based composite materials with light weight, high durability, and high-temperature stability have been actively studied for use in aerospace and defense applications. Moreover, environmental barrier coating (EBC) technologies using oxide-based ceramic materials have been studied to prevent chemical deterioration at a high temperature of $1300^{\circ}C$ or higher. In this study, an ytterbium silicate material, which has recently been actively studied as an environmental barrier coating because of its high-temperature chemical stability, is fabricated on a sintered SiC substrate. $Yb_2O_3$ and $SiO_2$ are used as the raw starting materials to form ytterbium disilicate ($Yb_2Si_2O_7$). Suspension plasma spraying is applied as the coating method. The effect of the mixing method on the particle size and distribution, which affect the coating formation behavior, is investigated using a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and X-ray diffraction (XRD) analysis. It is found that the originally designed compounds are not effectively formed because of the refinement and vaporization of the raw material particles, i.e., $SiO_2$, and the formation of a porous coating structure. By changing the coating parameters such as the deposition distance, it is found that a denser coating structure can be formed at a closer deposition distance.

키워드

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