DOI QR코드

DOI QR Code

정수 및 폐수처리에서 오존 미세기포와 초미세기포 기술의 적용 : 리뷰

Applications of Ozone Micro- and Nanobubble Technologies in Water and Wastewater Treatment: Review

  • 테킬 안디넷 (과학기술연합대학원대학교, 건설환경공학과) ;
  • 김일호 (과학기술연합대학원대학교, 건설환경공학과) ;
  • 이재엽 (한국건설기술연구원, 환경플랜트연구소)
  • Tekile, Andinet (Department of Construction Environment Eng., University of Science and Technology) ;
  • Kim, Ilho (Department of Construction Environment Eng., University of Science and Technology) ;
  • Lee, Jai-Yeop (Environmental and Plant Engineering Research Institute, Korea Institute of Civil Engineering & Building Technology)
  • 투고 : 2017.10.30
  • 심사 : 2017.11.15
  • 발행 : 2017.12.15

초록

Water and wastewater treatment has always been a challenging task due to the continuous increase in amount and the change in characteristics of the poorly biodegradable and highly colored organic matters, as well as harmful micro-organisms. Advanced techniques are therefore required to successfully remove these pollutants from water before reuse or discharge to receiving water bodies. Application of ozone, which is a powerful oxidant and disinfectant, alone or as part of advanced oxidation process depends on the complex kinetic reactions and the mass transfer of ozone involved. Micro- and nano bubbling considerably improves gas dissolution compared to conventional bubbles and hence mass transfer. It can also intensify generation of hydroxyl radical due to collapse of the bubbles, which in turn facilitates oxidation reaction under both alkaline as well as acidic conditions. This review gives the overview of application of micro- and nano bubble ozonation for purification of water and wastewater. The drawbacks of previously considered techniques and the application of the hydrodynamic ozonation to synthetic aqueous solutions and various industrial wastewaters are systematically reviewed.

키워드

참고문헌

  1. Ahmad, M. and Farooq, S. (1985). Influence of Bubble Sizes on Ozone Solubility Utilization and Disinfection. Water Sci. Technol., 17, 1081-1090. https://doi.org/10.2166/wst.1985.0203
  2. Beltran, F.J. (2003). Ozone reaction kinetics for water and wastewater systems. CRC press, Boca Raton, FL., USA. https://doi.org/10.1201/9780203509173
  3. Chen, K.K. (2009). Bathing Pool Assembly with Water Full of Nano-Scale Ozone Bubbles for Rehabilitation, U.S. Patent, USA.
  4. Chu, L.B., Xing, X.H., Yu, A.F., Sun, X.L. and Jurcik, B. (2008). Enhanced treatment of practical textile wastewater by microbubble ozonation, Process Saf. Environ., 86, 389-393. https://doi.org/10.1016/j.psep.2008.02.005
  5. Chu, L.B., Xing, X.H., Yu, A.F., Zhou, Y.N., Sun, X.L., Jurcik, B. (2007). Enhanced ozonation of simulated dyestuff wastewater by microbubbles. Chemosphere, 68, 1854-1860. https://doi.org/10.1016/j.chemosphere.2007.03.014
  6. Eikebrokk, B., Vogt, R.D. and Liltved, H. (2004). NOM increase in Northern European source waters: discussion of possible causes and impacts on coagulation/contact filtration processes. Wa. Sci. Technol., 4(4), 47-54.
  7. He, H., Zheng, L., Li, Y. and Song, W. (2015). Research on the Feasibility of Spraying Micro/Nano Bubble Ozonated Water for Airborne Disease Prevention, Ozone-Sci. Eng., 37(1), 78-84. https://doi.org/10.1080/01919512.2014.913473
  8. Hu, L. and Xia Z. (2018). Application of ozone micro-nano-bubbles to ground water remediation. J. Hazard. Mater., 342, 446-453. https://doi.org/10.1016/j.jhazmat.2017.08.030
  9. Ikeura, H., Kobayashi, F. and Tamaki, M. (2011). Removal of residual pesticide, fenitrothion, in vegetables by using ozone microbubbles generated by different methods. J. Food Eng., 103, 345-349. https://doi.org/10.1016/j.jfoodeng.2010.11.002
  10. Jabesa, A. and Ghosh, P. (2016). Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant, J. Environ. Manage., 180, 476-484. https://doi.org/10.1016/j.jenvman.2016.05.072
  11. Khuntia, S., Majumder, S.K. and Ghosh P. (2013). Removal of Ammonia from Water by Ozone Microbubbles. Ind. Eng. Chem. Res., 52, 318-326. https://doi.org/10.1021/ie302212p
  12. Khuntia, S., Majumder, S.K. and Ghosh, P. (2014). Oxidation of As(III) to As(V) using ozone microbubbles. Chemosphere, 97, 120-124. https://doi.org/10.1016/j.chemosphere.2013.10.046
  13. Khuntia, S., Majumder, S.K. and Ghosh, P. (2015). Quantitative prediction of generation of hydroxyl radicals from ozone microbubbles. Chem. Eng. Res. Des., 98, 231-239 https://doi.org/10.1016/j.cherd.2015.04.003
  14. Kobayashi, F., Ikeura, H., Ohsato, S., Goto, T. and Tamaki M. (2011). Disinfection using ozone microbubbles to inactivate Fusarium oxysporum f. sp. melonis and Pectobacterium carotovorum subsp. Carotovorum. Crop Prot., 30, 1514-1518. https://doi.org/10.1016/j.cropro.2011.07.018
  15. Li, P. and Tsuge, H. (2006). Ozone Transfer in a New Gas-Induced Contactor with Microbubbles. J. Chem. Eng. Jap., 39(11), 1213-1220. https://doi.org/10.1252/jcej.39.1213
  16. Liu, S., Wang, Q., Sun, T., Wu, C. and Shi, Y. (2011). The effect of different types of micro-bubbles on the performance of the coagulation flotation process for coke waste-water. J. Chem. Technol. Biot., 87, 206-215.
  17. Liu, S., Wang, Q., Zhai, X., Huang, Q., and Huang, P. (2010). Improved pretreatment (coagulation-floatation and ozonation) of younger landfill leachate by microbubbles, Water Environ. Res., 82, 657-65. https://doi.org/10.2175/106143010X12609736966522
  18. Loeb, B.L., Thompson, C.M., Drago, J., Takahara, H. and Baig, S. (2012). Worldwide Ozone Capacity for Treatment of Drinking Water and Wastewater: A Review. Ozone-Sci. Eng., 34(1), 64-77. https://doi.org/10.1080/01919512.2012.640251
  19. Shin, W.T., Mirmiran, A., Yiacoumi, S. and Tsouris, C. (1999). Ozonation using microbubbles formed by electric fields, Sep. Purif. Technol., 15: 271-282. https://doi.org/10.1016/S1383-5866(98)00107-5
  20. Sumikura, M., Hidaka, M., Murakami, H., Nobutomo, Y. and Murakami, T. (2007). Ozone micro-bubble disinfection method for wastewater reuse system, Water Sci Technol., 56(5), 53-61. https://doi.org/10.2166/wst.2007.556
  21. Takahashi, M., Chiba, K. and Li, P. (2007). Formation of hydroxyl radicals by collapsing ozone microbubbles under strongly acidic conditions. J. Phys. Chem. B, 111, 11443-11446. https://doi.org/10.1021/jp074727m
  22. Walker, A.B., Tsouris, C., DePaoli, D.W. and Klasson, K.T. (2001). Ozonation of Soluble Organics in Aqueous Solutions Using Microbubbles, Ozone-Sci. Eng., 23(1), 77-87. https://doi.org/10.1080/01919510108961990
  23. Yasuda, K. and Ban, N. (2012). Wastewater Treatment for Bioethanol Production System Using Ozone Microbubbles. J. Chem. Eng. Jap., 45(9), 672-677. https://doi.org/10.1252/jcej.12we056
  24. Zhang, F., Xi J., Huang J.-J. and Hu H.-Y. (2013). Effect of inlet ozone concentration on the performance of a microbubble ozonation system for inactivation of Bacillus subtilis spores, Sep. Purif. Technol., 114, 126-33. https://doi.org/10.1016/j.seppur.2013.04.034
  25. Zheng, T., Wang, Q., Zhang, T., Shi, Z., Tian, Y., Shi, S., Smale, N. and Wang, J. (2015). Microbubble enhanced ozonation process for advanced treatment of wastewater produced in acrylic fiber manufacturing industry. J. Hazard. Mater., 287, 412-420. https://doi.org/10.1016/j.jhazmat.2015.01.069

피인용 문헌

  1. Using design of experiments to understand and predict polymer microcapsule core‐shell architecture vol.138, pp.13, 2017, https://doi.org/10.1002/app.50100
  2. Control of Vibrio parahaemolyticus (AHPND strain) and improvement of water quality using nanobubble technology vol.52, pp.6, 2017, https://doi.org/10.1111/are.15124
  3. Direct Oxidation of Antibiotics from Aqueous Solution by Ozonation with Microbubbles vol.1973, pp.1, 2021, https://doi.org/10.1088/1742-6596/1973/1/012157
  4. Global trends and characteristics of nano- and micro-bubbles research in environmental engineering over the past two decades: A scientometric analysis vol.785, pp.None, 2021, https://doi.org/10.1016/j.scitotenv.2021.147362
  5. Free radical degradation in aqueous solution by blowing hydrogen and carbon dioxide nanobubbles vol.11, pp.1, 2017, https://doi.org/10.1038/s41598-021-82717-z
  6. Disinfection applications of ozone micro- and nanobubbles vol.8, pp.12, 2017, https://doi.org/10.1039/d1en00700a