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Iron(III) removal from aqueous solution using MCM-41 ceramic composite membrane

  • Basumatary, Ashim Kumar (Department of Chemical Engineering, Indian Institute Technology Guwahati) ;
  • Kumar, R. Vinoth (Department of Chemical Engineering, Indian Institute Technology Guwahati) ;
  • Pakshirajan, Kannan (Department of Biosciences and Bioengineering,Indian Institute Technology Guwahati) ;
  • Pugazhenthi, G. (Department of Chemical Engineering, Indian Institute Technology Guwahati)
  • Received : 2016.01.23
  • Accepted : 2016.07.24
  • Published : 2016.11.25

Abstract

Mesoporous MCM-41 was deposited on an inexpensive disk shaped ceramic support through hydrothermal technique for ultrafiltration of $Fe^{3+}$ from aqueous solution. The ceramic support was fabricated using uni-axial compaction technique followed by sintering at $950^{\circ}C$. The characteristics of MCM-41 powder as well as the composite membrane were examined by X-ray diffraction (XRD), thermogravimetric analysis (TGA), field emission scanning electron microscope (FESEM), porosity and pure water permeation test. The XRD result revealed the good crystallinity and well-resolved hexagonally arranged pore geometry of MCM-41. TGA profile of synthesized MCM-41 zeolite displayed the three different stepwise mechanisms for the removal of organic template. The formation of MCM-41 on the porous support was verified by FESEM analysis. The characterization results clearly indicated that the accumulation of MCM-41 by repeated coating on the ceramic disk directs to reduce the porosity and pore size from 47% to 23% and 1.0 to $0.173{\mu}m$, respectively. Moreover, the potential of the fabricated MCM-41 membrane was investigated by ultrafiltration of $Fe^{3+}$ from aqueous stream at various influencing parameters such as applied pressure, initial feed concentration and pH of solution. The maximum rejection 85% was obtained at applied pressure of 276 kPa and the initial feed concentration of 250 ppm at pH 2.

Keywords

References

  1. Basumatary, A.K., Kumar, R.V., Ghoshal, A.K. and Pugazhenthi, G. (2015a), "Synthesis and characterization of MCM-41-ceramic composite membrane for the separation of chromic acid from aqueous solution", J. Membr. Sci., 475, 521-532. https://doi.org/10.1016/j.memsci.2014.10.055
  2. Basumatary, A.K., Singh, P.V., Kumar, R.V., Ghoshal, A.K. and Pugazhenthi, G. (2015b), "Development and characterization of a MCM-48 ceramic composite membrane for the removal of Cr(VI) from an aqueous slution", J. Environ. Eng-ASCE., 142(9), C4015013-11.
  3. Chougui, A., Zaiter, K., Belouatek, A. and Asli, B. (2014), "Heavy metals and color retention by a synthesized inorganic membrane", Arabian J. Chem., 7(5), 817-822. https://doi.org/10.1016/j.arabjc.2012.11.017
  4. Chung, C.V., Buu, N.Q. and Chau, N.H. (2005), "Influence of surface charge and solution pH on the performance characteristics of a nanofiltration membrane", Sci. Technol. Adv. Mater., 6(3-4), 246-250. https://doi.org/10.1016/j.stam.2005.02.025
  5. Guillou, F., Rouleau, L., Pirngruber, G. and Valtchev, V. (2009), "Synthesis of FAU-type zeolite membrane: An original in situ process focusing on the rheological control of gel-like precursor species", Micropor. Mesopor. Mater., 119(1-3), 1-8. https://doi.org/10.1016/j.micromeso.2008.11.030
  6. Gzara, L. (2001), "Removal of chromate anions by micellar-enhanced ultrafiltration using cationic surfactants", Desalination, 137(1-3), 241-250. https://doi.org/10.1016/S0011-9164(01)00225-9
  7. Jia, M.D, Chen, B., Noble, R.D. and Falconer, J.L. (1994), "Ceramic-zeolite composite membranes and their application for separation of vapor/gas mixtures", J. Membr. Sci., 90(1-2), 1-10. https://doi.org/10.1016/0376-7388(94)80029-4
  8. Kasim, N., Mohammad, A.W. and Abdullah, S.R.S. (2016), "Performance of membrane filtration in the removal of iron and manganese from Malaysia's groundwater", Membr. Water Treat., Int. J., 7(4), 277-296. https://doi.org/10.12989/mwt.2016.7.4.277
  9. Kumar, R.V., Moorthy, I.G. and Pugazhenthi, G. (2015a), "Modelling and optimization of critical parameters by hybrid RSM-GA for the separation of BSA using tubular configured MFI-type zeolite microfiltration membrane", RSC Adv., 5(106), 87645-87659. https://doi.org/10.1039/C5RA20114D
  10. Kumar, R.V., Basumatary, A.K., Ghoshal, A.K. and Pugazhenthi, G. (2015b), "Performance assessment of an analcime-C zeolite-ceramic composite membrane by removal of Cr (VI) from aqueous solution", RSC Adv., 5, 6246-6254. https://doi.org/10.1039/C4RA14527E
  11. Kumar, R.V., Ghoshal, A.K. and Pugazhenthi, G. (2015c), "Elaboration of novel tubular ceramic membrane from inexpensive raw materials by extrusion method and its performance in microfiltration of synthetic oily wastewater treatment", J. Membr. Sci., 490, 92-102. https://doi.org/10.1016/j.memsci.2015.04.066
  12. Liou, T.H. (2011), "A green route to preparation of MCM-41 silicas with well-ordered mesostructure controlled in acidic and alkaline environments", Chem. Eng. J., 171(3), 1458-1468. https://doi.org/10.1016/j.cej.2011.05.074
  13. Liu, C., Wang, L., Ren, W., Rong, Z., Wang, X. and Wang, J. (2007), "Synthesis and characterization of a mesoporous silica (MCM-48) membrane on a large-pore ${\alpha}-Al_2O_3$ ceramic tube", Micropor. Mesopor. Mater., 106(1-3), 35-39. https://doi.org/10.1016/j.micromeso.2007.02.007
  14. Majhi, A., Monash, P. and Pugazhenthi, G. (2009), "Fabrication and characterization of ${\gamma}-Al_2O_3$-clay composite ultrafiltration membrane for the separation of electrolyte from its aqueous solution", J. Membr. Sci., 340(1-2), 181-191. https://doi.org/10.1016/j.memsci.2009.05.030
  15. Monash, P. and Pugazhenthi, G. (2011), "Development of ceramic supports derived from low-cost raw materials for membrane applications and its optimization based on sintering temperature", Int. J. Appl. Ceram. Technol., 8(1), 227-238. https://doi.org/10.1111/j.1744-7402.2009.02443.x
  16. Nandi, B.K., Uppaluri, R. and Purkait, M.K. (2008), "Preparation and characterization of low cost ceramic membranes for micro-filtration applications", Appl. Clay Sci., 42(1-2), 102-110. https://doi.org/10.1016/j.clay.2007.12.001
  17. Nazzal, F.F. and Wiesner, M.R. (1994), "pH and ionic strength effects on the performance of ceramic membranes in water filtration", J. Membr. Sci., 93(1), 91-103. https://doi.org/10.1016/0376-7388(94)85019-4
  18. Shukla, A. and Kumar, A. (2005), "Characterization of chemically modified zeolite-clay composite membranes using separation of trivalent cations", Sep. Purif. Technol., 41(1), 83-89. https://doi.org/10.1016/j.seppur.2004.05.001
  19. Shukla, A. and Kumar, A. (2007), "Separation of Cr(VI) by zeolite-clay composite membranes modified by reaction with NOx", Sep. Purif. Technol., 52(3), 423-429. https://doi.org/10.1016/j.seppur.2006.05.022
  20. Udayakumar, S., Pandurangan, A. and Sinha, P.K. (2005), "Mesoporous material as catalyst for the production of fine chemical: Synthesis of dimethyl phthalate assisted by hydrophobic nature MCM-41", J. Mol. Catal. A: Chem., 240(1-2), 139-154.
  21. Urbanowska, A. and Kabsch-Korbutowicz, M. (2016), "Cleaning agents efficiency in cleaning of polymeric and ceramic membranes fouled by natural organic matter", Membr. Water Treat., Int. J., 7(1), 1-10. https://doi.org/10.12989/mwt.2016.7.1.001
  22. Wang, Z., Kumakiri, I., Tanaka, K., Chen, X. and Kita, H. (2013), "NaY zeolite membranes with high performance prepared by a variable-temperature synthesis", Micropor. Mesopor. Mater., 182, 250-258. https://doi.org/10.1016/j.micromeso.2013.05.002
  23. Workneh, S. and Shukla, A. (2008), "Synthesis of sodalite octahydrate zeolite-clay composite membrane and its use in separation of SDS", J. Membr. Sci., 309(1-2), 189-195. https://doi.org/10.1016/j.memsci.2007.10.033
  24. Wu, S., Yang, J., Lu, J., Zhou, Z., Kong, C. and Wang, J. (2008), "Synthesis of thin and compact mesoporous MCM-48 membrane on vacuum-coated ${\alpha}-Al_2O_3$ tube", J. Membr. Sci., 319(1-2), 231-237. https://doi.org/10.1016/j.memsci.2008.03.057

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