한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제32권5호
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  • Pages.485-500
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  • 2016
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  • 1598-7132(pISSN)
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  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
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한반도 서부유입권역에서 대기 중 에어로졸 성분의 화학적 특성 연구 II. 입자의 산성도 및 산화 특성

A Study on Chemical Characteristics of Aerosol Composition at West Inflow Regions in the Korean Peninsula II. Characteristics of Inorganic Aerosol Acidity and Organic Aerosol Oxidation

  • 최진수 (국립환경과학원 기후대기연구부 대기환경연구과) ;
  • 김정호 (에이피엠 엔지니어링(주)) ;
  • 이태형 (한국외국어대학교 환경학과) ;
  • 최용주 (한국외국어대학교 환경학과) ;
  • 박태현 (한국외국어대학교 환경학과) ;
  • 안준영 (국립환경과학원 기후대기연구부 대기환경연구과) ;
  • 박진수 (국립환경과학원 기후대기연구부 대기환경연구과) ;
  • 김현재 (국립환경과학원 기후대기연구부 대기환경연구과) ;
  • 구윤서 (안양대학교 환경에너지공학과) ;
  • 김신도 (서울시립대학교 환경공학과) ;
  • 홍유덕 (국립환경과학원 기후대기연구부 대기환경연구과) ;
  • 홍지형 (국립환경과학원 기후대기연구부 대기환경연구과)
  • Choi, Jin-Soo (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research) ;
  • Kim, Jeong-Ho (APM Engineering Co., Ltd.) ;
  • Lee, Tae-Hyoung (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Choi, Yong-Joo (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Park, Tae-Hyun (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Ahn, Joon-Young (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research) ;
  • Park, Jin-Soo (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research) ;
  • Kim, Hyun-Jae (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research) ;
  • Koo, Youn-Seo (Department of Environmental and Energy Engineering, Anyang University) ;
  • Kim, Shin-Do (Department of Environmental Engineering, University of Seoul) ;
  • Hong, You-Deog (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research) ;
  • Hong, Ji-Hyung (Department of Air Quality Research, Climate and Air Quality Research Division, National Institute of Environmental Research)
  • 투고 : 2016.06.20
  • 심사 : 2016.09.21
  • 발행 : 2016.10.31
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초록

We examined acidity state of inorganic aerosol and oxidation state of organic aerosol by High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) at Baengnyeong Super site from Jan 2012 to Dec 2013. Additionally, we carried out the analysis for the aerosol component group of organic matter ($C_xH_y$, $C_xH_yO_1$, $C_xH_yO_z$, $C_xH_yO_zN_p$) and elemental composition to calculate H/C, O/C, N/C, OM/OC and identify the oxidation state. The aerosol chemical composition in this study is dominated by sulfate ($SO_4{^{2-}}$), nitrate ($NO_3{^-}$) plays a smaller role in aerosol acidity. Ammonium ($NH_4{^+}$) was found in a formation of $(NH_4)_3H(SO_4)_2$. However, the binding formations of $NH_4NO_3$ and $NH_4Cl$ increase in the winter. $C_xH_yO_1$ indicating the oxidized state of $PM_{1.0}$ has the highest ratio of 41% while $C_xH_y$ indicating the non-oxidized state has a lower ratio of 36%, meaning that the oxidation level of $PM_{1.0}$ in Baengnyeong Island is high. The ratio between H/C and O/C was 1.33 and 0.78 respectively, showing the characteristic of LV-OOA (Low volatility-Oxygenated Organic Aerosol). Acidic and oxidized aerosols sampled during this field study were largely anthropogenic in origin from Chinese continent and photochemically aged.

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참고문헌

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