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플라이애시-고로슬래그 기반 지오폴리머 세라믹스의 열적특성

Thermal Property of Geopolymer Ceramics Based on Fly Ash-Blast Furnace Slag

  • 김진호 (강원대학교 나노응용공학과) ;
  • 남인탁 (강원대학교 나노응용공학과) ;
  • 박현 (강원대학교 신소재공학과) ;
  • 김경남 (강원대학교 신소재공학과)
  • Kim, Jin-Ho (Department of Nano Applied Engineering, Kangwon National University) ;
  • Nam, In-Tak (Department of Nano Applied Engineering, Kangwon National University) ;
  • Park, Hyun (Department of Advanced Materials Engineering, Kangwon National University) ;
  • Kim, Kyung-Nam (Department of Advanced Materials Engineering, Kangwon National University)
  • 투고 : 2016.08.05
  • 심사 : 2016.08.30
  • 발행 : 2016.10.27

초록

Geopolymers have many advantages over Portland cement, including energy efficiency, reduced greenhouse gas emissions, high strength at early age and improved thermal resistance. Alkali activated geopolymers made from waste materials such as fly ash or blast furnace slag are particularly advantageous because of their environmental sustainability and low cost. However, their durability and functionality remain subjects for further study. Geopolymer materials can be used in various applications such as fire and heat resistant fiber composites, sealants, concretes, ceramics, etc., depending on the chemical composition of the source materials and the activators. In this study, we investigated the thermal properties and microstructure of fly ash and blast furnace slag based geopolymers in order to develop eco-friendly construction materials with excellent energy efficiency, sound insulation properties and good heat resistance. With different curing times, specimens of various compositions were investigated in terms of compressive strength, X-ray diffraction, thermal property and microstructure. In addition, we investigated changes in X-ray diffraction and microstructure for geopolymers exposed to $1,000^{\circ}C$ heat.

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참고문헌

  1. P. Duxson, J. L. Provis, G. C. Lukey and J. S. J. Van Deventer, Cem. Concr. Res., 37, 1590 (2007). https://doi.org/10.1016/j.cemconres.2007.08.018
  2. J. Temuujin and A. van Riessen, J. Hazard. Mater., 164, 634 (2008).
  3. J. Davidovits, in Proceedings of 1st International Conference on Alkaline Cement and Concrete, Scientific Research Institute on Binders and Materials (Kiev, Ukraine, October 1994) p.131.
  4. S. G. Son, S. Y. Hong and Y. D. Kim, J. Korean Ceram. Soc., 45, 395 (2008). https://doi.org/10.4191/KCERS.2008.45.7.395
  5. J. T. Kim, D. S. Seo, G. J. Kim and J. K. Lee, J. Korean Ceram. Soc., 47, 216 (2010). https://doi.org/10.4191/KCERS.2010.47.3.216
  6. S. K. Lee and Y. S. Kim, J. Arch. Inst. Korean Struct. Const., 30, 39 (2014).
  7. K. T. Koh, G. S. Ryu and J. H. Lee, J. Korean Recy. Cons. Insti., 6, 119 (2011).
  8. T. W. Cheng and J. P. Chiu, Miner. Eng., 16, 205 (2003). https://doi.org/10.1016/S0892-6875(03)00008-6
  9. V. F. F. Barbosa and L. J. D. KacKenzie, Mater. Res. Bull., 38, 319 (2003). https://doi.org/10.1016/S0025-5408(02)01022-X
  10. R. Zhao and J. G. Sanjayan, Mag. Concr. Res., 63, 163 (2011) https://doi.org/10.1680/macr.9.00110
  11. V. F. F. Barbosa and K. J. D. MacKenzie, Mater. Res. Bull., 38, 319 (2003). https://doi.org/10.1016/S0025-5408(02)01022-X
  12. C. H. Chen, I. J. Chiou and K. S. Wang, Cem. Concr. Com., 28, 26 (2006). https://doi.org/10.1016/j.cemconcomp.2005.09.003
  13. J. Davidovits, US Patent 4, 472, 199 (1984).
  14. S. Kumar, R. Kumar and S. P. Mehrotra, J. Mat. Sci., 45, 607 (2010). https://doi.org/10.1007/s10853-009-3934-5
  15. D. Panias, I. P. Giannopoulou and T. Perraki, Colloids Surf. A Physicochem. Eng. Asp., 301, 246 (2007). https://doi.org/10.1016/j.colsurfa.2006.12.064
  16. Y. Zhang, W. Sun, Q. Chen and L. Chen, J. Harzard. Mater., 143, 206 (2007). https://doi.org/10.1016/j.jhazmat.2006.09.033
  17. J. Zhang, J. L. Provis, D. Feng and J. S. J. van Deventer, J. Harzard. Mater., 157, 587 (2008). https://doi.org/10.1016/j.jhazmat.2008.01.053
  18. A. Palomo, M. W. Grutzeck and M. T. Blanco, Cem. Concr. Res., 29, 1323 (1999). https://doi.org/10.1016/S0008-8846(98)00243-9
  19. Sindhunata, Ph. D Thesis, Unversity of Melboume, Australia, 83-88, (2006).
  20. W. Z. Choi and E. K. Park, J. Korean Inst. Res. Recy., 15, 47 (2006).
  21. M. Palacios and F. Puertas, Cem. Concr. Res., 37, 691 (2007) https://doi.org/10.1016/j.cemconres.2006.11.021
  22. S. G. Son, W. K. Lee, Y. D. Kim and K. N. Kim, Korean J. Mater. Res., 21, 502 (2011). https://doi.org/10.3740/MRSK.2011.21.9.502
  23. P. He, D. Jia, M. Wang and Y. Zhou, Ceram. Int., In Press (2010).
  24. A. R. Lucia, P. Gerard, M. Etienne and E. Alain, Cem. Concr. Res., 35, 609 (2005). https://doi.org/10.1016/j.cemconres.2004.06.015
  25. S. G. Son and Y. D. Kim, J. Korea Soc. Waste Manag., 27, 709 (2010).
  26. B. Joseph, Ph. D. Thesis (in Indian), p.90-92 Cochin University of Science and Technology (2015).