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Studies on Electrode Integrated Piezoelectric Polyvinylidene difluoride(PVDF) Fiber

전극 일체형 polyvinylidene difluoride(PVDF) 압전 섬유에 관한 연구

  • Lee, Se Young (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Kim, Seul Bi (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Choi, Se Jin (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Bang, Ju Yup (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Kim, Han Seong (Department of Organic Material Science and Engineering, Pusan National University)
  • 이세영 (부산대학교 유기소재시스템공학과) ;
  • 김슬비 (부산대학교 유기소재시스템공학과) ;
  • 최세진 (부산대학교 유기소재시스템공학과) ;
  • 방주엽 (부산대학교 유기소재시스템공학과) ;
  • 김한성 (부산대학교 유기소재시스템공학과)
  • Received : 2016.07.17
  • Accepted : 2016.08.14
  • Published : 2016.08.31

Abstract

Polyvinylidene difluoride solution dip-coating and a high-voltage poling process is effective at inducing chain reorientation and phase transformation. Moreover, a copper wire external electrode and coated fiber combined to form a piezoelectric device successfully. In addition, a textile-like piezoelectric device comprising of three warps and one weft was fabricated, and the piezoelectric properties of the device were evaluated. The voltage from the polyvinylidene difluoride fiber was increased as the external force was applied. The piezoelectric performance was affected by the presence of external load resistors. Moreover, in the case of the textile-type piezoelectric device, the more warps and weft were connected to each other, the higher was the voltage generated. Consequently, single fiber can be used for piezoelectric devices, moreover, it enables advanced users to have wide application, for example, woven or knitted smart textile-type sensors or micro energy harvesters.

Keywords

References

  1. H. Kawai, "The Piezoelectricity of Poly(vinylidene fluoride)", Jpn. J. Appl. Phys., 1969, 8, 975-976. https://doi.org/10.1143/JJAP.8.975
  2. A. Salimi and A. A. Yousefi, "Analysis Method: FTIR Studies of ${\beta}$-phase Crystal Formation in Stretched PVDF Films", Polym. Test., 2003, 22, 699-704. https://doi.org/10.1016/S0142-9418(03)00003-5
  3. H. Liang, R. Cooper, and J. Files, "Phase Transformation of Poly(vinylidene difluoride) in Energy Harvesting", J. Mater. Res., 2011, 26, 1-8. https://doi.org/10.1557/jmr.2010.81
  4. B. Mohammadi, A. A. Yousefi, and S. M. Bellah, "Effect of Tensile Strain Rate and Elongation on Crystalline Structure and Piezoelectric Properties of PVDF Thin Films", Polym. Test., 2007, 26, 42-50. https://doi.org/10.1016/j.polymertesting.2006.08.003
  5. A. J. Lovinger, "Poly(vinylidene fluoride)", Springer, Netherlands, 1982, pp.195-273.
  6. A. Salimi and A. A. Yousefi, "Analysis Method: FTIR Studies of ${\beta}$-phase Crystal Formation in Stretched PVDF Films", Polym. Test., 2003, 22, 699-704. https://doi.org/10.1016/S0142-9418(03)00003-5
  7. Joseph C. Salamone, "Polymeric Materials Encyclopedia", CRC Press, New York, 1996, pp.7115-7122.
  8. A. Jain, J. Kumar, D. R. Mahapatra, and H. H. Kumar, "Detailed Studies on the Formation of Piezoelectric ${\beta}$-phase of PVDF at Different Hot-stretching Conditions", Sensors and Smart Structures Technologies for Civil, Mechanical, and Aerospace Systems 2010, 76472C.
  9. H. J. Ye, L. Yang, W. Z. Shao, S. B. Sun, and L. Zhen, "Effect of Electroactive Phase Transformation on Electron Structure and Dielectric Properties of Uniaxial Stretching Poly(vinylidene fluoride) Films", RSC Adv., 2013, 3, 23730-23736. https://doi.org/10.1039/c3ra43966f
  10. V. Sencadas, R. Gregorio Jr., and S. Lanceros-Mendez, "${\alpha}$ to ${\beta}$ Phase Transformation and Microestructural Changes of PVDF Films Induced by Uniaxial Stretch", J. Macromol. Sci. B, 2009, 48, 514-525. https://doi.org/10.1080/00222340902837527
  11. D. V. Khakhar and A. Misra, "Studies on ${\alpha}$ to ${\beta}$ Phase Transformations in Mechanically Deformed PVDF Films", J. Appl Polym Sci., 2010, 117, 3491-3497.
  12. M. P. Silva, C. M. Costa, V. Sencadas, A. J. Paleo, and S. Lanceros-Mendez, "Degradation of the Dielectric and Piezoelectric Response of ${\beta}$-poly(vinylidene fluoride) after Temperature Annealing", J. Polym. Res., 2011, 18, 1451-1457. https://doi.org/10.1007/s10965-010-9550-x
  13. A. Garton and M. H. George, "Effect of Oxygen on the Polymerization of Vinyl Chloride. I. Kinetic Features", J. Polym. Sci. Polym. Phys. Ed., 1973, 11, 2153-2167 https://doi.org/10.1002/pol.1973.170110908
  14. S. Satapathy, S. Pawar, P. K. Gupta, and K. B. R. Varma, "Effect of Annealing on the Phase Transition in Poly(vinylidene fluoride) Films Prepared Using Polar Solvent", Bull. Mater. Sci., 2011, 34, 727-733. https://doi.org/10.1007/s12034-011-0187-0
  15. A. Peterlin and J. H. Elwell, "Dielectric Constant of Rolled Polyvinylidene Fluoride", J. Mater. Sci., 1967, 2, 1-6.
  16. V. Sencadas, R. Barbosa, J. F. Mano, and S. Lanceros-Mendez, "Mechanical Characterization and Influence of the High Temperature Shrinkage of ${\beta}$-PVDF Films on Its Electromechanical Properties", Ferroelectrics, 2003, 294, 61-71. https://doi.org/10.1080/00150190390238621
  17. E. Fukada, "History and Recent Progress in Piezoelectric Polymers, Ultrasonics, Ferroelectrics, and Frequency Control", IEEE Transactions on 2000, 47, 1277-1290. https://doi.org/10.1109/58.883516
  18. V. Sencadas, C. M. Costa, V. Moreira, J. Monteiro, S. K. Mendiratta, J. F. Mano, and S. Lanceros-Mendez, "Poling of ${\beta}$-Poly(vinylidene fluoride): Dielectric and IR Spectroscopy Studies", e-Polymers, 2005, 5, 10-21.
  19. M. Sharma, G. Madras, and S. Bose, "Process Induced Electroactive ${\beta}$-polymorph in PVDF: Effect on Dielectric and Ferroelectric Properties", Phys. Chem. Chem. Phys., 2014, 16, 14792-14799. https://doi.org/10.1039/c4cp01004c
  20. J. Zheng, A. He, J. Li, and C. C. Han, "Polymorphism Control of Poly(vinylidene fluoride) through Electrospinning", Macromol. Rapid. Commun., 2007, 28, 2159-2162. https://doi.org/10.1002/marc.200700544
  21. E. Zampetti, A. Bearzotti, and A. Macagnano, "Flexible Piezoelectric Transducer Based on Electrospun PVDF Nanofibers for Sensing Applications", Procedia Eng., 2014, 87, 1509-1512. https://doi.org/10.1016/j.proeng.2014.11.585
  22. C. K. Yen, C. H. Tsao, C. T. Pan, H. C. Wu, Y. C. Lai, Z. H. Liu, Y. L. Lin, Liwei Lin, S. W. Kuo, Y. S. Lu, H. L. Hung, S. W. Mao, C. F. Liu, and S. C. Shen, "Electrospun PVDF Fibers oN Biowings Using Multi-spinnerets", 2014 9th IEEE International Conference on Nano/Micro Engineered and Molecular Systems, 2014, pp.609-613.
  23. J. Pu, X. Yan, Y. Jiang, C. Chang, and L. Lin, "Piezoelectric Actuation of Direct-write Electrospun Fibers", Sens. Actuat. A Phys., 2010, 164, 131-136. https://doi.org/10.1016/j.sna.2010.09.019
  24. E. Nilsson, A. Lund, C. Jonasson, C. Johansson, and B. Hagstrom, "Poling and Characterization of Piezoelectric Polymer Fibers for Use in Textile Sensors", Sens. Actuat. A Phys., 2013, 201, 477-486. https://doi.org/10.1016/j.sna.2013.08.011
  25. D. Mandal, S. Yoon, and K. J. Kim, "Origin of Piezoelectricity in an Electrospun Poly(vinylidene fluoride-trifluoroethylene) Nanofiber Web-Based Nanogenerator and Nano-Pressure Sensor", Macromol. Rapid. Commun., 2011, 32, 831-837. https://doi.org/10.1002/marc.201100040
  26. R. Gregorio Jr. and N. C. P. de Souza Nociti, "Effect of PMMA Addition on the Solution Crystallization of the Alpha and Beta Phases of Poly(vinylidene fluoride)(PVDF)", J. Phys. D Appl. Phys., 1995, 28, 432-436. https://doi.org/10.1088/0022-3727/28/2/028
  27. E. Klimiec, K. Zaraska, W. Zaraska, and S. Kuczynski, "Micropower Generators and Sensors Based on Piezoelectric Polypropylene PP and Polyvinylidene Fluoride PVDF Films-Energy Harvesting from Walking", Appl. Mech. Mater., 2012, 110, 1245-1251.
  28. C. T. Pan, C. K. Yen, L. Lin, Y. S. Lu, H. W. Li, J. C. C. Huang, and S. W. Kuo, "Energy Harvesting with Piezoelectric Poly(${\gamma}$-benzyl-L-glutamate) Fibers Prepared Through Cylindrical Near-field Electrospinning", RSC Adv., 2014, 4, 21563-21570. https://doi.org/10.1039/c4ra01452a
  29. C. Chang, V. H. Tran, J. Wang, Y. K. Fuh, and L. Lin, "Directwrite Piezoelectric Polymeric Nanogenerator with High Energy Conversion Efficiency", Nano Lett., 2010, 10, 726-731. https://doi.org/10.1021/nl9040719