DOI QR코드

DOI QR Code

Structural and Physical Properties of Ternary Composite Nonwovens by Fiber Blend Ratio and Heat Treatment Condition

3성분 복합부직포의 혼섬비와 열처리 조건에 따른 구조와 물성

  • Park, Young Shin (Department of Advanced Organic Materials & Textile System Engineering, Chungnam National University) ;
  • Joo, Chang Whan (Department of Advanced Organic Materials & Textile System Engineering, Chungnam National University)
  • 박영신 (충남대학교 공과대학 유기소재.섬유시스템공학과) ;
  • 주창환 (충남대학교 공과대학 유기소재.섬유시스템공학과)
  • Received : 2016.05.27
  • Accepted : 2016.06.12
  • Published : 2016.06.30

Abstract

In this work, effects of fiber blend ratios and heat treatments on structural and physical properties of ternary composite nonwovens were investigated. Composite nonwovens were fabricated using different blend ratios of nylon, PET, and PTT/PET fibers and were treated in hot-air flow or hot-water immersion. Morphological and pore structure of composite nonwovens were analyzed by SEM and PMI, respectively. Tensile properties of composite nonwovens were measured by Instron with different loading directions. Although shrinkage behavior of PTT/PET bicomponent fibers (bicofibers) increased surface bulkiness of nonwovens via heat treatments, evenness of composite nonwovens was improved in proportion with the ratio of bicofibers. Average pore size of composite nonwovens was decreased owing to heat treatments, and hot-air treatment was found to be a more suitable process for achieving a uniform pore structure compared to hot-water treatments. Pore size distribution of composite nonwovens was found to be narrow with hot-air flow treatments but was widened with increasing bicofiber content. Tensile strength and tensile modulus of nonwovens were inversely proportional to PTT/PET bicofiber content, and their values were observed to considerably decrease in the cross-direction of composite nonwovens. From the results, we confirm that the structural stability of composite nonwovens was improved significantly by heat treatments owing to curling behavior of bicofibers in proportion with content of bicofibers.

Keywords

References

  1. T. H. Cho, M. Tanaka, H. Ohnishi, Y. Kondo, M. Yoshikazu, T. Nakamura, and T. Sakai, "Composite Nonwoven Separator for Lithium-ion Battery: Development and Characterization", J. Power Sources, 2010, 195, 4272-4277. https://doi.org/10.1016/j.jpowsour.2010.01.018
  2. D. V. Parikh, Y. Chen, and L. Sun, "Reducing Automotive Interior Noise with Natural Fiber Nonwoven Floor Covering Systems", Text. Res. J., 2006, 76, 813-820. https://doi.org/10.1177/0040517506063393
  3. A. Rawal and R. Anandjiwala, "Comparative Study between Needlepunched Geotextile Structure Made from Flax and Polyester Fibres", Geotext. Geomembr., 2007, 25, 61-65. https://doi.org/10.1016/j.geotexmem.2006.08.001
  4. H. Wang, Q. Wei, X. Wang, W. Gao, and X. Zhao, "Antibacterial Properties of PLA Nonwoven Medical Dressing Coated with Nanostructured Silver", Fiber. Polym., 2008, 9, 556-560. https://doi.org/10.1007/s12221-008-0089-y
  5. M. Mohanmmadi, P. B. Lee, and P. Ghadimi, "Air Permeability of Multilayer Needle-Punched Nonwoven Fabrics: Theorical Method", J. Ind. Text., 2002, 32, 45-57. https://doi.org/10.1106/152808302031065
  6. J. Verschuren, P. V. Herzele, K. D. Clerch, and P. Kiekens, "Influence of Fiber Surface Purity on Wicking Properties of Needle-punched Nonwoven after Oxygen Plasma Treatment", Text. Res. J., 2005, 75, 437-441. https://doi.org/10.1177/0040517505054170
  7. M. Kucuk and Y. Korkmaz, "Sound Absorption Properties of Bilayered Nonwoven Composites", Fiber. Polym., 2015, 16, 941-948. https://doi.org/10.1007/s12221-015-0941-9
  8. C. F. J. Kuo, T. L. Su, and C. P. Tsai, "Optimization of the Needle Punching Process for the Nonwoven Fabrics with Multiple Quality Characteristics by Grey-based Taguchi Method", Fiber. Polym., 2007, 8, 654-664. https://doi.org/10.1007/BF02876005
  9. S. Debnath and M. Madhusoothanan, "Water Absorbency of Jute-Polypropylene Blended Needle-punched Nonwoven", J. Ind. Text., 2010, 39, 215-231. https://doi.org/10.1177/1528083709347121
  10. C. C. Lin, C. M. Lin, C. C. Huang, C. W. Lou, H. H. Meng, C. H. Hsu, and J. H. Lin, "Elucidating the Design and Impact Properties of Composites Nonwoven Fabrics with Various Filaments in Bulletproof Vest Cushion Layer", Text. Res. J., 2009, 79, 268-274. https://doi.org/10.1177/0040517507097515
  11. E. K. Savel'eva, A. V. Dedov, E. S. Bokova, and G. P. Andrianova, "Pore Structure of Heat-treated Nonwoven Materials", Fibre Chemistry, 2005, 37, 202-204. https://doi.org/10.1007/s10692-005-0081-x
  12. B. Ding, E. Kimura, T. Sato, S. Fujita, and S. Dhiratori, "Fabrication of Blend Biodegradable Nanofibrous Nonwoven Mats via Multi-Jet Electrospinning", Polymer, 2004, 45, 1895-1902. https://doi.org/10.1016/j.polymer.2004.01.026
  13. Y. Hong, Y. Li, X. Zhuang, X. Chen, and X. Jing, "Electrospinning of Multicomponent Utrathin Fibrous Nonwovens for Semi-occlusive Wound Dressings", J. Biomed. Mater. Res. Part A, 2009, 89A, 345-354. https://doi.org/10.1002/jbm.a.31968
  14. D. G. Yu, L. D. Gao, K. White, C. Branford-White, W. Y. Lu, and L. M. Zhu, "Multicomponent Amorphous Nanofibers Electrospun from Hot Aqueous Solutions of a Poorly Soluble Drug", Pharmaceutical Research, 2010, 27, 2466-2477. https://doi.org/10.1007/s11095-010-0239-y
  15. R. Pradanth, V. Aravindan, and M. Srinivasan, "Novel Polymer Electrolyte Based on Coweb Electrospun Multi Component Polymer Blend of Polyacrylonitril/Poly(methyl methacrylate)/Polystyrene for Lithium Ion Batteries-Preparation and Electrochemical Characterization", J. Power Sources, 2012, 202, 299-307. https://doi.org/10.1016/j.jpowsour.2011.11.057
  16. N. Vasanthan and D. R. Salem, "FTIR Spectroscopic Characterization of Structural Changes in Polyamide-6 Fibers during Annealing and Drawing", J. Polym. Sci. Part B, 2001, 39, 536-547. https://doi.org/10.1002/1099-0488(20010301)39:5<536::AID-POLB1027>3.0.CO;2-8
  17. P. J. Hine and I. M. Ward, "Hot Compaction of Woven Poly(ethylene terephthalate) Multifilament", J. Appl. Polym. Sci., 2004, 91, 2223-2233. https://doi.org/10.1002/app.13343
  18. J. S. Grebowicz, H. Brown, H. Chuah, J. M. Olvera, A. Wasiak, P. Sajkiewicz, and A. Ziabicki, "Deformation of Undrawn Poly(trimethylene terephthalate) (PTT) Fibers", Polymer, 2001, 42, 7153-7160. https://doi.org/10.1016/S0032-3861(01)00047-7