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The Effects of Annealing on Changes in Properties and Crystal Structure of Nylon 46/6 Blend Filament

열처리에 따른 나일론 46/6 블렌드 원사의 물성과 결정구조 변화 연구

  • Jang, Soon Ho (Department of Organic and Nano Engineering, Hanyang University) ;
  • Oh, Tae Hwan (Department of Nano, Medical and Polymer Materials, Yeungnam University) ;
  • Kim, Seong Hun (Department of Organic and Nano Engineering, Hanyang University)
  • 장순호 (한양대학교 유기나노공학과) ;
  • 오태환 (영남대학교 나노메디컬유기재료공학과) ;
  • 김성훈 (한양대학교 유기나노공학과)
  • Received : 2016.04.09
  • Accepted : 2016.05.20
  • Published : 2016.06.30

Abstract

In this study, the annealing effects on changes in tensile properties and crystal structure of nylon 46/6 blend filament were investigated and compared with those of nylon 6 filament. The nylon 46/6 blend filament was prepared by mixing nylon 46 chips (polymerized nylon 4, 6 (40 mole%) and nylon 6 (60 mole%)) and nylon 6 chips in the ratio 1:1 by weight. The elongation at break of nylon 46/6 blend filaments decreases with increasing annealing temperature and time. Wide angle X-ray scattering revealed that the crystal structure of nylon 46/6 blend filaments had changed to ${\alpha}$-form at an annealing temperature of $180^{\circ}C$. Changes in the properties and crystal structure of the nylon 46/6 blend filament were more sensitive to annealing conditions than those of nylon 6.

Keywords

References

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