DOI QR코드

DOI QR Code

Removal of Uranium from Uranium Plant Wastewater Using Zero-Valent Iron in an Ultrasonic Field

  • Li, Jing (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Zhang, Libo (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Peng, Jinhui (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Hu, Jinming (Nuclear Group Two Seven Two Uranium Industry Limited Liability Company) ;
  • Yang, Lifeng (Nuclear Group Two Seven Two Uranium Industry Limited Liability Company) ;
  • Ma, Aiyuan (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Xia, Hongying (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Guo, Wenqian (Yunnan Provincial Key Laboratory of Intensification Metallurgy) ;
  • Yu, Xia (Yunnan Provincial Key Laboratory of Intensification Metallurgy)
  • Received : 2015.09.07
  • Accepted : 2016.01.20
  • Published : 2016.06.25

Abstract

Uranium removal from uranium plant wastewater using zero-valent iron in an ultrasonic field was investigated. Batch experiments designed by the response surface methodology (RSM) were conducted to study the effects of pH, ultrasonic reaction time, and dosage of zero-valent iron on uranium removal efficiency. From the experimental data obtained in this work, it was found that the ultrasonic method employing zero-valent iron powder effectively removes uranium from uranium plant wastewater with a uranium concentration of $2,772.23{\mu}g/L$. The pH ranges widely from 3 to 7 in the ultrasonic field, and the prediction model obtained by the RSM has good agreement with the experimental results.

Keywords

References

  1. W.H. Zou, L. Zhao, R.P. Han, Removal of uranium (VI) by fixed bed ion-exchange column using natural zeolite coated with manganese oxide, Chin. J. Chem. Eng. 17 (2009) 585-593. https://doi.org/10.1016/S1004-9541(08)60248-7
  2. D.L. Sparks, Environmental Soil Chemistry, Academic Press, San Diego (CA), 1998.
  3. J. Latey, C. Roberts, M. Penberth, C. Vasek, An agricultural dilemma: drainage water and toxics disposal in the San Joaquin Valley, University of California Agricultural Experiment Station, Riverside (CA), 1986.
  4. R. Han, W. Zou, Y. Wang, L. Zhu, Removal of uranium (VI) from aqueous solutions by manganese oxide coated zeolite: discussion of adsorption isotherms and pH effect, J. Environ. Radioact. 93 (2007) 127-143. https://doi.org/10.1016/j.jenvrad.2006.12.003
  5. J.B. Ji, X.H. Lu, M.Q. Cai, Z.C. Xu, Improvement of leaching process of geniposide with ultrasound, Ultrason. Sonochem. 13 (2006) 455-462. https://doi.org/10.1016/j.ultsonch.2005.08.003
  6. C. Stavarache, M. Vinatoru, R. Nishmura, Y. Maeda, Fatty acids methyl esters from vegetable oil by means of ultrasonic energy, Ultrason, Sonochem. 12 (2005) 367-372. https://doi.org/10.1016/j.ultsonch.2004.04.001
  7. J. Ji, J. Wang, Y. Li, Y. Yu, Z. Xu, Preparation of biodiesel with the help of ultrasonic and hydrodynamic cavitation, Ultrasonics 44 (2006) e411-e414. https://doi.org/10.1016/j.ultras.2006.05.020
  8. L.M. Camacho, S. Deng, R.R. Parra, Uranium removal from groundwater by natural clinoptilolite zeolite: effects of pH and initial feed concentration, J. Hazard. Mater. 175 (2010) 393-398. https://doi.org/10.1016/j.jhazmat.2009.10.017
  9. M. Dickinson, T.B. Scott, The application of zero-valent iron nanoparticles for the remediation of a uraniumcontaminated waste effluent,, J. Hazard Mater. 178 (2010) 171-179. https://doi.org/10.1016/j.jhazmat.2010.01.060
  10. D.C. Montgomery, United States; Solutions from Montgomery. Design and Analysis of Experiments, John Wiley & Sons, Hoboken (NJ), 2001.
  11. A.L. Ahmad, S.C. Low, S.R. Abd Shukor, A. Ismail, Optimization of membrane performance by thermalmechanical stretching process using responses surface methodology (RSM), Sep. Purif. Technol. 66 (2009) 177-186. https://doi.org/10.1016/j.seppur.2008.11.007
  12. M. Basri, N.Z. Rahman, A. Ebrahimpour, A.B. Salleh, E.R. Gunawan, B.A. Rahman, Comparison of estimation capabilities of response surface methodology (RSM) with artificial neural network (ANN) in lipase-catalyzed synthesis of palm-based wax ester, BMC Biotechnol. 53 (2007) 1-14.
  13. C.J. Shieh, C.C. Akoh, P.E. Koehler, Four-factor response surface optimization of the enzymatic modification of triolein to structured lipids, J. Am. Oil. Chem. Soc. 72 (1995) 619-623. https://doi.org/10.1007/BF02635645
  14. B.K. Korbhati, N. Aktas, A. Tanyolac, Optimization of electrochemical treatment of industrial paint wastewater with response surface methodology, J. Hazard. Mater. 148 (2007) 83-90. https://doi.org/10.1016/j.jhazmat.2007.02.005
  15. H. Ceylan, S. Kubilay, N. Aktas, N. Sahiner, An approach for prediction of optimum reaction conditions for laccasecatalyzed bio-transformation of 1-naphthol by response surface methodology (RSM), Bioresour. Technol. 99 (2008) 2025-2031. https://doi.org/10.1016/j.biortech.2007.03.018
  16. EJ1056-2005, Regulations for radiation protection for uranium processing and fuel fabrication facility, China Commission of Science Technology and Industry for National Defense, Beijing (China), 2005 [In Chinese].
  17. GB8798-1996, Integrated Wastewater Discharge Standard, National Standard of the People's Republic of China, 1998 [In Chinese].
  18. P. Verma, U.S. Agrawal, A.K. Sharma, B.C. Sarkar, H.K. Sharma, Optimization of process parameters for the development of a cheese analogue from pigeon pea (Cajanus cajan) and soy milk using response surface methodology, Int. J. Dairy Technol. 39 (2005) 319-320.
  19. H.S. Wu, G.C. Zhu, X.W. Lu, Application of micro-electrolysis process for the treatment of dyestuff wastewater, Environ. Herald 2 (1999) 18-20 [In Chinese].

Cited by

  1. The effects of hydrogen peroxide solution and ultrasound on the dissolution of electrodeposited uranium oxide vol.319, pp.3, 2016, https://doi.org/10.1007/s10967-018-6271-9
  2. Ultrasonic-enhanced replacement of lead in lead hydrometallurgy process from lead leaching solution vol.6, pp.7, 2019, https://doi.org/10.1098/rsos.190042