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Feasibility Study on Potassium Iodide (KI) Sensor for Measuring Total Resiudual Oxidant in Ballast Water

선박 평형수 내 총 잔류 산화물(Total Residual Oxidant) 분석을 위한 Potassium Iodide (KI) Sensor 적용가능성 평가

  • 권재형 ((주)테크로스 중앙연구소) ;
  • 임헌진 ((주)테크로스 중앙연구소) ;
  • 이광호 ((주)테크로스 중앙연구소) ;
  • 이해돈 ((주)테크로스 중앙연구소) ;
  • 김대원 ((주)테크로스 중앙연구소)
  • Received : 2016.07.26
  • Accepted : 2016.11.04
  • Published : 2016.11.30

Abstract

Potassium iodide (KI) TRO sensor for measuring total residual oxidant which is an index for disinfection and neutralization in ballast water has been constructed. The results of UV absorption wavelength and absorbance test in various TRO concentrations show high linear correlation ($r^2=0.9825$) at 350 nm wavelengths and it can be possible to visualize numerical value of TRO concentration (0.1~7.0 mg/L). The result of comparison test according to TRO concentration between the KI based TRO sensor system and the DPD based TRO sensor system showed identical trend. Overall results indicated that the KI TRO sensing system could be applied for continuous TRO concentration measurement in ballast water treatment system.

Potassium iodide (KI) TRO sensor에 의한 선박평형수의 살균 및 중화배출 기준이 되는 총 잔류 산화물(TRO)의 농도분석 적용 가능성을 검토하였다. UV 흡수파장 도출시험 및 흡광도 분석결과 350 nm 단일파장에서 TRO 농도에 대한 흡광도 값은 높은 상관관계($r^2=0.9825$)를 가지며 흡광도 값의 TRO 농도(0.1~7.0 mg/L) 수치화가 가능하였다. 상기 시험결과를 토대로 KI 기반의 센서 시스템 구축을 통해 기존의 센서(DPD 기반 시스템)와의 TRO 농도측정 비교결과 동일한 경향의 측정값이 도출되었으며, KI TRO 센서 시스템이 선박평형수 내 연속 TRO 측정장치로 적용할 수 있는 가능성이 있다고 판단하였다.

Keywords

References

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