지질공학 (The Journal of Engineering Geology)

  • 제26권4호
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  • Pages.515-529
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  • 2016
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  • 1226-5268(pISSN)
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  • 2287-7169(eISSN)
대한지질공학회 (The Korean Society of Engineering Geology)
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제주도 서귀포지역 천연탄산수의 기원과 수리화학특성

Origin and Hydrochemical Characteristics of Natural Carbonated Water at Seoqwipo, Jeju Island

  • 정찬호 (대전대학교 건설안전방재공학과) ;
  • 이용천 (대전대학교 건설안전방재공학과) ;
  • 이유진 (대전대학교 건설안전방재공학과) ;
  • 최현영 (대전대학교 건설안전방재공학과) ;
  • 고기원 (제주특별자치도개발공사 지역가치연구팀) ;
  • 문덕철 (제주특별자치도개발공사 지역가치연구팀) ;
  • 정차연 (한국농어촌공사제주지역본부 지하수지질부) ;
  • 조시범 (한국농어촌공사제주지역본부 지하수지질부)
  • Jeong, Chan Ho (Department of Construction Safety and Disaster Prevention Engineering, Daejeon University) ;
  • Lee, Yong Cheon (Department of Construction Safety and Disaster Prevention Engineering, Daejeon University) ;
  • Lee, Yu Jin (Department of Construction Safety and Disaster Prevention Engineering, Daejeon University) ;
  • Choi, Hyeon Young (Department of Construction Safety and Disaster Prevention Engineering, Daejeon University) ;
  • Koh, Gi Won (Local Value Research Team, Jeju Province Development Corporation) ;
  • Moon, Duk Chul (Local Value Research Team, Jeju Province Development Corporation) ;
  • Jung, Cha Youn (Groundwater & Geology division, Korea Rural Community Corporation Jeju Regional Headquarter) ;
  • Jo, Si Beom (Groundwater & Geology division, Korea Rural Community Corporation Jeju Regional Headquarter)
  • 투고 : 2016.12.02
  • 심사 : 2016.12.27
  • 발행 : 2016.12.30
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초록

본 연구에서는 제주 서귀포지역에서 산출되는 온천수 2지점과 탄산수 2지점에 대한 화학성분, CFCs (Chlorofluorocarbons) 동위원소, ${\delta}^{18}O$, ${\delta}D$, ${\delta}^{13}C$ 동위원소, 영족기체(He, Ne) 동위원소 분석을 통하여 탄산온천수와 탄산수의 수리화학적 특성, 생성연령, 영족기체의 기원과 $CO_2$ 가스의 기원을 해석하였다. 연구지역의 탄산수의 pH는 6.21~6.84의 범위의 약산성과 매우 높은 전기전도도 값($1,928{\sim}4,720{\mu}S/cm$)의 특성을 보인다. 화학적 유형은 $Mg(Ca,Na)-HCO_3$ 내지는 $Na(Ca,Mg)-HCO_3$ 유형을 보인다. 환경추적자인 CFCs 농도를 이용하여 지하수 연령측정결과, 탄산수는 약 47.5~57.2년, 지하수는 약 30.3~49.5년으로 추정되었다. 탄산수의 ${\delta}^{13}C$값은 -1.77~-7.27‰의 범위를 보여 $CO_2$ 가스의 기원은 심부기원과 일부 심부-무기기원의 혼합 기원으로 도시되었지만, 영족기체 조성비($^3He/^4He$, $^4He/^{20}Ne$)에서 헬륨가스가 심부기원의 농도가 절대적으로 높은 값을 보여 화산활동과 관련한 심부 마그마 기원임을 보여준다.

In this study, geochemical composition, CFCs (Chlorofluorocarbons), ${\delta}^{18}O$, ${\delta}D$, ${\delta}^{13}C$ isotopes and noble gases isotopes (He, Ne) were analyzed to determine their recharge age, source of $CO_2$ gas and noble gases of carbonated hot spring water and carbonated-water samples collected in the Seoqwipo of the Jeju. The pH of the carbonated waters ranges from 6.21 to 6.84, and the high electrical conductivity range ($1,928{\sim}4,720{\mu}S/cm$). Their chemical composition is classified as $Mg(Ca,\;Na)-HCO_3$ and $Na(Ca,\;Mg)-HCO_3$ types. As a result of the calculation of groundwater age using CFCs concentrations as an environmental tracer, the carbonated water and groundwater were estimated to be about 47.5~57.2 years and about 30.3~49.5 years, respectively. The ${\delta}^{13}C$ values of carbonated water range from -1.77 to -7.27‰, and are plotted on thr deep-seated field or the mixing field of the deep-seated and inorganic origin. Noble gases isotopic ($^3He/^4He$, $^4He/^{20}Ne$) ratio shows that helium gas of carbonated hot waters comes from deep-seated magma origin.

키워드

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