DOI QR코드

DOI QR Code

Synthesis and Characterization of Brilliant Yellow Color Pigments using α-FeOOH Nanorods

α-FeOOH 나노로드를 이용한 선명한 황색 안료 합성 연구

  • Yun, JiYeon (Engineering Ceramic Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Yu, Ri (Engineering Ceramic Center, Korea Institute of Ceramic Engineering & Technology) ;
  • Kim, YooJin (Engineering Ceramic Center, Korea Institute of Ceramic Engineering & Technology)
  • 윤지연 (한국세라믹기술원 엔지니어링세라믹센터) ;
  • 유리 (한국세라믹기술원 엔지니어링세라믹센터) ;
  • 김유진 (한국세라믹기술원 엔지니어링세라믹센터)
  • Received : 2016.10.06
  • Accepted : 2016.12.07
  • Published : 2016.12.28

Abstract

In this work, we synthesize brilliant yellow color ${\alpha}$-FeOOH by controlling the rod length and core-shell structure. The characteristics of ${\alpha}$-FeOOH nanorods are controlled by the reaction conditions. In particular, the length of the ${\alpha}$-FeOOH rods depends on the concentration of the raw materials, such as the alkali solution. The length of the nanorods is adjusted from 68 nm to 1435 nm. Their yellowness gradually increases, with the highest $b^*$ value of 57 based on the International Commission on Illumination (CIE) Lab system, by controlling the nanorod length. A high quality yellow color is obtained after formation of a silica coating on the ${\alpha}$-FeOOH structure. The morphology and the coloration of the nal products are investigated in detail by X-ray diffraction, scanning electron microscopy, UV-vis spectroscopy, and the CIE Lab color parameter measurements.

Keywords

References

  1. G. Buxbaum: Industrial Inorganic Pigment, Wiley-VCH, German (1998) 99.
  2. U. Schewertmann: Iron oxides in the Laboratory, Wiley-VCH, Weinheim (1991) 67.
  3. H. Katsuki and S. Komarneni: J. Am. Ceram. Soc., 86 (2003) 183. https://doi.org/10.1111/j.1151-2916.2003.tb03300.x
  4. H. Katsuki and S. Komarneni: J. Am. Ceram. Soc., 84 (2001) 2313.
  5. R. Yu, K. Choi, J. H. Pee and Y. J. Kim: J. Korean Powder Metall. Inst., 20 (2013) 210. https://doi.org/10.4150/KPMI.2013.20.3.210
  6. R. Yu, Y. J. Kim, J. H. Pee, K. J. Kim and W. Kim: J. Nanosci. Nanotechnol., 11 (2011) 6283. https://doi.org/10.1166/jnn.2011.4379
  7. J. Yue, X. C. Jiang and A. Tu: J. Nanopart. Res., 13 (2000) 3961.
  8. J. Yun, R. Yu and Y. Kim: J. Nanosci. Nanotechnol., 16 (2016) 11080. https://doi.org/10.1166/jnn.2016.13293
  9. C. Domingo, R. R. Clemente and M.A. Blesa: Solid State Ion., 59 (1993) 187. https://doi.org/10.1016/0167-2738(93)90049-9
  10. S. Krehula, S. Popovic and S. Music: Mater. Lett., 54 (2002) 108. https://doi.org/10.1016/S0167-577X(01)00546-8
  11. K. Parida and J. Das: J. Colloid Interface Sci., 178 (1996) 586. https://doi.org/10.1006/jcis.1996.0155
  12. C. Domingo-Pascual, R. Rodriguez-Clemente and M.A. Blesa: Colloids Surf. A Physicochem. Eng. Asp., 79 (1993) 177. https://doi.org/10.1016/0927-7757(93)80173-C
  13. F. Geng, Z. Zhao, J. Geng, H. Cong and H. M. Cheng: Mater. Lett., 61 (2007) 4794. https://doi.org/10.1016/j.matlet.2007.03.036
  14. M. Muller, H. C. Villalba, F. Q. Mariani, M. Dalpasquale, M. Z. Lemos, M. F. G. Huila and F. J. Auaissi: Dyes Pigm., 120 (2015) 271. https://doi.org/10.1016/j.dyepig.2015.04.026
  15. M. Zhang, K. Chen, X. Chen, X. Peng, X. Sun and D. Xue: CrystEngComm, 17 (2015) 1917. https://doi.org/10.1039/C4CE02543A
  16. J. Yue, X. Jiang and A. Yu: Solid State Sci., 13 (2011) 263. https://doi.org/10.1016/j.solidstatesciences.2010.11.026
  17. S. Sameera, P. Prabhakar Rao, S. Divya and Athira K. V. Raj: ACS Sustain. Chem. Eng., 3 (2015) 1227. https://doi.org/10.1021/acssuschemeng.5b00198
  18. R. Yu, J. H. Pee and Y. Kim: J. Nanosci. Nanotechnol., 14 (2014) 2667. https://doi.org/10.1166/jnn.2014.8482