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Fabrication and Characteristics of Thermal Barrier Coatings in the La2O3-Gd2O3-ZrO2 System by Using Suspension Plasma Spray with Different Suspension Preparations

서스펜션의 준비방법에 따른 서스펜션 플라즈마 용사를 이용한 La2O3-Gd2O3-ZrO2 계 열차폐코팅의 제조와 특성

  • Lee, Soyul (Engineering Ceramics Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Sung-Min (Engineering Ceramics Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Oh, Yoon-Suk (Engineering Ceramics Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Hyung-Tae (Engineering Ceramics Center, Korea Institute of Ceramic Engineering and Technology) ;
  • Nahm, Sahn (Department of Materials Science and Engineering, Korea University) ;
  • Kim, Seongwon (Engineering Ceramics Center, Korea Institute of Ceramic Engineering and Technology)
  • 이소율 (한국세라믹기술원 이천분원 엔지니어링세라믹센터) ;
  • 이성민 (한국세라믹기술원 이천분원 엔지니어링세라믹센터) ;
  • 오윤석 (한국세라믹기술원 이천분원 엔지니어링세라믹센터) ;
  • 김형태 (한국세라믹기술원 이천분원 엔지니어링세라믹센터) ;
  • 남산 (고려대학교 신소재공학과) ;
  • 김성원 (한국세라믹기술원 이천분원 엔지니어링세라믹센터)
  • Received : 2016.12.12
  • Accepted : 2016.12.29
  • Published : 2016.12.31

Abstract

Rare-earth zirconates, including lanthanum zirconate and gadolinium zirconate, have been investigated as ones of the most promising candidates for next-generation thermal barrier coating (TBC) materials due to their excellent properties such as low thermal conductivity, chemical stability at high temperature and so on. In this study, TBCs with three compositions, in the $La_2O_3-Gd_2O_3-ZrO_2$ system with reduced rare-earth contents from $RE_2Zr_2O_7$ compositions, were fabricated by using suspension plasma spray with different suspension preparation methods. The phase formation, microstructure, and thermal properties of TBCs were examined. In particular, each coating exhibited single fluorite phase and a dense, vertically-separated microstructure. The potential of coatings with rare-earth zirconates for TBC applications was also discussed.

Keywords

References

  1. D. R. Clarke, S. R. Phillpot, Thermal Barrier Coating Materials, Mater. Today, 8 (2005) 22-29.
  2. R. Vassen, M. O. Jarligo, T. Steinke, D. E. Mack, D. Stover, Overview on Advanced Thermal Barrier Coatings, Surf. Coat. Technol., 205 (2010) 938-942. https://doi.org/10.1016/j.surfcoat.2010.08.151
  3. D. R. Clarke, M. Oechsner, N. P. Padture, Thermal-Barrier Coatings for More Efficient Gas-Turbine Engines, MRS Bull., 37 (2012) 891-898. https://doi.org/10.1557/mrs.2012.232
  4. W.-J. Lee, B.-K. Jang, D.-S. Lim, Y.-S. Oh, S.-W. Kim, H.-T. Kim, H. Araki, H. Murakami, S. Kuroda, Hot Corrosion Behavior of Plasma Sprayed 4 mol.% $Y_2O3$-$ZrO_2$ Thermal Barrier Coatings with Volcanic Ash(in Korean), J. Korean Ceram. Soc., 50 (2013) 353-358. https://doi.org/10.4191/kcers.2013.50.6.353
  5. W. Pan, S. R. Phillpot, C. Wan, A. Chernatynskiy, Z. Qu, Low Thermal Conductivity Oxides, MRS Bull., 37 (2012) 917-922. https://doi.org/10.1557/mrs.2012.234
  6. S. Sampath, U. Schulz, M. O. Jarligo, S. Kuroda, Processing Science of Advanced Thermal-Barrier Systems, MRS Bull., 37 (2012) 903-910. https://doi.org/10.1557/mrs.2012.233
  7. C.-S. Kwon, S.-M. Lee, Y.-S. Oh, H.-T. Kim, B.-K. Jang, S. Kim, Structure and Thermal Conductivity of Thermal Barrier Coatings in Lanthanum/Gadolinium Zirconate System Fabricated via Suspension Plasma Spray(in Korean), J. Korean Inst. Surf. Eng., 47 (2014) 316-322. https://doi.org/10.5695/JKISE.2014.47.6.316
  8. R. Vassen, X. Cao, F. Tietz, D. Basu, D. Stover, Zirconates as New Materials for Thermal Barrier Coatings, J. Am. Ceram. Soc., 83 (2000) 2023-2028.
  9. J. Wu, X. Wei, N. P. Padture, P. G. Klemens, M. Gell, E. Garcia, P. Miranzo, M. I. Osendi, Low-Thermal-Conductivity Rare-Earth Zirconates for Potential Thermal-Barrier-Coating Applications, J. Am. Ceram. Soc., 85 (2002) 3031-3035.
  10. D. Chen, M. Gell, E. H. Jordan, E. Cao, X. Ma, Thermal Stability of Air Plasma Spray and Solution Precursor Plasma Spray Thermal Barrier Coatings, J. Am. Ceram. Soc., 90 (2007) 3160-3166. https://doi.org/10.1111/j.1551-2916.2007.01864.x
  11. J. W. Fergus, Zirconia and Pyrochlore Oxides for Thermal Barrier Coatings in Gas Turbine Engines, Metall. Mater. Trans. E, (2014) 1-14.
  12. S.-J. Kim, W.-J. Lee, C.-S. Kwon, S.-M. Lee, Y.-S. Oh, H.-T. Kim, D.-S. Im, S. Kim, Phase Formation and Thermo-physical Properties of $GdO_{1.5}-ZrO_2$ System for Thermal Barrier Coating Application(in Korean), J. Korean Ceram. Soc., 51 (2014) 554-559. https://doi.org/10.4191/kcers.2014.51.6.554
  13. S. Lee, C.-S. Kwon, S.-M. Lee, Y.-S. Oh, H.-T. Kim, S. Nahm, S. Kim, Phase Formation and Thermo-physical Properties of Lanthanum/Gadolinium Zirconate with Reduced Rare-Earth Contents for Thermal Barrier Coatings(in Korean), J. Korean Powd. Metall. Inst., 22 (2015) 420-425. https://doi.org/10.4150/KPMI.2015.22.6.420
  14. X. Q. Cao, R. Vassen, D. Stoever, Ceramic Materials for Thermal Barrier Coatings, J. Euro. Ceram. Soc., 24 (2004) 1-10. https://doi.org/10.1016/S0955-2219(03)00129-8
  15. H. Lehmann, D. Pitzer, G. Pracht, R. Vassen, D. Stover, Thermal Conductivity and Thermal Expansion Coefficients of the Lanthanum Rare-Earth-Element Zirconate System, J. Am. Ceram. Soc., 86 (2003) 1338-1344. https://doi.org/10.1111/j.1151-2916.2003.tb03473.x
  16. K.-H. Kwak, B.-C. Shim, S.-M. Lee, Y.-S. Oh, H.-T. Kim, B.-K. Jang, S. Kim, Formation and Thermal Properties of Fluorite-Pyrochlore Composite Structure in $La_2(Zr_xCe_{1-x})_2O_7$ Oxide System, Mater. Lett., 65 (2011) 2937-2940. https://doi.org/10.1016/j.matlet.2011.06.043
  17. J. Wu, N. P. Padture, P. G. Klemens, M. Gell, E. Garcia, P. Miranzo, M. I. Osendi, Thermal Conductivity of Ceramics in the $ZrO_2-GdO_{1. 5}$ System, J. Mater. Res., 17 (2002) 3193-3200. https://doi.org/10.1557/JMR.2002.0462
  18. R. Vassen, H. Kassner, A. Stuke, F. Hauler, D. Hathiramani, D. Stover, Advanced Thermal Spray Technologies for Applications in Energy Systems, Surf. Coat. Technol., 202 (2008) 4432-4437. https://doi.org/10.1016/j.surfcoat.2008.04.022
  19. U. Schulz, B. Saruhan, K. Fritscher, C. Leyens, Review on Advanced EB-PVD Ceramic Topcoats for TBC Applications, Inter. J. Appl. Ceram. Technol., 1 (2004) 302-315.
  20. W. Fan, Y. Bai, Review of Suspension and Solution Precursor Plasma Sprayed Thermal Barrier Coatings, Ceram. Inter., 42 (2016) 14299-14312. https://doi.org/10.1016/j.ceramint.2016.06.063
  21. K. VanEvery, M. J. M. Krane, R. W. Trice, H. Wang, W. Porter, M. Besser, D. Sordelet, J. Ilavsky, J. Almer, Column Formation in Suspension Plasma-Sprayed Coatings and Resultant Thermal Properties, J. Therm. Spray Technol., 20 (2011) 817-828. https://doi.org/10.1007/s11666-011-9632-2
  22. N. Curry, Z. Tang, N. Markocsan, P. Nylen, Influence of Bond Coat Surface Roughness on the Structure of Axial Suspension Plasma Spray Thermal Barrier Coatings - Thermal and Lifetime Performance, Surf. Coat. Technol., 268 (2015) 15-23. https://doi.org/10.1016/j.surfcoat.2014.08.067
  23. C.-S. Kwon, S. Lee, S.-M. Lee, Y.-S. Oh, H.-T. Kim, B.-K. Jang, S. Kim, Fabrication and Characterization of $La_2Zr_2O_7$/YSZ Double-Ceramic-Layer Thermal Barrier Coatings Fabricated by Suspension Plasma Spray(in Korean), J. Korean Inst. Surf. Eng., 48 (2015) 315-321. https://doi.org/10.5695/JKISE.2015.48.6.315
  24. M. A. Subramanian, G. Aravamudan, G. V. S. Rao, Oxide Pyrochlores: A Review, Progr. Sol. St. Chem., 15 (1983) 55-143. https://doi.org/10.1016/0079-6786(83)90001-8
  25. L. Minervini, R. W. Grimes, K. E. Sickafus, Disorder in Pyrochlore Oxides, J. Am. Ceram. Soc., 83 (2000) 1873-1878.
  26. B. D. Cullity, S. R. Stock, Elements of X-Ray Diffraction, 3rd Ed., Prentice Hall, New Jersey (2001) 388.
  27. D. Michel, R. Collongues, Study by Raman Spectroscopy of Order-Disorder Phenomena Occurring in Some Binary Oxides with Fluorite-Related Structures, J. Raman Spectro., 5 (1976) 163-180. https://doi.org/10.1002/jrs.1250050208
  28. W.-J. Lee, Y.-S. Oh, S.-M. Lee, H.-T. Kim, D.-S. Lim, S. Kim, Fabrication and Characterization of 7.5 wt% $Y_2O_3-ZrO_2$ Thermal Barrier Coatings Deposited by Suspension Plasma Spray(in Korean), J. Korean Ceram. Soc., 51 (2014) 598-604. https://doi.org/10.4191/kcers.2014.51.6.598
  29. C. Kittel, P. McEuen, Introduction to Solid State Physics, Wiley and Sons, New York (1986) 125.