Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Odor Modeling of acetaldehyde in Gumi National Industrial Complex

구미국가산업단지의 아세트알데히드 악취모델링

  • Received : 2015.12.30
  • Accepted : 2016.01.12
  • Published : 2016.02.01
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Abstract

In this study CALPUFF modeling was performed to establish a correlation between regions of frequent civil odor complaints near Gumi national industrial complex and odor-emission facilities of synthetic fiber manufacturers in the same area as main acetaldehyde-emission point sources. As a result of the CALPUFF modeling, the maximum concentration of acetaldehyde in Gumi national industrial complex was reduced from O ($10^{-5}g/m^3$) to O ($10^{-6}g/m^3$) upon improving emission facilities of T company so that the maximum concentrations of acetaldehyde frequently appeared in complex 3. In addition, the predicted range of the maximum acetaldehyde concentration in Gumi national industrial complex was also improved in comparison with that prior to improving emission facilities of T company. These maximum concentrations of acetaldehyde obtained to estimate the expected contribution of total acetaldehyde point source by CALPUFF modeling showed the similar values to those measured in 'HAPs investigation in the region of Gumi-Daegu' and were consistent to the trend of civil odor complaints. Therefore, the expected contribution of total acetaldehyde point source was validated. The relative contribution of T company upon improving its emission facilities was predicted to be lowered by more than factor of two, compared to that prior to improving its emission facilities. To the contrary, the relative contribution of W company upon improving emission facilities of T company was predicted to be increased by more than factor of two, compared to that prior to improving emission facilities of T company. This indicates that the contribution of aldehyde point sources of W company was relatively increased upon improving emission facilities of T company.

본 연구에서는 CALPUFF 모델링을 수행하여 구미국가산업단지 공단지역에 악취로 인한 주민의 민원이 빈번한 지역과 아세트알데히드 배출 주요 점오염원인 구미국가산업단지 공단지역 합성섬유제조업체 악취배출시설과의 상관관계를 정립하고자 하였다. 본 연구의 CALPUFF 모델링 결과로서 T사 배출설비 개선 후에 구미공단의 아세트알데히드 농도의 최대값이 T사 배출설비 개선 전보다 O ($10^{-5}g/m^3$)에서 O ($10^{-6}g/m^3$)으로 저감되고 겨울(1월)과 봄(4월)에 구미 1공단의 아세트알데히드 농도가 개선되어서 구미 3공단에서 자주 아세트알데히드 농도의 구미공단 내 최대값이 도출되었다. 또한 T사 배출설비 개선 후에 도출된 아세트알데히드 농도의 구미공단 내 최대값 예측범위는 T사 배출설비 개선 전의 구미공단 내 최대값 예측범위보다 개선되었다. 이와 같은 총괄 점오염원의 아세트알데히드 기여도 평가 예측을 위한 CALPUFF 모델링 최대값은 '구미대구지역 HAPs 조사연구'의 측정 최대값 결과와 비교하였을 때에 상호 비교할 수 있는 비슷한 값을 보였고 민원추세와도 잘 일치하였다. 따라서 본 연구에서 총괄 점오염원의 아세트알데히드 기여도 평가 예측에 대한 유효성을 보여주었다. 한편 총괄 점오염원에서의 아세트알데히드 배출에 의하여 확산된 아세트알데히드 농도에 대한 T사 점오염원의 상대적 기여도가 T사 배출설비 개선 후에 개선 전보다 대부분 배 이상 낮아짐이 예측되었다. 반면에 이에 대한 W사 점오염원의 상대적 기여도는 T사 배출설비 개선 후가 T사 배출설비 개선 전보다 배 이상 증가하였다. 이것은 T사 배출설비 개선에 의하여 상대적으로 W사 점오염원의 아세트알데히드 기여도가 커졌음을 의미하였다.

Keywords

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