한국재료학회지 (Korean Journal of Materials Research)

  • 제26권1호
  • /
  • Pages.17-21
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  • 2016
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  • 1225-0562(pISSN)
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  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
권호 표지
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Pt@Cu/C Core-Shell Catalysts for Hydrogen Production Through Catalytic Dehydrogenation of Decalin

  • Kang, Ji Yeon (Department of Chemical Engineering, Myongji University) ;
  • Lee, Gihoon (Department of Chemical Engineering, Myongji University) ;
  • Jeong, Yeojin (Department of Chemical Engineering, Myongji University) ;
  • Na, Hyon Bin (Department of Chemical Engineering, Myongji University) ;
  • Jung, Ji Chul (Department of Chemical Engineering, Myongji University)
  • 투고 : 2015.11.30
  • 심사 : 2015.12.15
  • 발행 : 2016.01.27
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초록

Pt@Cu/C core-shell catalysts were successfully prepared by impregnation of a carbon support with copper precursor, followed by transmetallation between platinum and copper. The Pt@Cu/C core-shell catalysts retained a core of copper with a platinum surface. The prepared catalysts were used for hydrogen production through catalytic dehydrogenation of decalin for eventual application to an onboard hydrogen supply system. Pt@Cu/C core-shell catalysts were more efficient at producing hydrogen via decalin dehydrogenation than Pt/C catalysts containing the same amount of platinum. Supported core-shell catalysts utilized platinum highly efficiently, and accordingly, are lower-cost than existing platinum catalysts. The combination of impregnation and transmetallation is a promising approach for preparation of Pt@Cu/C core-shell catalysts.

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