Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Characterization of Eco-friendly Polyurethane Incorporating Soybean-oil-based Polyol

대두유 폴리올을 이용한 환경친화형 폴리우레탄의 합성 및 물성 연구

  • 옥주원 (건국대학교 유기나노시스템공학과) ;
  • 김풍기 (건국대학교 유기나노시스템공학과) ;
  • 조현상 (건국대학교 유기나노시스템공학과) ;
  • 권오경 ((주)비에스지) ;
  • 정원욱 ((주)비에스지) ;
  • 고준석 (건국대학교 유기나노시스템공학과)
  • Received : 2015.09.05
  • Accepted : 2015.10.04
  • Published : 2015.10.31
⟨ Previous Next ⟩

Abstract

An eco-friendly polyurethane incorporating a soybean-oil-based polyol was synthesized using a prepolymer method, and the chemical structure, molecular weights, and thermal properties of the polyurethane were characterized using instrumental analysis. The disperse and reactive dyeing properties of the eco-friendly polyurethane incorporating the soybean-oil-based polyol were compared to those of conventional petroleum-based polyurethane.

Keywords

References

  1. D. B. Kim, "Preparation of Dyeable Polyurethanes Containing an Acid Dye Enhancer and Their Coloration Properties", MSc Thesis, Konkuk University, Seoul, 2010.
  2. K. I. Kim and S. B. Kim, "Reserach Trend of Bio-polyurethane", KIC News, 2012, 15, 11-20.
  3. A. K. Mohanty, M. Misra, and G. Hinrichsen, "Biofibres, Biodegradable Polymers and Biocomposites: An Overview", Macromol. Mater. Eng., 2000, 1, 276-277.
  4. S. Miao, P. Wang, Z. Su, and S. Zhang, “Vegetable-oil-based Polymers as Future Polymeric Biomaterials”, Acta Biomaterialia, 2014, 10, 1692-1704. https://doi.org/10.1016/j.actbio.2013.08.040
  5. J. Pollack and A. L. Greig, "A Life Cycle Update of Soybean and Petroleum Based Polyols", Proceeding of Polyurethanes Technical Conference, p.696, Houston, Texas, 2010.
  6. J. S. Ko, J. H. Lee, and K. C. Sung, "A Study on the Bio- Polyurethane", J. Korean Oil Chemists' Soc., 2012, 29, 531-542.
  7. S. Tan, T. Abraham, D. Ference, and C. W. Macosko, "Rigid Polyurethane Foams from a Soybean Oil-based Polyol", Polymer, 2011, 52, 2840-2846. https://doi.org/10.1016/j.polymer.2011.04.040
  8. C. Fua, Z. Zheng, Z. Yang, Y. Chen, and L. Shen, “A Fully Biobased Waterborne Polyurethane Dispersion from Vegetable Oils: from Synthesis of Precursors by Thiol-ene Reaction to Study of Final Material”, Progress in Organic Coatings, 2014, 77, 53-60. https://doi.org/10.1016/j.porgcoat.2013.08.002
  9. L. Zhang, H. K. Jeon, J. Malsam, R. Herrington, and C. W. Macosko, “Substituting Soybean Oil-based Polyol into Polyurethane Flexible Foams”, Polymer, 2007, 48, 6656-6667. https://doi.org/10.1016/j.polymer.2007.09.016
  10. I. Mihail and P. S. Zoran in "Soybean-Applications and Technology" (T. B. Ng Ed.), InTech, 2011, pp.365-386.

Cited by

  1. On use of cellulose nanowhisker to enhance the physical properties of electrospun biopolyurethane vol.17, pp.1, 2016, https://doi.org/10.1007/s12221-016-5470-7