Journal of the Korean Wood Science and Technology

  • 제43권5호
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  • Pages.558-565
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  • 2015
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  • 1017-0715(pISSN)
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  • 2233-7180(eISSN)
한국목재공학회 (The Korean Society of Wood Science & Technology)
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A Gallotannin from Cercidiphyllum japonicum Leaves

  • Lee, Tae-Seong (Samcheok City Agricultural Technology and Extension Center) ;
  • Bae, Young-Soo (Department of Forest Biomaterials Engineering, College of Forest and Environment Sciences, Kangwon National University)
  • 투고 : 2015.03.13
  • 심사 : 2015.04.20
  • 발행 : 2015.09.25
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초록

Katsura tree (Cercidiphyllum japonicum Sieb. Et Zucc) leaves were collected, air-dried and extracted with 70% aqueous acetone, then concentrated and sequentially fractionated using n-hexane, methylene chloride ($CH_2Cl_2$), ethylacetate (EtOAc), and $H_2O$. The EtOAc fraction was chromatographed on a Sephadex LH-20 column with various aqueous MeOH eluting solvents and finally treated with acetone-$H_2O$ (7:3, v/v) to isolate a gallotannin. According to the NMR analysis, including HSQC and HMBC, and with the comparison of authentic literature data, the isolate was elucidated as 6-m-digalloyl-1,2,3,4-tetra-O-galloyl ${\beta}$-D-(+)-glucose, one of hydrolyzable tannins and one of gallotannins. The compound was only gallotannin which was firstly isolated from the extracts of Katsura tree leaves, and has not been reported before in domestic tree sources.

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참고문헌

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피인용 문헌

  1. Hydrolysable Tannins from Cercidiphyllum japonicum Bark vol.44, pp.4, 2016, https://doi.org/10.5658/WOOD.2016.44.4.559
  2. Extractives of Cercidiphyllum japonicum twigs: isolation and structural elucidation of a new galloylflavonol glycoside, anomeric tannins and flavonoids vol.72, pp.9, 2018, https://doi.org/10.1515/hf-2018-0029
  3. Chemical Constituents of the Flowers of Cercidiphyllum japonicum pp.1573-8388, 2019, https://doi.org/10.1007/s10600-019-02638-2