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수열합성법을 이용한 BaTiO3 나노분말 합성

Synthesis of Nano-Size BaTiO3 Powder by Hydrothermal Reaction Method

  • 심영재 (경상대학교 세라믹공학과) ;
  • 최경진 (경상대학교 세라믹공학과)
  • Shim, Young-Jae (Department of Ceramic Engineering, Engineering Research Institute, Gyeongsang National University) ;
  • Choi, Gyoung-Jin (Department of Ceramic Engineering, Engineering Research Institute, Gyeongsang National University)
  • 투고 : 2015.08.12
  • 심사 : 2015.08.18
  • 발행 : 2015.09.01

초록

Nano-size $BaTiO_3$ powder was synthesized by relatively simple hydrothermal reaction method. Finely dispersed Ti hydroxide precursor was first precipitated using $Ti(SO_4)_2$ and NaOH solution by applying ultrasonic power and washed thoroughly to remove $SO_4{^{2-}}$ and $Na^+$ ion. Then hydrothermal reaction was done at $160^{\circ}C$ for 6 hrs using solution prepared by washed Ti hydroxide precursor slurry and $Ba(OH)_2{\cdot}8H_2O$ with Ti:Ba mole ratio of 1:1. 200 ~ 500 nm size and uniform size distributed $BaTiO_3$ powder was synthesized by relatively low temperature and simple process.

키워드

참고문헌

  1. M. M. Vijatovic, J. D. Bobic, and B. D. Dtojanovic, Sci. Sinter, 40, 155 (2008). [DOI: http://dx.doi.org/10.2298/SOS0802155V
  2. J. T. Bailey and R. Russell Jr., Ceramic Bulletin, 47, 1025 (1968).
  3. P. K. Dutta and J. R. Gregg, Chem Mater., 4, 843 (1992). [DOI: http://dx.doi.org/10.1021/cm00022a019
  4. J. Azadmanjiri, H. K. Salehani, A. D. Hamedan, and M. Sadeghi, Solid State Phenom., 121, 53 (2007). [DOI: http://dx.doi.org/10.4028/www.scientific.net/SSP.121-123.53]
  5. S. Urek and M. Drofenik, Journal of European Ceramic Society, 18, 279 (1998). [DOI: http://dx.doi.org/10.1016/S0955-2219(97)00138-6]
  6. C. Xia, E. Shi, W. Zhong, and J. Guo, Journal of Crystal Growth, 166, 961 (1996). [DOI: http://dx.doi.org/10.1016/0022-0248(95)00521-8]
  7. Y. J. Shim, D. H. Kim, and H. S. Kim, Manufacturing Method of Titanium Dioxide Having Nano Particles, Titanium Dioxide Having Nano Particles Manufactured Using the Same Method, and a Solar Battery Using the Same Titanium Dioxide, KR Patent 2008-0072260 (2011).
  8. N. V. Tarakina, R. B. Neder, T. A. Denisova, L. G. Maksimova, Y. V. Baklanova, A. P. Tyutyunnik, and V. G. Zubkov, The Royal Society of Chemistry, 39, 8169 (2010).