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Preparation of Spherical Cobalt Fine Powders by New Liquid Reduction Method

새로운 용액환원법에 의한 구형 코발트 미세 분말의 제조

  • Received : 2015.06.18
  • Accepted : 2015.08.19
  • Published : 2015.08.28

Abstract

Spherical fine cobalt powders were fabricated by new liquid reduction method. Commercial cobalt sufate heptahydrate was used as raw material. Also ethylene glycol was used as solvent and hydrazine-sodium hypophosphite mixture was used as reduction agent for the new liquid reduction method. A plate shaped cobalt powders with an approximately 300 nm were prepared by a traditional wet ruduction method using distilled water as solvent and hydrazine. Spherical fine cobalt powders with an average size of $1-3{\mu}m$ were synthesized by a new liquid reduction method in 0.3M cobalt sulfate and 1.5M hydrazine-0.6M sodium hypophosphite mixture at 333K.

Keywords

References

  1. H. S. Hong, H. C. Jung, G. H. Kim, L. S. Kang and H. G. Suk: J. Korean Powder Metall. Inst., 20 (2013) 191 (Korean). https://doi.org/10.4150/KPMI.2013.20.3.191
  2. S. A. Salman, T. Usami, K. Kuroda and M. Okido: J. of Nanotechnology, 2014 (2014) 1.
  3. J. P. Chen, K. M. Lee and C. M. Sorenen: J. Appl. Phys., 75 (1994) 5876. https://doi.org/10.1063/1.355546
  4. H. S. Hong, Y. D. Ko, L. S. Kang, G. H. Kim and H. C. Jung: J. Korean Powder Metall. Inst., 18 (2011) 244 (Korean). https://doi.org/10.4150/KPMI.2011.18.3.244
  5. L. P. Zhu, W. D. Zhang, H. M. Xiao, Y. Yang and S. Y. Fu: J. Phys. Chem. C, 112 (2008) 10073. https://doi.org/10.1021/jp8019182
  6. S. Ohara, H. Ditaka, J. Zhang, M. Umetsu. T. Naka and T. Adschiri: J. Jpn. Soc. Powd. Powd. Met., 54 (2007) 635. https://doi.org/10.2497/jjspm.54.635
  7. J. Z. Gao, Y. C. Zhao, J. N. Tian, W. Yang, F. Guan, Y. J. Ma, J. G. Hou and J. W. Kang: Chinese Chemical Letters, 12 (2001), 555.
  8. S. H. An, S. H. Kim, J. H. Lee, H. S. Hong and Y. D. Kim: Kor. J. Mater. Res., 21 (2001) 327 (Korean).
  9. D. J. Kim, H. S. Chung, S. D. Woo, J. J. Lee and J. G. Ahn: J. of the Korean Crystal Growth and Crystal Technology, 12 (2002) 73 (Korean).
  10. D. J. Kim, H. S. Chung, S. D. Woo and J. J. Lee: J. of the Korean Association of Crystal Growth, 11 (2001) 290 (Korean).
  11. M. G. Montiel, P. S. Jacinto, J. A. I. D. Gongora, E. Reguera and G. R. Gattorno: Nano Micro Lett, 3 (2011) 12. https://doi.org/10.1007/BF03353646
  12. H. Yang, C. Shen, N. Song, Y. Wang, T. Yang, H. Gao and Z. Cheng: Nanotechnology, 21 (2010) 1.
  13. J. P. Kim: Trans. of the Korean Hydrogen and New Energy Society, 22 (2011) 35 (Korean).
  14. Y. Li, C. Lin and R. Cao: Int. J. of Refractory Metals & Hard Materials, 20 (2010) 270.
  15. D. J. Kim, H. S. Chung and K. Yu: Material Research Bullentin, 37 (2002) 2067. https://doi.org/10.1016/S0025-5408(02)00939-X
  16. J. H. Huang, C. Kargl-Simard, M. Oliazadeh and A. M. Alfantazi: Hydrometallurgy, 75 (2004) 77. https://doi.org/10.1016/j.hydromet.2004.06.008
  17. H. I. Won, H. H. Nersisyan and C. W. Won: Materials Chemistry and Physics, 133 (2012) 225. https://doi.org/10.1016/j.matchemphys.2012.01.014
  18. KIGAM: Korea, KR 10-2011-0122796 (2011).