DOI QR코드

DOI QR Code

주유소 유증기 회수설비 사용에 따른 가솔린 증기의 개인노출양상

Occupational Exposure Aspects of Gasoline Vapor According to the Use of a Gasoline Vapor Recovery System

  • 이희명 (연세대학교 보건대학원 및 산업보건연구소) ;
  • 원종욱 (연세대학교 의과대학 예방의학교실 및 산업보건연구소) ;
  • 김치년 (연세대학교 보건대학원 및 산업보건연구소) ;
  • 노재훈 (연세대학교 의과대학 예방의학교실 및 산업보건연구소)
  • Lee, Heemyung (Institute for Occupational Health & Graduate School of Public Health, Yonsei University) ;
  • Won, Jong-Uk (Institute for Occupational Health & Department of Preventive Medicine, Yonsei University College of Medicine) ;
  • Kim, Chi-Nyon (Institute for Occupational Health & Graduate School of Public Health, Yonsei University) ;
  • Roh, Jaehoon (Institute for Occupational Health & Department of Preventive Medicine, Yonsei University College of Medicine)
  • 투고 : 2014.02.24
  • 심사 : 2015.06.18
  • 발행 : 2015.06.30

초록

Objectives: The purpose of this study was to investigate the possible effects of a gasoline vapor recovery system on personal exposure levels of gasoline vapor constituents including benzene, toluene, ethyl benzene, xylene(BTEX), and methyl tert-butyl ether(MTBE) among gas station workers in a metropolitan area. Methods: Thirty-one gas station workers at ten gas stations in a metropolitan area were selected as subjects for this study. Test method PV2028 as recommended in the OSHA process was used for sampling and analysis. Results: The personal exposure levels of benzene, toluene, ethyl benzene, xylene, MTBE and gasoline vapor in the gas station workers were $0.0018{\pm}0.0069ppm$, $0.0077{\pm}0.0137ppm$, $0.0002{\pm}0.0008ppm$, $0.0016{\pm}0.0084ppm$, $0.2619{\pm}0.3340ppm$, and $1.4940{\pm}1.7984ppm$, respectively. After adjustment for refueling frequency and volume, personal exposure levelswere higher in the gas stations where gasoline vapor recovery systems(Stage II) were not installed, but the results were not statistically significant. Gasoline vapor concentrations showed a positive correlation to the level of MTBE, a gasoline additive. Conclusions: Vapor recovery systems(Stage II) were effective not only in reducing emissions of air pollutants, but also in reducing exposure to hazardous substances among gas station workers. In addition, acorrelation between gasoline vapors and MTBE concentration was confirmed.

키워드

참고문헌

  1. Ahmed FE. Toxicology and human health effects following exposure to oxygenated or reformulated gasoline. Toxicol Lett 2001. p. 89-113
  2. Amberg A, Rosner E, Dekant W. Biotransformation and kinetics of excretion of methyl tert-butyl ether in rats and humans. Toxicol Sci 1999; 51(1): 1-8 https://doi.org/10.1093/toxsci/51.1.1
  3. Amberg A, Rosner E, Dekant W. Toxicokinetics of methyl tert-butyl ether and Its metabolite in humans after oral exposure. Toxicol Sci 2001; 61(1): 62-67 https://doi.org/10.1093/toxsci/61.1.62
  4. American Conference of Governmental Industrial Hygienists(ACGIH). 2013 Threshold limit values for chemical substances and physical agents & biological exposure indices, Cincinnati. Ohio, ACGIH 2013
  5. An YJ, Lee WM. Effects of gasoline additive, methyl tert-butyl ether(MTBE) to human health and ecosystem. J Environ Toxicol 2006; 21(2); 93-102
  6. Belpoggi F, Soffritti M, Maltoni C. Methyl tertiary butyl ether(MTBE) a gasoline additive causes testicular and lympho haematopoietic cancer in rats. Toxicol Ind Health 1995; 11(2): 119-149 https://doi.org/10.1177/074823379501100202
  7. Belpoggi F, Soffritti M, Filippini F, Maltoni C. Result of long-term experimental studies on the carcinogenicity of methyl tert-butyl ether. Ann N Y Acad Sci 1997. p. 77-95
  8. Hakkola MA, Saarinen LH. Customer exposure to gasoline vapors during refueling at service stations. Appl Occup Environ Hyg 2000. p. 677-680
  9. Halder CA, Van Gorp GS, Hatoum NS, Warne TM. Gasoline vapor exposure. Part I. Characterization of workplace exposures. Am Ind Hyg Assoc J 1986; 47(3): 164-172 https://doi.org/10.1080/15298668691389522
  10. Hansen J. Elevated risk for male breast cancer after occupational exposure to gasoline and vehicular combustion products. Am J Ind Med 2000. p. 349-352
  11. Hartle R. Exposure to methyl tert-butyl ether and benzene among service station attendants and operators. Environ Health Persp 1993; 101(6): 23-26
  12. International Agency for Research on Cancer(IARC). Gasoline. In: Occupational exposure in petroleum refining; crude oil and major petroleum fuels. 1989. p. 9-11
  13. Johanson G, Nihlen A, Lof A. Toxicokinetics and acute effects of MTBE and ETBE in male volunteers. Toxicol Lett 1995. p. 713-718
  14. Kajihara H, Lshizuka S, Fushimi A, Masuda A, Nakanishi J. Population risk assessment of ambient benzene and evaluation of benzene regulation in gasoline in Japan. Environ Engg and Poicy 2000. p. 1-9
  15. McCoy M, Abernethy J, Johnson T. Anecdotal healthrelated complaint data pertaining to possible exposure to Methyl Tertiary Butyl Ether(MTBE): 1993 and 1994 Follow-up Surveys(1984-1994). American Petroleum Institute. 1995
  16. Mehlman MA. Dangerous and cancer-causing properties of products and chemicals in the oil refining and petrochemical industry: VIII. Health effects of motor fuels: Carcinogenicity of gasoline-Scientific update. Environmental research 1992; 59(1): 238-249. https://doi.org/10.1016/S0013-9351(05)80243-9
  17. Neasham D, Sifi A, Nielsen K, Overvad K, Raaschou-Nielsen O et al. Occupation and risk of lymphoma: a multicentre prospective cohort study(EPIC). Occup Environ Med 2011. p. 177-181
  18. Palma G De, Poli D, Manini P, Andreoli R, Mozzoni P et al. Biomarkers of exposure to aromatic hydrocarbons and methyl tert-butyl ether in petrol station workers. Biomarkers 2012; 17(4): 343-351 https://doi.org/10.3109/1354750X.2012.672459
  19. Periago JF, Prado C. Evolution of occupational exposure to environmental levels of aromatic hydrocarbons in service stations. Ann Occup Hyg 2005. p. 233-240
  20. Rekhadevi P, Mohammed F, Mohammed M, Paramjit Gl. Genotoxicity in filling station attendants exposed to petroleum hydrocarbons. Ann Occup Hyg 2010; 54(8): 944-954 https://doi.org/10.1093/annhyg/meq065
  21. Shin GA. Qualitative analysis and quantification of VOCs in ambient air at gasoline service station and roadsides. Environ Eng Res 1995. p. 669-672
  22. Song SH, Paik NW, Ha KC. A study on exposure to volatile organic compounds at gas stations in Korea. J Korea Soc Occup Environ Hyg 2000;10(1):58-73
  23. Tironi G, Hodgkins DG. Compliane with the OSHA benzene permissible exposure limit(PEL) at the gasoline vapor PEL. Appl Occup Environ Hyg 1991; 6(10): 881-884 https://doi.org/10.1080/1047322X.1991.10387981