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Provenance Study on Ancient Lead Glass Relics Using a Lead Isotope Ratio

납동위원소비를 이용한 고대 납유리 유물의 산지추정

  • Han, Min Su (Conservation Science Division, National Research Institute of Cultural Heritage) ;
  • Kim, So Jin (Conservation Science Division, National Research Institute of Cultural Heritage)
  • 한민수 (국립문화재연구소 보존과학연구실) ;
  • 김소진 (국립문화재연구소 보존과학연구실)
  • Received : 2015.06.12
  • Accepted : 2015.06.26
  • Published : 2015.06.30

Abstract

The purpose of the present study is to trace the provenance of lead raw materials using the lead isotope ratio of 9 lead glasses excavated from the Sarira hole of Mireuksaji stone pagoda and to determine correlation between them and other lead glasses excavated from the Wanggungri site. The results of chemical analysis of the 9 lead glasses show that they are common lead glass system($PbO-SiO_2$) with respect to the contents of PbO (70 wt.%) and $SiO_2$ (30 wt.%). The lead isotope ratios of them plot to northern Korean peninsula when applied to the distribution map of lead isotopes of East Asia. On the other hand, southern Korean peninsula is verified as the main deposits of the lead ore in the distribution map of lead isotopes of South Korea. With respect to the results, it is notable that the provenance of the 9 lead glasses can be very different depending on the distribution map. In addition, a comparative study between them and the lead glasses excavated from the Wanggungri which was built in the same region and period shows that their lead isotopes are highly correlated.

익산 미륵사지 석탑의 사리공 내에서 출토된 납유리 9점의 납동위원소비를 분석하여 납 원료의 산지를 추정하고, 이를 왕궁리 출토 납유리의 연구결과와 비교하여 상관관계를 알아보고자 하였다. 납유리는 주화학성분 분석결과, PbO가 약 70 wt.%, $SiO_2$가 약 30 wt.% 함유된 전형적인 $PbO-SiO_2$계의 유리였다. 납동위원소비를 이용한 납유리의 원료산지 추정결과, 기존 동북아시아 납동위원소비 분포도로는 대부분이 한국북부의 방연석 광산에 속하는 것으로 나타났다. 반면, 한반도 납동위원소비 분포도로는 한국남부의 방연석 광산이 납유리의 주요 원료 산지로 추정할 수 있어 두 분포도의 결과가 상이하게 나타났다. 또한 동일지역, 동시대에 조성된 것으로 알려진 왕궁리 출토 납유리의 기존 연구데이터와 비교한 결과, 납 원료의 산지가 서로 유사한 것으로 판단된다.

Keywords

References

  1. Brill, R.H. (1999) Chemical analyses of early glasses. The corning museum of glass, New York, 303-322.
  2. Brill, R.H. (1979) Lead isotope in some japanese and chinese glasses. Galley of Art, Washington D.C., 11, 87-110.
  3. Brill, R.H., Yamasaki, K., Barnes, I.L., Rosman, K.J.R., and Diaz, M. (1979) Lead isotopes in some japanese and chinese glasses. Ars Orientalis, 11, 87-109.
  4. Brill, R.H. and Wampler, J.M. (1967) Isotope studies in ancient lead. American Journal of Archaeology, 1, 77p.
  5. Choi, J., Lee, Y.J., Chong, T.C., Hong, H.S., Yun, Y.H., Kim, S.C., Song, C.H., and Pyun, C.H. (1996) Investigation on a potash-glass bead unearthed from Pyoungra-ri of around 5th century B.C.. Journal of Korea Traditional Science and Technology. 3(1), 15-32 (in Korean with English abstract).
  6. Jeong, Y.J., Cheong, C.S., Shin, D.B., Lee, K.S., Jo, H.J., Gautam, M.K., and Lee, I.S. (2012) Regional variations in the lead isotopic composition of galena from southern Korea with implications for the discrimination of lead provenance. Journal of Asian Earth Sciences, 61, 116-127. https://doi.org/10.1016/j.jseaes.2012.09.008
  7. Hwang, J.J., Kim, S.J., Han, W.R., and Han, M.S. (2014) Provenance study on lead isotope of bronze relics excavated from Cheonghaejin. Journal of Mineralogical Society of Korea, 27(4), 263-270 (in Korean with English abstract). https://doi.org/10.9727/jmsk.2014.27.4.263
  8. Han, M.S. (2014) Scientific Analysis of Glass Beads Relics. Sarira Reliquary of Stone Pagoda of Mireuksa Temple Site in Iksan, National Research Institute of Cultural Heritage & Jeollabuk-do, 238-247 (in Korean).
  9. Kang, H.T., Kim, S.B., Huh, W.Y., and Kim, G.H. (2003) Application of science for interpreting archaeological materials(II): Production and flow of lead glass from Mireuksa temple. Korean Journal of Cultural Heritage Study, 36, 241-266 (in Korean with English abstract).
  10. Kang, H.T., Chung, G.R., Huh, W.Y., Kim, S.B., and Cho, N.C. (2004) Chemical composition and lead isotope ratios of the lead glass from Wanggung-ni, Iksan, Chollabuk-do. Journal of Korean Ancient Historical Society, 45, 31-41 (in Korean with English abstract).
  11. Kang, H.T., Chung, Y.D., Cho, J.Y., and Kim, H.S. (2005) Analysis of glaze on brick, green-glazed earthenware in Unified Silla Period. Journal of Prehistoric and Ancient, 22, 211-222 (in Korean with English abstract).
  12. Kim, G.H. (2000) Scientific analysis and interpretation for ancient glass bead in Korea. Journal of Leeum, 5, 73p (in Korean with English abstract).
  13. Kim, G.H. (2001) A study of archaeological chemistry on ancient glasses found in Korea, P.D. Thesis, University of Chungang, Seoul, 1-42 (in Korean with English abstract).
  14. Koizuka, R.T. (1994) Studies of ancient silicate glass by chemical methods. Proceeding of the Korea and Japan Joint Research, 136-137 (in Japanese and Korean).
  15. Koezuka, T. and Yamadsaki, K. (1Chemical compositions of ancient glasses found in Japan: A historical survey995) , Proceedings of XVII International Congress on Glass. Chinese Ceramic Society, 469-474.
  16. Lee I.S. (1989) Analytical study of ancient glass in Korea (I). Korean Antiquity, 34, 79-93 (in Korean with English abstract).
  17. Lee, I.S. (1990) Archaeological study of ancient glass in Korea, Ph.D. Thesis, University of Hanyang, Seoul, 1p (in Korean with English abstract).
  18. Mabuchi, H. and Hirao, Y. (1983) The study of Han-type mirror by lead isotope ratio method(2), Museum, 382, 16-26 (in Japanese).
  19. Mabuchi, H. (1985) The lead isotope systematics in Asia and near East, Grant Report to the Ministry of Education. Science and Culture, Japan, 19 (in Japanese).
  20. Mabuchi, H. and Hirao, Y. (1987) Lead isotope ratios of lead ores in East Asia: In relation to bronze artifacts. Journal of the Archaeological Society of Nippon, 73(2), 199-245 (in Japanese).
  21. NRICH (2012) Lead isotope analysis and field survey of galena deposits in south Korea. National Research Institute of Cultural Heritage, 68-100 (in Korean with English abstract).
  22. Park, S.O. (2005) East Asia spread of western culture: Focused on the ancient glass to move the forces to gradually East Asia. China and Sinology, 3, 2-3 (in Korean).

Cited by

  1. 익산 미륵사지 석탑 사리공 내 출토 고대 유리 유물의 성분특성 분석 vol.33, pp.3, 2017, https://doi.org/10.12654/jcs.2017.33.3.06