Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Fabrication of Silica-Containing Breathable Waterproof Polyurethane Dispersion Film

Silica를 함유하는 Polyurethane dispersion 투습방수 Film의 제조

  • Shin, Hyun-Ki (Department of Textile System Engineering, Kyungpook National University) ;
  • Huh, Man-Woo (Department of Nursing, Kyungil University) ;
  • Yoon, Nam-Sik (Department of Textile System Engineering, Kyungpook National University)
  • 신현기 (경북대학교 섬유시스템공학과) ;
  • 허만우 (경일대학교 간호학과) ;
  • 윤남식 (경북대학교 섬유시스템공학과)
  • Received : 2015.05.16
  • Accepted : 2015.06.16
  • Published : 2015.06.27
Download PDF
⟨ Previous Next ⟩

Abstract

Silica-polyurethane hybrid breathable films were prepared and their breathabilities were assessed. Appropriately aggregated silica was prepared through sol-gel reaction of water glass and its particle size ranged 360~500nm. The polyurethane dispersion was prepared by the reaction of isophorone diisocyanate(IPDI) as diisocyanate and polytetramethylene glycol(PTMG) and dimethylol propionic acid(DMPA) as polyol, particle size ranging 30~120nm. The reaction between isocyanate and hydroxyl group to form urethane bonding was checked by the intensity of the stretch peak of isocyanate at $2270cm^{-1}$ in the FT-IR. The silica was incorporated into polyurethane dispersion and casted into film. It was shown that the incorporated silica(1~5wt.%) increased water vapour permeability of the films by 30~100%, and decreased the hydrostatic pressure by 10~40%. From the results, it could be concluded that the appropriate hybridization of silica can increase the breathability of polyurethane dispersion film, while minimizing the loss of hydrostatic pressure.

Keywords

References

  1. A. Gugliuzza and E. Drioli, A Review on Membrane Engineering for Innovation in Wearable Fabrics and Protective Textiles, J. of Membrane Science, 446, 350(2013). https://doi.org/10.1016/j.memsci.2013.07.014
  2. C. J. Painter, Waterproof, Breathable Fabric Laminates: A Perspective from Film to Market Place, J. of Coated Fabrics, 26, 107(1997).
  3. N. S. Save, M. Jassal, and A. K. Agrawal, Smart Breathable Fabric, J. of Industrial Textiles, 34(3), 139(2005). https://doi.org/10.1177/1528083705047905
  4. J. C. Gretton, D. B. Brook, H. M. Dyson, and S. C. Harlock, Moisture Vapor Transport through Waterproof Breathable Fabrics and Clothing Systems under a Temperature Gradient, Textile Research J., 68(12), 936(1998). https://doi.org/10.1177/004051759806801209
  5. D. L. Green, L. McAmish, and A. V. McCormick, Three-dimensional Pore Connectivity in Bi-axially Stretched Microporous Composite Membranes, J. of Membrane Science, 279, 100(2006). https://doi.org/10.1016/j.memsci.2005.11.051
  6. J. H. Yang, N. S. Yoon, I. K. Kim, and J. H. Yeum, Fabrication of Waterproof and Moisture-permeable Polyurethane Nanofiber Multi- Membrane, Textile Coloration and Finishing, 23(2), 107(2011). https://doi.org/10.5764/TCF.2011.23.2.107
  7. S. D. Kim and S. S. Kim, Improvement of Serviceability of Waterproof and Moisturepermeable Nylon Fabric, Textile Coloration and Finishing, 7(1), 23(1995).
  8. E. Y. Kim, J. H. Lee, D. J. Lee, Y. H. Lee, and H. D. Kim, Synthesis and Properties of Highly Hydrophilic Waterborne Polyurethane-ureas Containing Various Hardener Content for Waterproof Breathable Fabrics, J. of Applied Polymer Science, 129(4), 1745(2013). https://doi.org/10.1002/app.38860
  9. H. Quan and Z. Gu, Influences of Soft Monomers on the Application Properties of Hydrophilic Polyurethane with Mixed Polyether Segment, Advanced Materials Research, 331, 139(2011). https://doi.org/10.4028/www.scientific.net/AMR.331.139
  10. S. Mondal and J. L. Hu, Structural Characterization and Mass Transfer Properties of Nonporoussegmented Polyurethane Membrane: Influence of the Hydrophilic Segment Content and Soft Segment Melting Temperature, J. of Membrane Science, 276, 16(2006). https://doi.org/10.1016/j.memsci.2005.09.029
  11. J. H. Hwang, K. S. Oh, and N. S. Yoon, Fluoroalkylation of the Surface of Hydrophilic Polyurethane Breathable Membrane, Textile Coloration and Finishing, 25(1), 30(2013). https://doi.org/10.5764/TCF.2013.25.1.30
  12. C. J. Brinker and G. W. Scherer, "Sol-gel Science the Physics and Chemistry of Sol-gel Processing", Academic Press, Boston, pp.99-107, 1990.
  13. Y. M. Evtushenko, B. E. Zaitsev, and V. M. Ivanov, Determination of Phenylurethane and Isocyanate Groups in Isocyanates, J. of Analytical Chemistry, 54(3), 219(1999).
  14. H. G. Wissman, L. Rand, and K. C. Frisch, Kinetics of Polyether Polyols-diisocyanate Reactions, J. of Applied Polymer Science, 8(6), 2971(1964). https://doi.org/10.1002/app.1964.070080639
  15. A. M. Usmani, Reactions for Polyurethane Coatings, Organic Coatings, 8, 65(1986).
  16. G. Menges, H. Schwesig, and G. Hahn, Quantitative Determination of Reaction in PUR Foam Formation, Organic Coatings and Plastics Chemistry, 44, 229(1981).
  17. S. Li, R. Vatanparast, and H. Lemmetyinen, Crosslinking Kinetics and Swelling Behaviour of Aliphatic Polyurethane, Polymer, 41(15), 5571(2000). https://doi.org/10.1016/S0032-3861(99)00785-5
  18. H. C. Tsai, P. D. Hong, and M. S. Yen, Preparation and Physical Properties of MDEA-based Polyurethane Cationomers and their Application to Textile Coatings, Textile Research J., 77(9), 710(2007). https://doi.org/10.1177/0040517507080544
  19. M. H. Min, C. H. Jeong, S. H. Yoon, J. H. Yang, and T. K. Kim, Application Properties of Ultra Light Weight Silica Aerogel to Polyurethane Membrane, Textile Coloration and Finishing, 25(4), 287(2013). https://doi.org/10.5764/TCF.2013.25.4.287

Cited by

  1. Chemical Structural Approach to Understand Global Prohibition on Perfluorinated Compounds and their Uses vol.28, pp.3, 2016, https://doi.org/10.5764/TCF.2016.28.3.134
  2. Enhancement of Dyeing Fastness of Artificial Suede (3) vol.28, pp.4, 2016, https://doi.org/10.5764/TCF.2016.28.4.280