Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation and Characterization of Silver Nanoparticles by Polyols at Different Reduction Rates

환원력이 다른 폴리올을 이용한 은 나노입자의 제조 및 특성 고찰

  • Park, Hanna (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Kim, Min Hee (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Park, Won Ho (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 박한나 (충남대학교 공과대학 유기소재.섬유시스템공학과) ;
  • 김민희 (충남대학교 공과대학 유기소재.섬유시스템공학과) ;
  • 박원호 (충남대학교 공과대학 유기소재.섬유시스템공학과)
  • Received : 2015.05.01
  • Accepted : 2015.06.02
  • Published : 2015.06.30
⟨ Previous Next ⟩

Abstract

In this study, silver particles were prepared using two polyols at different reduction rates under controlled experimental conditions. Isosorbide was employed as a novel polyol reductant for silver particles, and its reduction rate in the polyol process was compared with ethylene glycol (EG). When the isosorbide reductant was used in the polyol process, silver particles could be formed. However, the reduction rate of isosorbide was slower than that of EG, and the resultant silver particles thus had anisotropic shapes. Additionally, the size of silver particles was dependent on the presence and amount of the PVP stabilizer. Therefore, the shape and size of silver particles were mainly affected by the reduction rate and stabilizer, respectively.

Keywords

References

  1. A. A. Ashkarran, S. Estakhri, M. R. H. Nezhad, and S. Eshghi, "Controlling the Geometry of Silver Nanostructures for Biological Applications", J. Phys. Procedia, 2013, 40, 76-83. https://doi.org/10.1016/j.phpro.2012.12.011
  2. V. S. Tiwari, T. Oleg, G. K. Darbha, W. Hardy, J. P. Singh, and P. C. Ray, "Non-resonance SERS Effects of Silver Colloids with Different Shapes", J. Chem. Phys. Lett., 2007, 446, 77-82. https://doi.org/10.1016/j.cplett.2007.07.106
  3. B. Wiley, Y. Sun, and Y. Xia, "Synthesis of Silver Nanostructures with Controlled Shapes and Properties", J. Acc. Chem. Res., 2007, 40, 1067-1076. https://doi.org/10.1021/ar7000974
  4. R. Jin, Y. Cao, C. A. Mirkin, K. L. Kelly, G. C. Schatz, and J. G. Zheng, "Photoinduced Conversion of Silver Nanospheres to Nanoprisms", J. Science, 2001, 294, 1901-1903. https://doi.org/10.1126/science.1066541
  5. Y. Zhang, P. Yang, and L. Zhang, "Ag Nanostructures with Various Shapes Created Through Degradation of Rods", J. Mater. Chem. Phys., 2013, 138, 767-772. https://doi.org/10.1016/j.matchemphys.2012.12.055
  6. S. H. Im, Y. T. Lee, B. Wiley, and Y. Xia, "Large‐scale Synthesis of Silver Nanocubes: The Role of HCl in Promoting Cube Perfection and Monodispersity", J. Angew Chem., 2005, 117, 2192-2195. https://doi.org/10.1002/ange.200462208
  7. J. J. Zhu, C. X. Kan, J. G. Wan, M. Han, and G. H. Wang, "High-yield Synthesis of Uniform Ag Nanowires with High Aspect Ratios by Introducing the Long-chain PVP in an Improved Polyol Process", J. Nanomater, 2011, 2011, 40.
  8. K. S. Chou and C. Y. Ren, "Synthesis of Nanosized Silver Particles by Chemical Reduction Method", J. Mater. Chem. Phys., 2000, 64, 241-246. https://doi.org/10.1016/S0254-0584(00)00223-6
  9. Z. Zhang, B. Zhao, and L. Hu, "PVP Protective Mechanism of Ultrafine Silver Powder Synthesized by Chemical Reduction Processes", J. Solid State Chem., 1996, 121, 105-110. https://doi.org/10.1006/jssc.1996.0015
  10. P. S. Mdluli, N. M. Sosibo, P. N. Mashazi, T. Nyokong, R. T. Tshikhudo, A. Skepu, and E. Van Der Lingen, "Selective Adsorption of PVP on the Surface of Silver Nanoparticles: A Molecular Dynamics Study", J. Mol. Struct., 2011, 1004, 131-137. https://doi.org/10.1016/j.molstruc.2011.07.049
  11. Y. Tang, W. He, G. Zhou, S. Wang, X. Yang, Z. Tao, and J. Zhou, "A New Approach Causing the Patterns Fabricated by Silver Nanoparticles to be Conductive Without Sintering", Nanotechnology, 2012, 23, 355304(6pp). https://doi.org/10.1088/0957-4484/23/35/355304
  12. Y. Xiong, I. Washio, J. Chen, H. Cai, Z. Y. Li, and Y. Xia, "Poly (vinyl pyrrolidone): A Dual Functional Reductant and Stabilizer for the Facile Synthesis of Noble Metal Nanoplates in Aqueous Solutions", J. Langmuir, 2006, 22, 8563-8570. https://doi.org/10.1021/la061323x
  13. Y. Sun, B. Gates, B. Mayers, and Y. Xia, "Crystalline Silver Nanowires by Soft Solution Processing", Nano Letters, 2002, 2, 165-168. https://doi.org/10.1021/nl010093y
  14. D. Chen and L. Gao, "Large-scale Growth and End-to-end Assembly of Silver Nanorods by PVP-directed Polyol Process", J. Cryst Growth, 2004, 264, 216-222. https://doi.org/10.1016/j.jcrysgro.2003.12.019
  15. C. Jia, P. Yang, and A. Zhang, "Glycerol and Ethylene Glycol Co-mediated Synthesis of Uniform Multiple Crystalline Silver Nanowires", J. Mater Chem. Phys., 2014, 143, 794-800. https://doi.org/10.1016/j.matchemphys.2013.10.015
  16. B. Khodashenas and H. R. Ghorbani, "Synthesis of Silver Nanoparticles with Different Shapes", Arabian Journal of Chemistry, 2015, In press.
  17. S. Coskun, B. Aksoy, and H. E. Unalan, "Polyol Synthesis of Silver Nanowires: An Extensive Parametric Study", Crystal Growth & Design, 2011, 11, 4963-4969. https://doi.org/10.1021/cg200874g

Cited by

  1. Fabrication and Characterization of Ag Particles by Polyol Process and Wet Chemical Process vol.23, pp.4, 2016, https://doi.org/10.4150/KPMI.2016.23.4.297