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Stability Improvement of CdTe Solar Cells using ZnTe:Na Back Contact

Na 도핑된 ZnTe 후면전극을 이용한 CdTe 태양전지의 안정성 개선에 관한 연구

  • Cha, Eun Seok (Department of Materials Science and Engineering, KAIST) ;
  • Park, Kyu Charn (Department of Materials Science and Engineering, KAIST) ;
  • Ahn, Byung Tae (Department of Materials Science and Engineering, KAIST)
  • 차은석 (한국과학기술원 신소재공학과) ;
  • 박규찬 (한국과학기술원 신소재공학과) ;
  • 안병태 (한국과학기술원 신소재공학과)
  • Received : 2015.02.22
  • Accepted : 2015.03.03
  • Published : 2015.03.31

Abstract

Cu doping by copper or $Cu_2Te$ materials enhances p+ formation in CdTe near the back contact interface, allowing better formation of ohmic contact. However, the Cu in CdTe junction is also considered as a principal component of CdTe cell degradation. In this paper, Na-doped ZnTe layer was employed as a back contact material to improve the stability of CdTe solar cells. As a process variable, post $CdCl_2$ treatment of CdS/CdTe film was conducted before or after depositing ZnTe:Na on CdTe. The change of the photovoltaic properties of CdTe cells were investigated with aging time. Low-temperature photoluminescence analysis was conducted to describe the degradation mechanism. The result showed that the CdTe solar cells with better stability compare to Cu contact were achieved using an optimized ZnTe:Na back contact.

Keywords

References

  1. A. L. Fahrenbruch. and R. H. Bube, "Fundamentals of solar cells", New York, Academic Press.
  2. P. V. Meyers, "Design of a thin film CdTe solar cell", Solar cells, Vol. 23, p.59-67, 1988. https://doi.org/10.1016/0379-6787(88)90007-5
  3. J.Britt and C.Ferekides, Thin-film CdS/CdTe solar cell with 15.8% efficiency, Applied physics letter, Vol.62 (22), pp. 2851-2852, 1993. https://doi.org/10.1063/1.109629
  4. T. Takamoto, T. Agui, H.Kurita and M. Ohmori, "Improved junction procedure for low temperature deposited CdS/CdTe solar cells", Solar Engergy Materials and Solar cells, Vol.49, p.219-225, 1997. https://doi.org/10.1016/S0927-0248(97)00198-0
  5. X.Wu, "High-efficiency polycrystalline CdTe thin-film solar cells", Solar energy Vol.77, p.803-814, 2004. https://doi.org/10.1016/j.solener.2004.06.006
  6. J. Ma, D. Kuciauskas, D. Albin, R. Bhattacharya, M. Reese, T. Barnes, J. V. Li, T. Gessert and S. H. Wei, Dependence of the minority-carrier lifetime on the stoichiometry of CdTe using time-resolved photoluminescence and first principles calculations, "Physical review letters", Vol. 111, p.067402-1-067402-5, 2013. https://doi.org/10.1103/PhysRevLett.111.067402
  7. B. E. McCandless, Y. Qu and R. W. Birkmire, "A treatment to allow contacting CdTe with different conductors",1st WCPEC, p.107-110, IEEE, 1994.
  8. J. H. Yun, K. H. Kim, D. Y. Lee and B. T. Ahn, "Back contact formation using $Cu_2Te$ as a Cu-doping source and as an electrode in CdTe solar cells", Solar energy materials and soalr cells, Vol.75, p.203-210, 2003. https://doi.org/10.1016/S0927-0248(02)00157-5
  9. J. H. Yun, E. S. Cha, B. T. Ahn, H. S. Kwon and E. A. Al-Ammar, "Performance improvement in CdTe solar cells by modifying the CdS/CdTe interface with a Cd treatment", Current applied physics, Vol.14, p.630-635, 2014. https://doi.org/10.1016/j.cap.2013.11.036
  10. B. T. Ahn, J. H. Yun, E. S. Cha and K. C. Park, "Understanding the junction degradation mechanism in CdS/CdTe solar cells using a Cd-deficient CdTe layer, Current applied physics, Vol.12, p.174-178, 2012. https://doi.org/10.1016/j.cap.2011.05.031
  11. S. Demtsu and J.Sites and D. Albin, "Role of Copper in the performance of CdS/CdTe solar cells", 4th WCPEC, IEEE, 2006.
  12. K. C. Park, E. S. Cha and B. T. Ahn, "Sodium-doping of ZnTe film by close-spaced sublimation for back contact of CdTe solar cell", Current applied physics, Vol. 11, p.S109-S112, 2011.
  13. G. Y. Chung and B. T. Ahn, "Electrical properties of CdTe films prepared by close-spaced sublimation with screen-printed source layers", Journal of Appplied physics, Vol.78, p. 5493-5498, 1995. https://doi.org/10.1063/1.359665