Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
권호 표지
DOI QR코드

DOI QR Code

Isotherm, Kinetic and Thermodynamic Characteristics for Adsorption of Congo Red by Activated Carbon

활성탄에 의한 Congo Red의 흡착에 대한 등온선, 동력학 및 열역학적 특성

  • Lee, Jong Jib (Division of chemical Engineering, Kongju National University)
  • 이종집 (공주대학교 화학공학부)
  • Received : 2014.11.17
  • Accepted : 2014.12.22
  • Published : 2015.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

Batch experiment studies were carried out for adsorption of congo red using granular activated carbon with various parameters such as activated carbon dose, pH, initial dye concentration, temperature and contact time. Equilibrium experimental data are fitted to the Langmuir, Freundlich, Temkin and Dubin-Radushkevich isotherm equations. From Freundlich's separation factor (1/n) estimated, adsorption could be employed as effective treatment method for adsorption of congo red from aqueous solution. Base on Temkin constant (B) and Dubinin-Radushkevich constant (E), this adsorption process is physical adsorption. Adsorption kinetics has been tested using pseudo-first order and pseudo second order models. The results followed pseudo second order model with good correlation. Adsorption process of congo red on granular activated carbon was endothermic (${\Delta}H$=42.036 kJ/mol) and was accompanied by decrease in Gibbs free energy (${\Delta}G$=-2.414 to -4.596 kJ/mol) with increasing adsorption temperature.

본 연구는 활성탄에 의한 congo red의 흡착 거동에 대해 회분식 실험을 통해 알아보았다. 흡착변수로 흡착제의 양, pH, 초기농도와 접촉시간과 온도를 사용하였다. 흡착평형자료는 Langmuir, Freundlich, Temkin 및 Dubin-Radushkevich 식에 적용하여 보았다. 평가된 Freundlich 분리계수(1/n)로부터 활성탄에 의한 congo red의 흡착공정이 적절한 처리방법이 될 수 있음을 알았고, Temkin 상수(B)와 Dubinin-Radushkevich 상수(E)로부터 물리흡착공정임을 알았다. 동력학적 실험을 통해 흡착공정이 유사이차반응속도식에 잘 일치함을 알았다. 입상활성탄에 대한 congo red의 흡착공정은 발열반응(${\Delta}H$=42.036 kJ/mol)이었고, Gibbs 자유에너지값(${\Delta}G$=-2.414~-4.596 kJ/mol)은 온도가 증가할수록 감소하였다.

Keywords

References

  1. Ahmad, R., Kumar, R., "Adsorptive Removal of Congo Red Dye from Aqueous Solution Using Bael Shell Carbon," Appl. Surf. Sci., 257(5), 1628-1633(2010). https://doi.org/10.1016/j.apsusc.2010.08.111
  2. Cestari, A. R., Vieira F. S., Vieira, G. S. and Almeida, L. E., "Aggregation and Adsorption of Reactive Dyes in the Presence an Anionic Surfactant on Mesoporous Aminopropyl Silica," J. Colloid. Interf. Sci., 309, 402-411(2007). https://doi.org/10.1016/j.jcis.2006.11.049
  3. Bagha A. R. T., Nikkar, H., Mahmoodi, N. M., Markazi, M. and Menger, F. M., "The Sorption of Cationic Dyes onto Kaolin: Kinetic, Isotherm and Thermodynamic Studies," Desalination, 266, 274-280(2011). https://doi.org/10.1016/j.desal.2010.08.036
  4. Mittal, A., Mittal, J., Malviya, A. and Gupta, V. K., "Adsorptive Removal of Hazardous Anionic Dye Congo red from Wastewater Using Waste Materials and Recovery by Desorption," J. Colloid Interf. Sci., 340, 16-26(2009). https://doi.org/10.1016/j.jcis.2009.08.019
  5. Hartono, B., Ismadji, A., Sudaryanto, Y. and Irawaty, W., "Utilization of Teak Sawdust from the Timber Industry as a Precursor of Activated Carbon for the Removal of Dyes from Synthetic Effluent," J. Ind. Chem. Chem., 11(6), 864-869(2005).
  6. Hema, M. and Arivoli, S., "Comparative Study on the Adsorption Kinetics and Thermodynamics of Dyes onto Acid Activated Low Cost Carbon," Int. J. Phys. Sci., 2(1), 10-17(2007).
  7. Mozumder, M. S. I. and AndIslam, M. A., "Development of Treatment Technology for Dye Containing Industrial Wastewater," Sci. Res., 2(3), 567-576(2010).
  8. Sandeman, S. R., Gun'ko, V. M., Bakalinska, O, M., Howell, C. A., Zheng, Y., Kartel, M. T., Phillips, G. J. and Mikhalovsky, S. V., "Adsorption of Anionic and Cationic Dyes by Activated Carbons, PVA Hydrogels and PVA/AC Composite," J. Colloid and Interf. Sci., 358, 582-592(2011). https://doi.org/10.1016/j.jcis.2011.02.031
  9. Hou, H., Zhou, R., Wu, P. and Wu, L., "Removal of Congo Red Dye from Aqueous Solution with Hydroxyapatite/Chitosan Composite," Chem. Eng. J., 211-212, 336-342(2012). https://doi.org/10.1016/j.cej.2012.09.100
  10. Akl, M. A., Youssef, A. M. and Al-Awadhi, M. M., "Adsorption of Acid Dyes onto Bentonite and Surfactant-modified Bentonite," J. Anal. Bioanal. Tech., 4(4), 2-7(2013).
  11. Garg, V. K., Kumar, R. and Gupta, R., "Removal and Recovery of Malachite Green Dye from Aqueous Solution by Adsorption Using Agro-industry Waste: a Case Study of Prosopis Cineraria," Dyes Pigments, 62, 1-10(2004). https://doi.org/10.1016/j.dyepig.2003.10.016
  12. Namasivayam, C. and Yamuna R. T., "Removal of Congo Red from Aqueous Solutions by Biogas Waste Slurry," J. Chem. Technol. Biotechnol., 53, 153-157(1992).
  13. Namasivayam, C. and Kavitha, D., "Removal of Congo Red from Water by Adsorption onto Activated Carbon Prepared from Coir Pith, an Agricultural Solid Waste," Dyes Pigments, 54, 47-58(2002). https://doi.org/10.1016/S0143-7208(02)00025-6
  14. Won, S. W., Wu, G., Ma, H., Liu, Q., Yah, Y., Cui, L., Liu, C. and Yun, Y. S., "Adsorption Performance and Mechanism in Binding of Reactive Red 4 by Coke Waste," J. Hazard. Mater., B138, 370-317(2006).
  15. Tan, I. A. W., Ahmad, A. L. and Hameed, B. H., "Adsorption of Basic Dye on High-Surface-Area Activated Carbon Prepared from Coconut Husk," J. Hazard. Mater., 154, 337-346(2008). https://doi.org/10.1016/j.jhazmat.2007.10.031
  16. Sivakumar, P. and Palanisamy, P. N., "Adsorption Studies of Basic Red 29 by a Non Conventional Activated Carbon Prepared from Euphorbia Antiquorum L," Int. J. Chem. Tech. Res., 1(3), 502-510 (2009).
  17. Jain, M., Garg, V. and Kadirvelu, D K., "Chromium (VI) Removal from Aqueous Solution, Using Sunflower Stem Waste," J. Hazard. Mater., 162, 365-372(2009). https://doi.org/10.1016/j.jhazmat.2008.05.048
  18. Zhang, Li, Y., Zhang, C. and Jing, Y., "Adsorption of Malachite Green from Aqeous Solution onto Carbon Prepared from Arundo Donax Root," J. Hazard. Mater., 150, 774-782(2008). https://doi.org/10.1016/j.jhazmat.2007.05.036
  19. Samiey, B. and Toosi, A., "Kinetics and Thermodynamics Adsorption of Congo Red on Cellulose," Central Eur. J. Chem., 8, 906-912(2010). https://doi.org/10.2478/s11532-010-0055-6
  20. Lee, J. J., "Adsorption Behavior and Kinetic Characteristic of Cibacron Brilliant red 3B-A by Activated Carbon," Korean Chem. Eng. Res., 52(4), 486-491(2014). https://doi.org/10.9713/kcer.2014.52.4.486
  21. Sulak, M. T., Demirbas, E. and Kobya, M., "Removal of Astrazon Yellow 7GL from Aqueous Solutions by Adsorption onto Wheat Bran," Bioresour. Technol., 98, 2590-2598(2007). https://doi.org/10.1016/j.biortech.2006.09.010

Cited by

  1. Isotherm, kinetic, and thermodynamic studies on the adsorption behavior of 10-deacetylpaclitaxel onto Sylopute vol.22, pp.5, 2017, https://doi.org/10.1007/s12257-017-0247-4
  2. 활성탄을 이용한 Acid Green 27의 흡착평형, 동역학 및 열역학 파라미터의 연구 vol.55, pp.4, 2015, https://doi.org/10.9713/kcer.2017.55.4.514
  3. 폐감귤박 활성탄을 이용한 항생제 Dimetridazole의 흡착특성 vol.55, pp.6, 2015, https://doi.org/10.9713/kcer.2017.55.6.798
  4. 실로퓨트에 대한 2-피콜린의 흡착 특성 평가 vol.57, pp.2, 2015, https://doi.org/10.9713/kcer.2019.57.2.210
  5. 실로퓨트에 의한 Taxus chinensis 유래 7-에피-10-디아세틸파클리탁셀의 흡착에 대한 평형, 등온흡착식, 동역학 및 열역학적 특성 vol.58, pp.1, 2020, https://doi.org/10.9713/kcer.2020.58.1.113