DOI QR코드

DOI QR Code

대기용해 시 내화물 도가니의 종류가 가돌리늄(Gadolinium)을 함유한 듀플렉스 스테인레스 강의 미세조직에 미치는 영향

The Effect of Refractory Crucible on Microstructure of Duplex Stainless Steel Cast with Gadolinium during Air Induction Melting

  • 안지호 (한국생산기술연구원 주조공정그룹) ;
  • 임재한 (한국생산기술연구원 주조공정그룹) ;
  • 문병문 (한국생산기술연구원 주조공정그룹)
  • Ahn, Ji-Ho (Liquid Processing & Casting R&D Group, Korea Institute of Industrial Technology) ;
  • Lim, Jae-han (Liquid Processing & Casting R&D Group, Korea Institute of Industrial Technology) ;
  • Moon, Byung-Moon (Liquid Processing & Casting R&D Group, Korea Institute of Industrial Technology)
  • 투고 : 2015.07.16
  • 심사 : 2015.10.02
  • 발행 : 2015.10.31

초록

This paper reports the effect of a refractory crucible type on the microstructure of duplex stainless steel (DSS) cast with the addition of gadolinium using air-induction melting. Grade 4A DSSs with 1 wt% of gadolinium (Gd) were fabricated in various crucibles including alumina ($Al_2O_3$), magnesia (MgO), calcia (CaO) coated with yttria ($Y_2O_3$) and graphite. The standard free energies of the formation of calcium and yttrium oxide were lower than those of gadolinium oxide and other crucible elements based oxide. The yield of Gd in DSS using $Al_2O_3$, MgO, CaO-coated $Y_2O_3$ and graphite was 5, 19, 83 and 96%, respectively. As Gd yield increased, the amount of Gd-based inclusions increased, the size of the inclusions were reduced, and the inclusions became evenly distributed.

키워드

참고문헌

  1. Nilsson JO, Materials science and technology 8.8, "Super duplex stainless steels", (1992) 685-700.
  2. Olson J and Nordin S, Proc. The Hague, "Duplex Stainless Steels Symp", (1986) 219-225.
  3. Perteneder E, Tosch J, Reiterer P and Rabensteiner G, Proc. The Hague, "Duplex Stainless Steels Symp", (1986) 48-56.
  4. Hong CHEN, Ding TS, Jun LI, Xiao XS, Zhao JL and Jiang LZ, Journal of Iron and Steel Research International, "A New Economical Sigma-Free Duplex Stainless Steel 19Cr-6Mn-1. 0Mo-0. 5Ni-0. 5W-0. 5Cu-0. 2N", 18 (2011) 52-57.
  5. Blanco G, Bautista A and Takenouti H, Cement and Concrete Composites, "EIS study of passivation of austenitic and duplex stainless steels reinforcements in simulated pore solutions", 28 (2006) 212-219. https://doi.org/10.1016/j.cemconcomp.2006.01.012
  6. Hall EO and Algie SH, Metallurgical reviews, "The sigma phase", 11 (1966) 61-88.
  7. Martins Marcelo and Luiz Carlos Casteletti, Materials Characterization "Sigma phase morphologies in cast and aged super duplex stainless steel", 60 (2009) 792-795. https://doi.org/10.1016/j.matchar.2009.01.005
  8. Gupta CK and Krishnamurthy N, International Materials Reviews, "Extractive metallurgy of rare earths", 37 (1992) 197-248. https://doi.org/10.1179/imr.1992.37.1.197
  9. Kim ST, Jeon SH, Lee IS and Park YS, Corrosion Science "Effects of rare earth metals addition on the resistance to pitting corrosion of super duplex stainless steel-Part 1", 52 (2010) 1897-1904. https://doi.org/10.1016/j.corsci.2010.02.043
  10. LIU X, Yang JC, YANG L and Gao XZ, Journal of iron and steel research, international "Effect of Ce on inclusions and impact property of 2Cr13 stainless steel" 17 (2010) 59-64.
  11. Kuang JP, Harding RA and Campbell J, Materials Science and Technology "Investigation into refractories as crucible and mould materials for melting and casting ${\gamma}$-TiAl alloys" 16 (2000) 1007-1016. https://doi.org/10.1179/026708300101508964
  12. Ku KM, Ryu HY, Kim SH, Kim DY, Hwang IS, Sim JB and Lee JH, Journal of Nuclear Fuel Cycle and Waste Technology (JNFCWT) "Chemical stability evaluation of ceramic materials for liquid cadmium cathode" 11 (2013) 23-29. https://doi.org/10.7733/jkrws.2013.11.1.23
  13. ASTM A890 - standard specification for castings, ironchromium- nickel-molybdenum corrosion-resistant, duplex (austenitic/ferritic) for general applicationASTM, West Conshohocken, USA (2000).
  14. Copeland MI, Krug M, Armantrout CE and Kato H, No. BMRI- 5925. Bureau of Mines. Albany Metallurgy Research Center, "Iron-gadolinium phase diagram" Ore, (1961).