Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Charge Transfer Dye Probe for Thiol-containing Amino Acid

황원자를 함유한 아미노산 검출용 전하이동형 색소에 관한 연구

  • Shin, In Sub (Graduate School of Environment and Information Sciences, Yokohama National University) ;
  • Gwon, Seon Yeong (Department of Textile System Engineering, Kyungpook National University) ;
  • Matsumoto, Shinya (Graduate School of Environment and Information Sciences, Yokohama National University) ;
  • Kim, Sung Hoon (Department of Textile System Engineering, Kyungpook National University)
  • 신인섭 (요코하마 국립대학 환경정보연구원) ;
  • 권선영 (경북대학교 섬유시스템공학과) ;
  • 마츠모토 신야 (요코하마 국립대학 환경정보연구원) ;
  • 김성훈 (경북대학교 섬유시스템공학과)
  • Received : 2015.10.07
  • Accepted : 2015.11.26
  • Published : 2015.12.27
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Abstract

Two new D-${\pi}$-A dyes were synthesized by the condensation reaction between active methyl and aromatic aldehyde and its biothiol sensing properties in DMSO/water were investigated by UV-vis spectroscopy. Upon addition of $Hg^{2+}$, the solution of D-${\pi}$-A dyes showed color change and the absorption band shows a formation of a dye-$Hg^{2+}$ coordination complex. These dyes exhibited high selectivity for $Hg^{2+}$ as compared with other cations. The dye-$Hg^{2+}$ could be recovered by adding glutathion(GSH). The absorption intensity of dye-$Hg^{2+}$ increased only by the addition of glutathione(GSH). The competition experiments revealed that no obvious interference was observed by performing the titration with the mixture of glutathione(GSH) and other amino acids. The results indicated that these D-${\pi}$-A dyes were highly selective for glutathione(GSH) detection.

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References

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