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A Study of Optimal Conditions in Distillation for Production of Schisandra Chinensis Fruit Spirits

오미자 과실 증류주의 제조를 위한 증류 최적조건 연구

  • Cho, Hye-Seom (Dept. of Convergence Industry, Seoul Venture University) ;
  • Cheong, Chul (Dept. of Convergence Industry, Seoul Venture University)
  • 조혜섬 (서울벤처대학원대학교 융합산업학과) ;
  • 정철 (서울벤처대학원대학교 융합산업학과)
  • Received : 2015.07.01
  • Accepted : 2015.09.11
  • Published : 2015.09.30

Abstract

This study is conducted to develop and optimize fruit spirits by using Schizandra chinensis fruit which are rarely used as spirits in the world. For this purpose, the raw material, main compounds of fermented mash and, quality characteristics of distilled liquor prepared with different distillation methods were analyzed. The studt period lasted six months and the results were follows. Schizandra chinensis was not suitable for alcohol fermentation because the sugar concentration and acidity were low. Therefore, the fermentation condition was appropriate to mix with the weight ratio of fresh Schizandra chinensis fruit, water and sugar as 1:1.5:0.25, and was fermented the mix by adding 0.06 w/w% of $(NH_4)_2HPO_4$ compared to the must total weight. It was also examined to analyze product characteristics of fruit spirits prepared with different methods of distillation(column-pot still, pot still, vacuum still). The result showed that fruit spirits made by vacuum still with fresh Schizandra chinensis fruit indicated the best product quality while the distillation of column-pot still showed the best yield.

본 연구의 목적은 동양이 원산지이고 세계적으로 증류주 제조에 활용된 사례가 드문 오미자를 활용하여 오미자 과실 증류주를 개발하고 최적조건 확립을 하는데 있다. 이를 위해 오미자 원료분석 및 발효주의 주요 성분과 증류주를 증류 방식별로 제조한 후 증류주의 품질특성을 분석하였다. 연구기간은 6개월 소요되었고 그 분석 결과는 다음과 같다. 오미자는 당도와 pH가 낮고, 유기산 함량이 높아 효모의 알코올 발효에 적합하지 않아 생오미자 : 물 : 설탕 중량비율을 1 : 1.5 : 0.25 로 혼합한 후 과즙 총량 대비 $(NH_4)_2HPO_4$을 0.06 w/w%를 첨가하여 효모(SIHA Aktivhefe6 Brennereihefe)를 사용 발효시켰다. 주요 발효부산물로서 이소부탄올과 이소아밀알코올이 검출되었다. 한편 증류 방식별(다단식 증류, 단식 증류, 감압식 증류)로 제조한 과실증류주의 품질특성 분석을 위해 발효 과정, 에틸알코올 생산수율, 유기산과 향기성분 함량, 향기 패턴 및 관능을 평가한 결과 생 오미자를 사용한 경우 감압식 증류기로 제조한 과실증류주가 품질이 가장 우수한 것으로 나타났고, 다만 증류방식 중 원료 투입량 대비 과실증류주 수율이 가장 높은 것은 다단식 증류방식으로 나타났다.

Keywords

References

  1. K. H. Lee, "Studies on Fine Spirits Aging [Part I]-On the Aptitude of the Korean Oak Varieties as Barrels for Aging Apple Fine Spirits", Journal of the Korean Society for Applied Biological Chemistry, Vol. 20, No. 1, pp. 66-80, 1977.
  2. Y. K. Min, H. S. Yun, H. S. Jeong, "Studies on the Distillation Operation of Baikha - ju", Journal of the Korean Society for Applied Biological Chemistry, Vol. 37, No. 1, pp. 9-13, 1994.
  3. D. S. Lee, H. S. Park, K. Kim, T. S. et al, "Physicochemical Characteristics of Korean Folk Sojues", Korean J. Food SCI Technol, Vol. 26, No. 5, 649-654, 1994.
  4. H. C. Cho, S. A. Kang, S. I. Choi, et al, "Quality Characteristics of Fruit Spirits from a Copper Distillation Apparatus", Journal of the Korean Society of Food Science and Nutrition, Vol. 42, No. 5, 743-752, 2013. DOI: http://dx.doi.org/10.3746/jkfn.2013.42.5.743
  5. H. Y. In, T. S. Lee, D. S. Lee, et al, "Volatile Components and Fusel Oils of Sojues and Mashes Brewed by Korean Traditional Method", Korean Society of Food Science and Technology, Vol. 27, No. 2, pp. 235-240, 1995.
  6. D. S. Lee, H. S. Park, K. Kim, T. S. et al, "Determination and Multivariate Analysis of Flavour Components in the Korean Folk Sojues Using GC-MS", Korean Society of Food Science and Technology, Vol. 26, No. 6, pp. 750-758, 1994.
  7. K. H. Bae, K. S. Shin, H. Y. Ryu, et al, "Identification and Fermentation Characteristics of Lactic Acid Bacteria Isolated from the Fermentation Broth of Korean Traditional Liquor, Andong-Soju", Korean Journal of Microbiology and Biotechnology, Vol.35, No.4, pp. 310-315, 2007.
  8. H. R. Kim, B. H. Ahn, "Research trend of Korean traditional alcoholic beverage", Food industry and nutrition, Vol. 6, No. 3, pp. 5-10, 2001.
  9. S. M. Bea, S. Y. Jung, I. S. Jung, et al, "Effect of the Amount of Water on the Yield and Flavor of Korean Distilled Liquor Based on Rice and Corn Starch", Journal of the East Asian Society of Dietary Life, Vol. 13, No. 5, pp. 439-446, 2003.
  10. L. H. Ryu, Y. M. Kim, "Esterification of Alcohols with Organic Acids during Distilled Spirit Distillation", The Korean Journal of Food And Nutrition, Vol. 15, No. 4, pp. 295-299, 2002.
  11. H. C. Yi, S. H. Moon. J. S. Park, et al. "Volatile Compounds in Liquor Distilled from Mash Produced Using Koji or Nuruk under Reduced or Atmospheric Pressure", Journal of the Korean society of food science an nutrition, Vol. 39, No. 6, pp. 880-886, 2010. https://doi.org/10.3746/jkfn.2010.39.6.880
  12. Y. Y. Min, H. S. Yun, H. S. Jeong, et al. "Changes in Compositions of Liquor Fractions Distilled from Samil-ju with Various Distillation Conditions", Korean Society of Food Science and Technology, Vol. 24 No. 5, pp. 440-446, 1992.
  13. Y. H. Lee, T. K. Eom, C. Cheong, et al. "Quality Characteristics of Spirits by Different Distillation and Filtrations", Journal of the Korean society of food science and nutrition, Vol. 42, No. 12, pp. 2012-2018, 2013. https://doi.org/10.3746/jkfn.2013.42.12.2012
  14. G. E. Martin, J. M. Burgraff, R. H. Dyer, et al. "Gas-Liquid Chromatographic determination of congeners in alcoholic products with confirmation by Gas Chromatography/Mass Spectrometer", J. Assoc. of Anal. Chem, Vol. 64, No. 3. pp. 186-189. 1981.
  15. G. H. Reanzin, S. Baldwin, H. S. Scales, "Determination of the congeners produced from ethanol during whisky maturation", J. Assoc. of Anal. Chem, Vol. 59, No. 2, pp. 770-776, 1976.
  16. J. PVidal, S. Estreguil, R. Cantegrel, "Quantitative Analysis of cognac carbonyl compounds at the ppb level by GC-MS of their o-derivatives", Chromatography, Vol. 38, No. 6, pp. 183-189, 1993.
  17. C. Pinheiro, C. M. Rodrigues, T. Schfer, et al. "Monitoring the aroma production during wine-must fermentation with an elec-tronic nose", Biotechnol. Bioeng, Vol. 77, No. 4, pp. 632-640, 2002. DOI: http://dx.doi.org/10.1002/bit.10141
  18. C. Cimander, T. Bachinger, C. F. Mandenius, "Assessment of perfor-mance of a fed-batch cultivation from the preculture quality using an electronic nose", Biotechnol. Progr. Vol. 18, No. 2, pp. 380-386, 2002. DOI: http://dx.doi.org/10.1021/bp010166j
  19. National Tax Service Liquors Licence Aid Center, Analysis Rule, 2008.
  20. J. W. Lee, S. A. Kang, C. Cheong, "Quality Characteristics of Distilled Alcohols Prepared with Different Fermenting Agents", J Korean Soc appl Biol Chem, Vol. 58, No. 2, pp. 275-283, 2015. https://doi.org/10.1007/s13765-015-0028-8
  21. J. C. Kim, S. H. Lee, H. R. Min, et al. Enology, Baeksan publishing, 2009.
  22. Owaki, K, "A view of sake components Carbonyl", J Soc Brew Jpn, Vol. 62, No. 7, pp. 1097-1105, 1967. https://doi.org/10.6013/jbrewsocjapan1915.62.1097
  23. L. Nykanen, I. Nykanen, Distilled beverages. In Volatile compounds in foods and beverages, New York, Marcel Dekker, Inc, 1991.
  24. D. H. Kim, Food chemistry, Tamgudang publishing, 1988.
  25. D. H. Lee, J. W. Jung, Y. S. Lee, et al. "Fermentation Characteristics for Preparation of Distilled Liquor Made of Mixed Grains:, Korean J Food Sci. Technol. Vol. 46, No. 6, pp. 694-701. 2014. DOI: http://dx.doi.org/10.9721/KJFST.2014.46.4.446
  26. M. C. Meligard, "Prediction of flavor differences between beers from their chemical composition", J Agric Food Chem Vol. 30, No. 3, pp. 1009-1017, 1982. DOI: http://dx.doi.org/10.1021/jf00114a002