Journal of Korea Technical Association of The Pulp and Paper Industry (펄프종이기술)

Korea Technical Association of the Pulp and Paper Industry (한국펄프종이공학회)
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Cadmium Adsorption Characteristic of Cellulose-gel Manufacture using Alkali Solvent

알칼리 용제를 이용하여 제조한 셀룰로오스 겔의 카드뮴 흡착특성

  • Hwang, Kyo-Jung (Dept. of Biological and Environmental Science, Dongguk University) ;
  • Kwon, Gu-Joong (Dept. of Biological and Environmental Science, Dongguk University) ;
  • Yang, Ji-Wook (Dept. of Biological and Environmental Science, Dongguk University) ;
  • Hwang, Won-Jung (Dept. of Forest Products, Korea Forest Research Institute) ;
  • Hwang, Jae-Hyun (Dept. of Food Industrial Management, Dongguk University) ;
  • Kim, Dae-Young (Dept. of Biological and Environmental Science, Dongguk University)
  • 황교정 (동국대학교 바이오환경과학과) ;
  • 권구중 (동국대학교 바이오환경과학과) ;
  • 양지욱 (동국대학교 바이오환경과학과) ;
  • 황원중 (국립산림과학원 임산공학부 목재가공과) ;
  • 황재현 (동국대학교 식품산업관리학과) ;
  • 김대영 (동국대학교 바이오환경과학과)
  • Received : 2015.11.10
  • Accepted : 2015.12.17
  • Published : 2015.12.30
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Abstract

This study was carried out to investigate the characterization of cadmium adsorption by cellulose hydrogel and aerogel. Hydrogel and aerogel were made from ashless pulp dissolved in alkali hydroxide-urea aqueous solution and manufactured in film and bead types. After regeneration of cellulose, hydrogel went through the process of substitution of organic solvent and freeze-dry in order to make aerogel. SEM was used to analyze the microstructure of hydrogel and aerogel. Experiment was conducted in various concentrations and pH conditions to find out the characteristic of cadmium adsorption. After that, EDS was used to identify existence and distribution of cadmium in hydrogel and aerogel. The result from comparisons of cadmium adsorption shows that bead type aerogel has the maximum cadmium adsorption and film type hydrogel has the minimum cadmium adsorption.

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References

  1. Lee, H. S., Characteristics of cadmium biosorption and desorption by brown marine algae, Journal of the Korean Environmental Sciences Society 8(2):249-254 (1999).
  2. Yanagisawa, H., Matsumoto, Y., and Machida, M., Adsorption of Zn(II) and Cd(II) ions onto magnesium and activated carbon composite in aqueous solution, Journal of Surface Science 256(6):1619-1623 (2010). https://doi.org/10.1016/j.apsusc.2009.10.010
  3. Duruibe, J. O., Ogwuegbu, M. O. C., and Egwurugwu, J. N., Heavy metal pollution and human biotoxic effects, International Journal of Physical Sciences 2(5):112-118 (2007).
  4. Crini, G., Recent developments in polysaccharide- based materials used as adsorbents in wastewater treatment, Progress in Polymer Science 30:38-70 (2005). https://doi.org/10.1016/j.progpolymsci.2004.11.002
  5. Go, Y. M., Sutliff, R. L., Chandler, J. D., Khalidur, R., Kang, B. Y., Anania, F. A., Orr, M., Hao, L., Fowler, B. A., and Jones, P., Low-dose cadmium causes metabolic and genetic dysregulation associated with fatty liver disease in mice, Toxicological Sciences 147(2):524-534 (2015). https://doi.org/10.1093/toxsci/kfv149
  6. Chauhan, G. S., Chauhan, K., Chauhan, S., Kumar, S., and Kumari, A., Functionalization of pine needles by carboxymethylation and network formation for use as supports in the adsorption of $Cr^{6+}$, Carbohydrate Polymers 70(4):415-421 (2007). https://doi.org/10.1016/j.carbpol.2007.04.020
  7. Jang, M. K. and Nah, J. W., Characterization of chitin and chitosan as a biomedical polymer, J. Korean Ind. Eng. Chem. 19(5):457-465 (2008).
  8. Papageorgiou, S. K., Katsaros, F. K., Kouvelos, E. P., and Kanellopoulos, N. K., Prediction of binary adsorption isotherms of $Cu^{2+}$, $Cd^{2+}$, and $Pb^{2+}$ on calcium alginate beads from single adsorption data, Journal of Hazardous Materials 162:1347-1354 (2009). https://doi.org/10.1016/j.jhazmat.2008.06.022
  9. Krishnapriya, K. R. and Kandaswamy, M., A new chitosan biopolymer derivative as metal- complexing agent: Synthesis, characterization, and metal(II) ion adsorption studies, Carbohydrate Research 345(14):2013-2022 (2010). https://doi.org/10.1016/j.carres.2010.06.005
  10. Kwon, G. J., Kim, D. Y., Kim, E. J., and Kang, J. H., Adsorption capacity of lead on holocellulose aerogels synthesized from an alkali hydroxide-urea solution, Journal of the Korean Physical Society 67(4):687-693 (2015). https://doi.org/10.3938/jkps.67.687
  11. Jiang, M., Jin, M., Lu, X. Q., and Chen, Z., Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay, Desalination 252:33-39 (2010). https://doi.org/10.1016/j.desal.2009.11.005
  12. Unuabonah, E. I., Adebowale, K. O., Olu- Owolabi, B. I., Yang, L. Z., and Kong, L. X., Adsorption of Pb(II) and Cd(II) from aqueous solutions onto sodium tetraborate-modified kaolinite clay: Equilibrium and thermodynamic studies, Hydrometallurgy 93:1-9 (2008). https://doi.org/10.1016/j.hydromet.2008.02.009
  13. Naeem, A., Woertz, J. R., and Fein, J. B., Experimental measurement of proton, Cd, Pb, Sr, and Zn adsorption onto the fungal species Saccharomyces Cerevisiae , Environmental Science & Technology 40:5724-5729 (2006). https://doi.org/10.1021/es0606935
  14. Al-Ghouti, M. A., Li, J., Salamh, Y., Al- Laqtah, N., Walker, G., and Ahmad, M. N., Adsorption mechanisms of removing heavy metals and dyes from aqueous solution using date pits solid adsorbent, J. Hazardous Materials 176:510-520 (2010). https://doi.org/10.1016/j.jhazmat.2009.11.059

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