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방직용 재생펄프 제조를 위한 면 린터의 자기가수분해 공정 개발

Development of Auto-hydrolysis Method for Preparing Cotton Linter Regenerated Fibers of Textile Fabrics

  • 손하늘 (충남대학교 환경소재공학과) ;
  • 박희정 (충남대학교 환경소재공학과) ;
  • 서영범 (충남대학교 환경소재공학과)
  • Sohn, Ha Neul (Dept. of Bio-based Materials, Chungnam National University) ;
  • Park, Hee Jung (Dept. of Bio-based Materials, Chungnam National University) ;
  • Seo, Yung Bum (Dept. of Bio-based Materials, Chungnam National University)
  • 투고 : 2015.11.09
  • 심사 : 2015.12.16
  • 발행 : 2015.12.30

초록

The molecular weight (MW) and crystallinity of cotton linter need to be controlled to be dissolved well in N-methylmorpholine N-oxide (NMMO) solvent for manufacturing regenerated fibers of clothing fabrics. Electron beam irradiation or sulfuric acid pre-treatment followed by alkaline peroxide bleaching has been used to control MW effectively and to improve brightness of cotton linter. Auto-hydrolysis of cotton linter without electron beam irradiation or chemical pre-treatment was found to be effective as an alternative pre-treatment method. Removal of metal ions, that hampered dissolution of cotton linter by NMMO, was also investigated when the auto-hydrolysis was accompanied with ionic polymers and chelating agent.

키워드

참고문헌

  1. Kim, G. S. and Cha, J. Y., Cellulose and lyocell fibers, Tech. Trend Report, Korea Institute of Science and Technology Information (2003).
  2. Gang, T. J. and Cha, J. Y., Characterization and utilization of cellulose, BioWave 9(7):1-11 (2007).
  3. Park, Y. C. and Kim, G. J., Cotton cellulose regenerated fiber, Fiber Technology and Industry 14(2):71-77 (2010).
  4. Park, H. J., Han, J. S., Son, H. N., and Seo, Y. B., Study of cotton linter pre-treatment process for producing high quality regenerated fibers for fabrics, Journal of Korea TAPPI 45(3):27-35 (2013).
  5. Zhang, W., Okubayashi, S., and Thomas, B., Fibrillation tendency of cellulosic fibers: Part 3. Effects of alkali pretreatment of lyocell fiber, Carbohydrate Polymers 59(2):173-179 (2005). https://doi.org/10.1016/j.carbpol.2004.09.007
  6. Lee, S., Kim, J. W., and Jin, S. H., The Effect of chemical crosslinking in alkaline solution on fibrillation tendency and dyeability of lyocell fiber, Journal of the Korean Oil Chemists' Society 27(2):168-174 (2010).
  7. Huong, M. B., Anelise, E., and Thomas, B., Pilling in cellulosic fabrics, Part 2: A study on kinetics of pilling in alkali-treated lyocell fabrics, Journal of Applied Polymer Science 109(6):3696-3703 (2008). https://doi.org/10.1002/app.28570
  8. Yue, Y., A Comparative study of cellulose I and II fibers and nano-crystals, Master's Thesis, School of Renewable Natural Resources, Louisiana State Univ. (2011).
  9. Park, S. K., Baker, J. O., Himmel1, M. E., Parilla, P. A., and Johnson, D. K., Cellulose crystallinity index: Measurement techniques and their impact on interpreting cellulase performance, Biotechnology for Biofuels 12:3-10 (2010).
  10. Kumar, A., Negi1, Y. S., Choudhary, V., and Bhardwaj, N. K., Characterization of cellulose nano-crystals produced by acid-hydrolysis from sugarcane bagasse as agro-waste, Journal of Materials Physics and Chemistry 2(1):1-8 (2014).
  11. Liu, Y. and Hu, H., X-ray diffraction study of bamboo fibers treated with NaOH, Fibers and Polymers 9(6):735-739 (2008). https://doi.org/10.1007/s12221-008-0115-0
  12. Park, D. H., Lee, M. W., Jung, S. Y., and Seo, Y. B., Study of variations of cotton linter pulp characteristics by electron-beam treatment, Proceeding of Spring Conference of Korea TAPPI, pp. 157-167 (2011).
  13. Seo, Y. B., Lee, M. W., Park, D. H., and Park, H. J., Use of a low-energy electron beam for degree of polymerization control of cotton linter, Industrial Engineering Chemistry Research 52(2):692-695 (2013). https://doi.org/10.1021/ie300521w
  14. Park, J. S., Development of electron beam radiation technology to regulate the molecular weight of cellulose materials, Master's Thesis, Chungnam National University (2011).
  15. Chen, X., Lawoko, M., and van Heiningen, A. R. P., Kinetics and mechanism of autohydrolysis of hardwoods, Bioresource Technology 101:7812-7819 (2010). https://doi.org/10.1016/j.biortech.2010.05.006
  16. Tunc, M. S. and van Heiningen, A. R. P., Characterization and molecular weight distribution of carbohydrates isolated from the autohydrolysis extract of mixed southern hardwoods, Carbohydrate Polymers 83:8-13 (2011). https://doi.org/10.1016/j.carbpol.2010.07.015
  17. Garrote, G., Dominguez, H., and Parajo, J., Hydrothermal processing of lignocellulosic materials, European Journal of Wood and Wood Products 57(3):191-202 (1999). https://doi.org/10.1007/s001070050039
  18. Han, Q., Autohydrolysis pretreatment of lignocellulosic biomass for bioethanol production, Doctorial Thesis, NC State Univ., Raleigh, North Carolina (2014).
  19. Morton, J. H., Viscosity/DP relationships for cellulose dissolved in cuprammonium and cupriethylene diamine solvents, In The Chemistry and Processing of Wood Plant Fibrous Materials, Kennedy, J. F., Phillips, G. O., and Williams, P. A. (ed), Woodhead Publishing Ltd., England, pp. 151-158 (1996).