Bulletin of the Korean Chemical Society

  • 제35권12호
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  • Pages.3482-3488
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  • 2014
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Errors in Isotope Dilution Caused by Matrix-induced Mass Bias Effect in Quadrupole Inductively Coupled Plasma-Mass Spectrometry

  • Pak, Yong-Nam (Department of Chemistry Education, Korea National University of Education)
  • 투고 : 2014.07.02
  • 심사 : 2014.08.08
  • 발행 : 2014.12.20
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초록

Matrix-induced mass bias and its effect on the accuracy of isotope ratio measurements have been examined for a quadrupole-based inductively coupled plasma-mass spectrometer (Q ICP-MS). Matrix-induced mass bias effect was directly proportional to % mass difference, and its magnitude varied for element and nebulizer flow rate. For a given element and conditions in a day, the effect was consistent. The isotope ratio of Cd106/Cd114 under $200{\mu}g\;g^{-1}$ U matrix deviated from the natural value significantly by 3.5%. When Cd 111 and Cd114 were used for the quantification of Cd with isotope dilution (ID) method, the average of differences between the calculated and measured concentrations was -0.034% for samples without matrix ($0.076{\mu}g\;g^{-1}$ to $0.21{\mu}g\;g^{-1}$ for the period of 6 months). However, the error was as large as 1.5% for samples with $200{\mu}g\;g^{-1}$ U. The error in ID caused by matrix could be larger when larger mass difference isotopes are used.

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피인용 문헌

  1. Correction of Errors Caused by Matrix-induced Mass Bias in Quadrupole Inductively Coupled Plasma-Mass Spectrometry Isotope Dilution Method vol.36, pp.11, 2015, https://doi.org/10.1002/bkcs.10562
  2. Atomic spectrometry update: review of advances in atomic spectrometry and related techniques vol.31, pp.5, 2016, https://doi.org/10.1039/C6JA90020H
  3. Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Imaging in Biology vol.121, pp.19, 2021, https://doi.org/10.1021/acs.chemrev.0c01219