DOI QR코드

DOI QR Code

Removal Efficiency of Heavy Metals and Nutrients by Zeolite and Basic Oxygen Furnace Slag

제올라이트와 제강슬래그에 의한 중금속과 영양염류 복합오염물질의 제거 효과

  • Kim, Yongwoo (Environmental Standard Management Office, Korea Environmental Industry & Technology Institute) ;
  • Oh, Myounghak (Coastal Development & Ocean Energy Research Division, Korea Institute of Ocean Science & Technology) ;
  • Park, Junboum (Department of Construction & Environmental Engineering, Seoul National University) ;
  • Kwon, Osoon (Coastal Development & Ocean Energy Research Division, Korea Institute of Ocean Science & Technology)
  • Received : 2014.07.08
  • Accepted : 2014.08.19
  • Published : 2014.11.01

Abstract

Permeable reactive barrier has been recognized as the one of representative methods for remediation of contaminated groundwater. Reactive barrier system containing two and more reactive materials can remove multiple contaminants such as nutritive salts and heavy metals. In this study, removal efficiency of multiple contaminants was evaluated when both zeolite and basic oxygen furnace slag were used as reactive materials. Sequential batch test which consists of two materials was performed to evaluate removal efficiency comparing the reaction order of them against nutritive slats including ammonium and phosphate and heavy metal including cadmium. As a result, zeolite-basic oxygen furnace slag sequence batch test showed the best efficiency for removal of multiple contaminants including nutritive salts and heavy metal.

투수성 반응벽체 공법은 지하수 오염을 정화하는 대표적인 방법 중의 하나이다. 영양염류와 중금속 등 여러 가지 오염물질이 동시에 존재하는 경우 두 가지 이상의 반응성 매질을 적용한 반응벽체공법으로 복합오염물질의 제거가 가능하다. 본 연구에서는 반응성 매질로 제올라이트와 제강슬래그를 함께 사용하는 경우 복합오염물질의 제거능을 평가하였다. 영양염류인 암모늄과 인산염, 중금속인 카드뮴이 혼합된 복합오염물질에 대하여 연속회분식실험을 통하여 제올라이트 및 제강슬래그와의 반응순서에 따른 오염물질 제거능을 분석하였다. 연속회분식실험 결과에 의하면 제올라이트-제강슬래그 순서로 반응하는 경우 영양염류와 중금속의 복합오염물질에 대한 제거능이 더 좋은 것으로 나타났다.

Keywords

References

  1. 윤길림, 김한선 (2011), 준설토 활용공학, 도서출판 씨아이알, pp. 20-27.
  2. ASTM (2008), Standard test method for 24-h batch-type measurement of contaminant sorption by soils and sedimentsm, ASTM D4646-03, Pennsylvania, USA.
  3. Balkaya, N. and Cesur, H. (2008), Adsorption of cadmium from aqueous solution by phosphogypsum, Chemical Engineering Journal, Vol. 140, No. 1-3, pp. 247-254. https://doi.org/10.1016/j.cej.2007.10.002
  4. Blanchard, G., Maunaye, M. and Martin, G. (1984), Removal of heavy metals from waters by means of natural zeolites, Water Research, Vol. 18, No. 18, pp. 1501-1507. https://doi.org/10.1016/0043-1354(84)90124-6
  5. Dimitrova, S. and Mehanjiev, D. (2000), Interaction of blastfurnace slag with heavy metal ions in water solutions, Water research, Vol. 34, No. 6, pp. 1957-1961. https://doi.org/10.1016/S0043-1354(99)00328-0
  6. Han, R., Zoua, L., Zhaoc, X., Xua, Y., Xua, F., Lia, Y. and Wanga, Y. (2009), Characterization and properties of iron oxidecoated zeolite as adsorbent for removal of copper(II) from solution in fixed bed column, Chemical Engineering Journal, Vol. 149, No. 1-3, pp. 123-131. https://doi.org/10.1016/j.cej.2008.10.015
  7. Kim, E. H., Rhee, S. S., Lee, G. H., Kim, Y. W., Park, J. B. and Oh, M. H. (2011), Assessment of the sorption characteristics of cadmium onto steel-making slag in simulated sea water using batch experiment, Journal of the Korean Geotechnical Society, Vol. 27, No. 4, pp. 43-50 (in Korean). https://doi.org/10.7843/kgs.2011.27.4.043
  8. Kim, S. K., Chung, H. I., Yu, J. and Chang, W. S. (2005), Study on absorption of heavy-metals and organic-materials for utilizing atomizing-slag to media of reactive barrier, The Proceedings of Korean Society of Civil Engineers Conference 2005, pp. 2816-2819 (in Korean).
  9. Koon, J. and Kaufman, W. (2010), Ammonia removal from municipal wastewaters by ion exchange, Water Environmental Federation, Vol. 47, No. 3, Part 1, pp. 448-465.
  10. Lee, G. H., Kim, E. H., Park, J. B. and Oh, M. H. (2011), Estimation of the removal capacity for cadmium and calculation of minimum reaction time of BOF slag, Journal of the Korean Geotechnical Society, Vol. 27, No. 10, pp. 5-12 (in Korean). https://doi.org/10.7843/kgs.2011.27.10.005
  11. Lee, S. H., Lee, K. H. and Park, J. B. (2006), Simultaneous Removal of Cd and Cr(VI) Using Fe-Loaded Zeolite, Journal of Environmental Engineering, Vol. 132, No. 4, pp. 445-450. https://doi.org/10.1061/(ASCE)0733-9372(2006)132:4(445)
  12. Lewis, G, P., Jusko, W. J. and Coughlin, L. L. (1972), Cadmium accumulation in man: influence of smoking occupation alcoholic habit and disease, Journal of Chronic Diseases, Vol. 25, No. 12, pp. 717-726. https://doi.org/10.1016/0021-9681(72)90007-0
  13. Park, D. H., Lim, S. R., Lee, H. W. and Park, J. M. (2008), Mechanism and kinetics of Cr(VI) reduction by waste slag generated from iron making industry, Hydrometallurgy, Vol. 93, No. 1-2, pp. 72-75. https://doi.org/10.1016/j.hydromet.2008.03.003
  14. Park, J. B., Lee, S. H. and Lee, C. Y. (2002), Lab scale experiments for permeable reactive barriers against contaminated groundwater with ammonium and heavy metals using clinoptilolite, Journal of Hazardous Materials, Vol. 95, No. 1-2, pp. 65-9. https://doi.org/10.1016/S0304-3894(02)00007-9
  15. Park, K. S., Kim, H. S. and Chun, H. D. (2006), Application of steel-making (BOF) slag for in-situ remediation of subaqueous contaminated sediments, Korean National Committee on Irrigation and Drainage Journal, Vol. 13, No. 2, pp. 310-322 (in Korean).
  16. Weng, C. H. and Huang, C. P. (1994), Treatment of metal industrial waste water by fly ash and cement fixation, Journal of Environmental Engineering, Vol. 120, No. 6, pp. 1470-1487. https://doi.org/10.1061/(ASCE)0733-9372(1994)120:6(1470)
  17. Westerhoff, P. (2003), Reduction of nitrate, bromate, and chlorate by zero valent iron (Fe0), Journal of Environmental Engineering, ASCE, Vol. 29, No. 1, pp. 10-162.
  18. Yongjie, X., Haobo, H. and Shujing, Z. (2009), Characteristics and mechanism of phosphate adsorption onto basic oxygen furnace slag, Journal of Hazardous Materials, Vol. 162, No. 2-3, pp. 973-980. https://doi.org/10.1016/j.jhazmat.2008.05.131