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Electrochemical Corrosion Properties of Amorphous Co-Nb-B Alloys Prepared by Melt-Spinning Method

액체급냉법에 의해 제조한 비정질 Co-Nb-B 합금의 전기화학적 부식 특성

  • Kim, Eun-Sun (Department of Physics Education, Chosun University) ;
  • Kim, Hyun-Goo (Department of Physics Education, Chosun University) ;
  • Jang, HeeJin (Department of Metallurgical and Materials Engineering, Chosun University)
  • Received : 2014.07.21
  • Accepted : 2014.08.28
  • Published : 2014.08.31

Abstract

This study was undertaken to examine the electrochemical corrosion properties of an $Co_{80}Nb_{10}B_{10}$ and $Co_{82}Nb_8B_{10}$ amorphous alloys prepared by melt-spinning method under various conditions. The potentiodynamic polarization responses at various levels of pH (pH 2, pH 7, pH 12) showed that the corrosion current rate of $Co_{80}Nb_{10}B_{10}$ alloy is lower than that of $Co_{82}Nb_8B_{10}$ alloy in all levels of pH, implying the general corrosion resistance of the alloy with higher Nb content is better than that with higher Co content. The pitting potential of $Co_{80}Nb_{10}B_{10}$ alloy was also better than that of $Co_{82}Nb_8B_{10}$, evidenced by the higher pitting potential. Nb is thought to be effective in increasing the protectiveness of the passive film and hence to improve the corrosion resistance of Co-Nb-B alloys.

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