한국섬유공학회지 (Textile Science and Engineering)

  • 제51권4호
  • /
  • Pages.159-167
  • /
  • 2014
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지
DOI QR코드

DOI QR Code

여러 가지 수용액에서의 폴리아크릴로니트릴 필름의 팽윤이 히드라진과의 반응에 미치는 영향

Effects of the Swelling of Polyacrylonitrile Films in Various Aqueous Solutions on Their Reaction with Hydrazine

  • 박흥수 (숭실대학교 유기신소재.파이버공학과) ;
  • 김영호 (숭실대학교 유기신소재.파이버공학과)
  • Park, Heung Su (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Kim, Young Ho (Department of Organic Materials and Fiber Engineering, Soongsil University)
  • 투고 : 2014.07.01
  • 심사 : 2014.07.30
  • 발행 : 2014.08.31
⟨ 이전 논문 다음 논문 ⟩

초록

Swelling behaviors of polyacrylonitrile (PAN) films in various aqueous solutions, such as N,N'-dimethylformamide (DMF)/water, N,N'-dimethylacetamide (DMAc)/water, dimethylsulfoxide (DMSO)/water, NaSCN or KSCN solution, the effects of the concentrations of these solutions, and the effects of swelling temperature and time on the degree of swelling of PAN films were analyzed. Among the various aqueous solutions, DMF and NaSCN solution were found to be effective for high swelling of PAN films. High swelling of PAN films in the hydrazine solutions wherein aqueous, organic solvents or salt solutions were used as solvents for hydrazine, resulted in higher absorption of hydrazine and a high degree of cross-linking. Analysis of the bands of FT-IR spectra and the cyclization peaks of DSC curves for various hydrazine-treated PAN films showed that the effective cross-linking of PAN films at the same hydrazine concentration was obtained by using DMF/water or NaSCN/water solutions as solvents for hydrazine and treating medium for PAN films.

키워드

참고문헌

  1. A. D. Litmanovich and N. A. Plate, "Alkaline Hydrolysis of Polyacrylonitrile. On the Reaction Mechanism", Macromol Chem Phys, 2000, 201, 2176-2180. https://doi.org/10.1002/1521-3935(20001101)201:16<2176::AID-MACP2176>3.0.CO;2-5
  2. M. L. Gupta, B. Gupta, W. Oppermann, and G. Jardtmann, "Surface Modification of Polyacrylonitrile Staple Fibers via Alkaline Hydrolysis for Superabsorbent Application", J Appl Polym Sci, 2004, 91, 3127-3133. https://doi.org/10.1002/app.13486
  3. Z. Han, Y. Dong, and S. Dong, "Comparative Study on the Mechanical and Thermal Properties of Two Different Modified PAN Fibers and Their Fe Complexes", Mater Design, 2010, 31, 2784-2789. https://doi.org/10.1016/j.matdes.2010.01.015
  4. P. K. Neghlania, M. Rafizadeh, and F. A. Taromi, "Preparation of Aminated-Polyacrylonitrile Nanofiber Membranes for the Adsorption of Metal Ions: Comparison with Microfibers", J Haz Mater, 2011, 186(2), 182-189. https://doi.org/10.1016/j.jhazmat.2010.10.121
  5. I. Bunia, V. Neagu, and C. Luca, "Chemical Transformations of Different Acrylic Crosslinked Polymers with Primary Amines and Some Applications of the Synthesized Compounds", React Funct Polym, 2006, 66(1), 871-883. https://doi.org/10.1016/j.reactfunctpolym.2005.12.001
  6. S. Deng, G. Yu, S. Xie, Q. Yu, J. Huang, Y. Kuwaki, and M. Iseki, "Enhanced Adsorption of Arsenate on the Aminated Fibers: Sorption Behavior and Uptake Mechanism", Langmuir, 2008, 24, 10961-10967. https://doi.org/10.1021/la8023138
  7. S. Deng and R. Bai, "Adsorption and Desorption of Humic Acid on Aminated Polyacrylonitrile Fibers", J Coll Interf Sci, 2004, 280(12), 36-43. https://doi.org/10.1016/j.jcis.2004.07.007
  8. A. M. Shoushtari, M. Zaragaran, and M. Abdouss, "Preparation and Characterization of High Efficiency Ion-Exchange Crosslinked Acrylic Fibers", J Appl Polym Sci, 2006, 101, 2202-2209. https://doi.org/10.1002/app.23465
  9. B. W. Zhang, K. Fischer, D. Bieniek, and A. Kettrup, "Synthesis of Carboxyl Group Containing Hydrazine-Modified Polyacrylonitrile Fibres and Application for the Removal of Heavy Metals", React Polym, 1994, 24(11), 49-58. https://doi.org/10.1016/0923-1137(94)90136-8
  10. J. Z. Xu, C. M. Tian, Z. G. Ma, M. Gao, H. Z. Guo, and Z. H. Yao, "Study on the Thermal Behavior and Flammability of the Modified Polyacrylonitrile Fibers", J Therm Anal Cal, 2001, 63, 501-506. https://doi.org/10.1023/A:1010181618305
  11. M. M. Iovleva, V. N. Smirnova, and G. A. Budnitskii, "The Solubility of Polyacrylonitrile", Fiber Chem, 2001, 65, 262-264.
  12. J. C. Masson, "Acrylic Fiber Technology and Applications", Dekker Inc., 1995, pp.197-257.
  13. V. F. Uryash, V. A. Maslova, I. A. Barsukov, and A. N. Mochalov, "Physicochemical Analysis of the System Polyacrylonitrile-Sodium Thiocyanate-Water in the Gel-like State", Fiber Chem, 1993, 57, 57-59.
  14. T. Godjevargova, A. Simeonova, and A. Dimov, "Adsorption of Lead and Copper on Modified Polyacrylonitrile Bead", J Appl Polym Sci, 2001, 79, 283-288. https://doi.org/10.1002/1097-4628(20010110)79:2<283::AID-APP90>3.0.CO;2-2
  15. E. C. Riqueza and A. P. Aquiar, "Synthesis of Crosslinked Copolymer Based on Acrylonitrile Containing Carboxyl and Amidrazone Group", Polym Bull, 2005, 55, 31-40. https://doi.org/10.1007/s00289-005-0412-3
  16. G. Socrates, "Infrared and Raman Characteristic Group Frequencies", John Wiley & Sons, New York, 2001, Chap.10-18.
  17. F. Lian, J. Liu, Y. Xue, Z. Ma, and J. Liang, "The Demonstration of a Dense and Stable Circumferential Layer in the Subsurface of Polyacrylonitrile Fibers for the Carbon Fibers", Fiber Polym, 2013, 14, 243-249. https://doi.org/10.1007/s12221-013-0243-z
  18. C. Xu, J. Du, L. Ma, G. Li, M. Tao, and W. Zhang, "Tertiary Amine Functionalized Polyacrylonitrile Fiber Catalyst for the Synthesis of Tetrahydrothiophenes", Tetrahedron, 2013, 69, 4749-4757. https://doi.org/10.1016/j.tet.2013.02.084
  19. B. Wang, S. Xiao, W. Cao, X. Shi, and L. Xu, "Evolution of Aggregation Structure of Polyacrylonitrile Fibers in the Cyclization Reaction", J Appl Polym Sci, 2012, 124(4), 3413-3418. https://doi.org/10.1002/app.35361