Journal of the Korean Solar Energy Society (한국태양에너지학회 논문집)

The Korean Solar Energy Society (한국태양에너지학회)
권호 표지
DOI QR코드

DOI QR Code

SIMS Investigation of Black Cr Solar Selective Coatings

Black Cr 태양 선택흡수막의 SIMS 연구

  • Received : 2014.04.07
  • Accepted : 2014.07.28
  • Published : 2014.08.30
Download PDF
⟨ Previous Next ⟩

Abstract

The elemental composition of electro-deposited black Cr solar selective coatings before and after heating in air by using secondary ion mass spectrometry (SIMS) was investigated for optical property analysis. In addition, black Cr selective coating exposed by solar radiation for 5 months was compared with heated sample. SIMS investigation shows that $OH^+$ bearing ions were related to a near surface region of CrOH and CrO compound. The optical degradation of this coating after heating at $500^{\circ}C$ reveals that diffusion of the Cu and Ni elements in substrate material, the chemical interactions adjacent to the interface, and the interface width broadening.

Keywords

References

  1. G. B. Smith, G. Zajac, A. IgnatievandJ. W. Rabalais, Surface composition of selective black chrome films as determined by sims, Surface Science 114, pp. 614-626, 1981
  2. N. Selvakumar and H. C. Barshilia, Review of physical vapor deposited(PVD) spectrally selective coatings for mid-and high-temperature solar thermal applications, Solar Energy Materials and Solar Cells 98, pp. 1-23, 2012 https://doi.org/10.1016/j.solmat.2011.10.028
  3. H. C. Barshilia, N. Selvakumar, K. S. Rajam and A. Biswas, Structure and optical properties of pulsed sputter deposited $Cr_xO_y/Cr/Cr_2O_3$ solar selective coatings, Journal of Applied Physiscs 103, 023507-1-023507-11, 2008 https://doi.org/10.1063/1.2831364
  4. G. Zajac, G. B. Smith and A. Ignatiev, Refinment of solar absorbing black chrome microstructure and its relationship to optical degradation mechanism, Journal of Applied Physiscs 51, pp. 5544-5554, 1980 https://doi.org/10.1063/1.327475
  5. S. Khamlich, O. Nemraoui, N. Mongwaketsi, R. McCrindle, N. Cingo and M. Maaza, Black $Cr/{\alpha}-Cr_2O_3$ nanoparticles based solar absorbers, Physica B 407, pp. 1509-1512, 2012 https://doi.org/10.1016/j.physb.2011.09.073
  6. S. Eugenio, C. M. Rangel, R. Vilar, A. M. and Botelho do Rego, Eledepostion of black chromium spectrally selective coating from Cr(111)-ionic liquid solution, Thin Solid Films 519, pp. 1845-1850, 2011 https://doi.org/10.1016/j.tsf.2010.10.029
  7. J. A. Duffie and W. A, Beckman, Solar Engineering of Thermal Processes, 2nd Edition, Wiley-Interscience, New York, 1991
  8. K. D. Lee, Property analysis of solar selective coatings, Journal of the Solar Energy Society 33, pp. 31-38, 2013 https://doi.org/10.7836/kses.2013.33.4.031