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CaWO4:Sm3+ 형광체의 합성과 발광특성

Luminescent Characteristics and Synthesis of Sm3+-Doped CaWO4 Phosphors

  • 류종항 (동의대학교 물리학과) ;
  • 윤소진 (동의대학교 물리학과) ;
  • 유일 (동의대학교 물리학과)
  • Ryu, Jong-Hang (Department of Physics, Dong-Eui University) ;
  • Yoon, So-Jin (Department of Physics, Dong-Eui University) ;
  • Yu, Il (Department of Physics, Dong-Eui University)
  • 투고 : 2014.04.09
  • 심사 : 2014.06.05
  • 발행 : 2014.07.27

초록

$CaWO_4:Sm_x$(x = 0, 0.5, 1.0, 1.5, 2.0 mol%) white phosphors with different concentrations of $Sm^{3+}$ ions were synthesized using the hydrothermal method. The crystal structure, surface, and optical properties of the $CaWO_4:Sm_x$ phosphors were investigated using X-ray diffraction(XRD), field-emission scanning electron microscopy(FE-SEM), photoluminescence(PL) and photoluminescence excitation(PLE). From the XRD results, the crystal structure of the $CaWO_4:Sm$ phosphors was found to be tetragonal. The $CaWO_4:Sm$ phosphors became more cohesive with increasing $Sm^{3+}$-ion concentration. The photoluminescence excitation(PLE) peak of the phosphors, at around 250 nm, was ascribed to the transition from the 1A1 ground-state to the high-vibration level of 1T2 in the $WO{_4}^{2-}$ complex. The maximum emission spectra of the phosphors were observed when the $Sm^{3+}$ concentration was 0.5 mol%. The luminescence intensity of the $CaWO_4$ phosphors was decreased for $Sm^{3+}$ concentrations greater than 0.5 mol%.

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참고문헌

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