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EFFECTS OF TEMPERING AND PWHT ON MICROSTRUCTURES AND MECHANICAL PROPERTIES OF SA508 GR.4N STEEL

  • Received : 2013.10.07
  • Accepted : 2014.01.08
  • Published : 2014.06.25

Abstract

Presented in this study are the variations of microstructures and mechanical properties with tempering and Post-Weld Heat Treatment (PWHT) conditions for SA508 Gr.4N steel used as Reactor Pressure Vessel (RPV) material. The blocks of model alloy were austenitized at the conventional temperature of $880^{\circ}C$ then tempered and post-weld heat treated at four different conditions. The hardness and yield strength decrease with increased tempering and PWHT temperatures, but impact toughness is significantly improved, especially in the specimens tempered at $630^{\circ}C$. The sample tempered at $630^{\circ}C$ with PWHT at $610^{\circ}C$ shows optimum mechanical properties in hardness, strength, and toughness, excluding only the transition property in the low temperature region. The microstructural observation and quantitative analysis of carbide size distribution show that the variations of mechanical properties are caused by the under-tempering and carbide coarsening which occurred during the heat treatment process. The introduction of PWHT results in the deterioration of the ductile-brittle transition property by an increase of coarse carbides controlling cleavage initiation, especially in the tempered state at $630^{\circ}C$.

Keywords

References

  1. Y.R. Im, Y.J. Oh, B.J. Lee, J.H. Hong and H.C. Lee, "Effects of carbide precipitation on the strength and Charpy impact properties of low carbon Mn-Ni-Mo bainitic steels," J. Nucl. Mater. 297, pp. 138-148 (2001). https://doi.org/10.1016/S0022-3115(01)00610-9
  2. K. Suzuki, "Neutron irradiation embrittlement of ASME SA508, C1.3 steel," J. Nucl. Mater. 108 & 109, pp. 443-450 (1982).
  3. Y.S. Ahn, H.D. Kim, T.S. Byun, Y.J. Oh, G.M. Kim and J.H. Hong, "Application of intercritical heat treatment to improve toughness of SA508 Cl.3 reactor pressure vessel steel," Nucl. Eng. Des. 194, pp. 161-167 (1999). https://doi.org/10.1016/S0029-5493(99)00196-X
  4. Y.S. Ahn, Y.J. Oh, G.M. Kim and J.H. Hong, "Change of microstructure and mechanical properties in Mn-Mo-Ni low alloy steel with respect to intercritical heat treatment conditions," J. Kor. Inst. Met. & Mater. 38, pp. 1309-1316 (2000).
  5. B.S. Lee, M.C. Kim, J.H. Yoon and J.H. Hong, "Characterization of high strength and high toughness Ni-Mo-Cr low alloy steels for nuclear application," Int. J. Press. Ves. & Pip. 87, pp. 74-80 (2010). https://doi.org/10.1016/j.ijpvp.2009.11.001
  6. K.H. Lee, S.G. Park, M.C. Kim, B.S. Lee and D.M. Wee, "Characterization of transition behavior in SA508 Gr.4N Ni-Cr-Mo low alloy steels with microstructural alteration by Ni and Cr contents," Mater. Sci. Eng. A 529, pp. 156-163 (2011). https://doi.org/10.1016/j.msea.2011.09.012
  7. K.H. Lee, S.G. Park, M.C. Kim and B.S. Lee, "Cleavage fracture toughness of tempered martensitic Ni-Cr-Mo low alloy steel with different martensite fraction," Mater. Sci. Eng. A 534, pp. 75-82 (2012). https://doi.org/10.1016/j.msea.2011.11.043
  8. S.G. Park, M.C. Kim, B.S. Lee and D.M. Wee, "Correlation on the thermodynamic calculation and the experimental observation of Ni-Mo-Cr low alloy steel changing Ni, Mo, and Cr contents," J. Nucl. Mater. 407, pp. 126-135 (2010). https://doi.org/10.1016/j.jnucmat.2010.09.004
  9. ASME boiler & pressure vessel code, Section II-Materials, part A-Ferrous material specifications, American Society of Mechanical Engineers (2013).
  10. Z. Sterjovski, D.P. Dunne and S. Ambrose, "Evaluation of cross-weld properties of quenched and tempered pressure vessel steel before and after PWHT," Int. J. Pres. Ves. & Pip. 81, pp. 465-470 (2004). https://doi.org/10.1016/j.ijpvp.2003.12.007
  11. C.C. Wang and Y. Chang, "Effect of postweld treatment on the fatigue growth rate of electron-beam-welded AISI 4130 steel," Metall. Mater. Trans. A 27A, pp. 3162-3169 (1996).
  12. G. Nicoletto, "Fatigue crack growth in multi-pass butt-welded joints of mild steel," Int. J. Pres. Ves. & Pip. 42, pp. 363-378 (1990). https://doi.org/10.1016/0308-0161(90)90033-E
  13. S.I. Kwun and R.A. Fournelle, "Fatigue crack initiation and propagation in a quenched and tempered niobium bearing HSLA steel," Metall. Mater. Trans. A 38, pp. 575-580 (1982).
  14. ASTM A508/A508M-05b, "Standard specification for quenched and tempered vacuum-treated carbon and alloy steel forgings for pressure vessels," American Society for Testing and Materials (2005).
  15. ASTM E8M-08, "Standard test methods for tension testing metallic materials," American Society for Testing and Materials (2008).
  16. ASTM E23-07a, "Standard methods for notched bar impact testing of metallic materials," American Society for Testing and Materials (2007).
  17. W. Oldfield, "Fitting impact test data-a statistical procedure," ASTM Standardizations News, pp. 24 (1975)
  18. S.Y. Shin, B.C. Hwang, S.H. Lee, N.J. Kim and S.S. Ahn, "Correlation of microstructure and charpy impact properties in API X70 and X80 line-pipe steels," Mater. Sci. Eng. A 458, pp. 281-289 (2007) https://doi.org/10.1016/j.msea.2006.12.097
  19. ASTM E1921-09c, "Standard test method for determination of reference temperature, T0, for ferritic steels in the transition range," American Society for Testing and Materials (2009).
  20. S.D. Funni, M.G. Koul and A.L. Moran, "Evaluation of properties and microstructure as a function of tempering time at intercritical temperatures in HY-80 steel castings." Eng. Fail. Anal. 14, pp. 753-764 (2007). https://doi.org/10.1016/j.engfailanal.2006.11.029
  21. K.H. Lee, M.C. Kim, W.J. Yang and B.S. Lee, "Evaluation of microstructural parameters controlling cleavage fracture toughness in Mn-Mo-Ni low alloy steels," Mater. Sci. Eng. A 565, pp. 158-164 (2013). https://doi.org/10.1016/j.msea.2012.12.024
  22. S. Lee, S. Kim, B. Hwang, B.S. Lee and C.G. Lee, "Effect of carbide distribution on the fracture toughness in the transition temperature region of an SA508 steel," Acta Mater. 50, pp. 4755-4762 (2002) https://doi.org/10.1016/S1359-6454(02)00313-0
  23. Z. Zhang, D. Delagnes and G. Bernhart, "Microstructure evolution of hot-work tool steels during tempering and definition of a kinetic law based on hardness measurements," Mater. Sci. Eng. A 380, pp. 222-230 (2004). https://doi.org/10.1016/j.msea.2004.03.067
  24. J.H. Chen, G.Z. Wang and H. Ma, "Fracture behavior of C-Mn steel and weld metal in notched and precracked specimens: Part II. micromechanism of fracture," Metall. Mater. Trans. A 21A, pp. 321-330 (2000).
  25. W.J. Yang, M.H. Huh, S.J. Roh, B.S. Lee, Y.J. Oh and J.H. Hong, "The effects of the local fracture stress and carbides on the cleavage fracture characteristics of Mn-Mo-Ni low alloy steels in the transition region," J. Kor. Inst. Met. & Mater. 38, pp. 675-680 (2000).
  26. F.B. Pickering and T. Gladman, "Metallurgical developments in carbon steels," Iron Steel Inst. Spec. Rep. 81 pp. 10-20 (1963).
  27. S.F. Iradj and K. Wallin, SKI (Swedish Nuclear Power Inspectorate) Report 2005, Vol. 55, Sweden, Stockholm (2005).

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