Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Effect of TiO2 on the Color Generation in Celadon Glaze

산화티타늄이 청자유약의 발색에 끼치는 영향에 관한 연구

  • Received : 2014.01.22
  • Accepted : 2014.02.18
  • Published : 2014.05.31
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Abstract

In aprevious study, the mutual interaction between $Fe_2O_3$ and $TiO_2$ was found to influence the color of celadon glaze. Celadon samples were prepared with varying concentrations of $TiO_2$ at a fixed level of $Fe_2O_3$. The electronic states of Fe and Ti were analyzed by M$\ddot{o}$ssbauer spectroscopy and electron spin-resonance spectroscopy, respectively. These results were examined with the celadon colors measured according to CIELAB values. This study revealed that an increase of $Ti^{3+}$ in the glassy phase decreased the $Fe^{2+}/Fe^{3+}$ ratio, resulting in a color change of the celadon samples in the GY and Y groups. The maximum reflectance wavelength was shifted from 505 nm to 610 nm with an increase in the $TiO_2$ concentration.

Keywords

References

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