DOI QR코드

DOI QR Code

Surface Modification Method of Stainless Steel using Electrochemical Etching

전기화학적 에칭을 이용한 스테인리스 스틸의 표면 개질

  • Lee, Chan (Department of Mechanical Engineering, POSTECH) ;
  • Kim, Joonwon (Department of Mechanical Engineering, POSTECH)
  • 이찬 (포항공과대학교 기계공학과) ;
  • 김준원 (포항공과대학교 기계공학과)
  • Received : 2013.12.30
  • Accepted : 2014.02.28
  • Published : 2014.04.01

Abstract

This paper reports a simple, yet effective 1-step surface modification method for stainless steel. Electrochemical etching in dilute Aqua Regia forms hierarchical micro and nanoscale structure on the surface. The surface becomes highly hydrophobic (${\sim}150^{\circ}$) as a result of the etching in terms of static contact angle (CA). However the liquid drops easily pinned on the surface because of high contact angle hysteresis (CAH), which is called a "petal effect": The petal effect occur because of gap between surface microstructures, despite of intrinsic hydrophobicity of the base material. The pore size and period of surface structure can be controlled by applied voltage during the etching. This method can be applied to wide variety of industrial demand for surface modification, while maintaining the advantageous anti-corrosion property of stainless steel.

Keywords

References

  1. Quere, D., "Wetting and Roughness," Annual Rev iew of Materials Research, Vol. 38, pp. 71-99, 2008. https://doi.org/10.1146/annurev.matsci.38.060407.132434
  2. Kwok, D. Y. and Neumann, A. W., "Contact An gle Measurement and Contact Angle Interpretation," Advances in Colloid and Interface Science, Vol. 81, No. 3, pp. 167-249, 1999. https://doi.org/10.1016/S0001-8686(98)00087-6
  3. Kim, D., Kim, J., Park, H. C., Lee, K., and Hw ang, W., "A Superhydrophobic Dual-Scale Engine ered Lotus Leaf," Journal of Micromechanics and Microengineering, Vol. 18, No. 1, Paper No. 01 5019, 2008.
  4. Kim, H. and Kim, J., "Evaporation Characteristics of a Hydrophilic Surface with Micro-Scale and/o r Nano-Scale Structures Fabricated by Sandblastin g and Aluminum Anodization," Journal of Micro mechanics and Microengineering, Vol. 20, No. 4, Paper No. 045008, 2010.
  5. Ahn, H. S., Lee, C., Kim, J., and Kim, M. H., "The Effect of Capillary Wicking Action of Micr o/Nano Structures on Pool Boiling Critical Heat Flux," International Journal of Heat and Mass Transfer, Vol. 55, No. 1-3, pp. 89-92, 2012. https://doi.org/10.1016/j.ijheatmasstransfer.2011.08.044
  6. Yewang, S., Baohua, J., Yonggang, H., and Kehchih, H., "Nature's Design of Hierarchical Superh ydrophobic Surfaces of a Water Strider for Low Adhesion and Low-Energy Dissipation," Langmuir, Vol. 26, No. 24, pp. 18926-18937, 2010. https://doi.org/10.1021/la103442b
  7. Kota, A. K., Li, Y., Mabry, J. M., and Tuteja, A., "Hierarchically Structured Superoleophobic Su rfaces with Ultralow Contact Angle Hysteresis", Advanced Materials, Vol. 24, No. 43, pp. 5838-5843, 2012. https://doi.org/10.1002/adma.201202554
  8. Feng, L., Zhang, Y., Xi, J., Zhu, Y., Wang, N., Xia, F., and Jiang, L., "Petal Effect: A Superhydr ophobic State with High Adhesive Force," Langmuir, Vol. 24, No. 8, pp. 4114-4119, 2008. https://doi.org/10.1021/la703821h
  9. Bhushan, B. and Nosonovsky, M., "The Rose Pet al Effect and the Modes of Superhydrophobicity," Philosophical Transactions A, Vol. 368, No. 1929, pp. 4713-4728, 2010. https://doi.org/10.1098/rsta.2010.0203
  10. Guo, Z. G. and Liu, W. M., "Sticky Superhydrop hobic Surface," Applied Physics Letters, Vol. 90, No. 22, Paper No. 223111, 2007.
  11. Li, A. P., Muller, F., Birner, A., Nielsch, K., and Gosele, U., "Hexagonal Pore Arrays with a 50-4 20 nm Interpore Distance Formed by Self-Organi zation in Anodic Alumina," Journal of Applied P hysics, Vol. 84, No. 11, pp. 6023-6026, 1998. https://doi.org/10.1063/1.368911
  12. Su, Z. and Zhou, W., "Pore Diameter Control in Anodic Titanium and Aluminium Oxides," Journal of Materials Chemistry, Vol. 21, No. 2, pp. 357-362, 2011. https://doi.org/10.1039/c0jm02521f

Cited by

  1. Oil Retention Experiments and Evaluations for Electrochemically Etched Porous Stainless Steel Surface vol.31, pp.12, 2014, https://doi.org/10.7736/KSPE.2014.31.12.1171
  2. Surface treatment of stainless steel by electrolytic oxidation and deposition of titanium complexing ion solution to improve metal-ceramic adhesion vol.31, pp.23, 2017, https://doi.org/10.1080/01694243.2017.1310694