Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
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Electrochemical Behavior of TiO2 Nanotube/Ti Prepared by Anodizing for Micro-Lithium Ion Batteries

  • Received : 2013.09.09
  • Accepted : 2013.12.15
  • Published : 2014.02.28
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Abstract

The $TiO_2$ nanotube/Ti electrode are used as an anode in thin-film lithium microbatteries is known to have high oxidation-reduction potential of 1.8 V (vs. $Li/Li^+$). It can prevent from dendrite growth of lithium during charging. The $TiO_2$ nanotube/Ti electrode was prepared by anodizing at constant voltages for thin-film lithium microbatteries. The capacities of $TiO_2$ nanotube/Ti anode prepared by anodizing at 10 V, 20 V and 30 V were observed to be $23.9{\mu}Ah\;cm^{-2}$, $43.1{\mu}Ah\;cm^{-2}$ and $74.0{\mu}Ah\;cm^{-2}$. We identified it was found that the capacity of $TiO_2$ nanotube/Ti increases with increasing anodizing voltage and the anatase structure of $TiO_2$ nanotube/Ti compared with amorphous structure has batter cycle performance than amorphous $TiO_2$ nanotube/Ti.

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References

  1. P. G. Bruce, B. Scrosati, J. M. Tarascon, 'Nanomaterials for Rechargeable Lithium Batteries', Angew. Chem., Int. Ed., 47, 2930 (2008). https://doi.org/10.1002/anie.200702505
  2. J. B. Bates, G. R. Gruzalski, N. J. Dudney, C. F. Luck, X. Yu, 'Rechargeable thin-film lithium batteries', Solid State Ionics, 71, 619 (1994).
  3. K. H. Hwang, S. H. Lee, S. K, Joo, 'Fabrication and characterization of LiMnO thin-film cathode for rechargeable lithium microbatteries', J. Power Sources, 54, 224 (1995). https://doi.org/10.1016/0378-7753(94)02072-B
  4. K. Kushida, K. Kuriyama, T. Nozaki, 'Hundred-micronsized all-solid-state Li secondary battery arrays embedded in a Si substrate', Appl. Phys. Lett., 81, 5066 (2002). https://doi.org/10.1063/1.1531220
  5. J. B. Bates, N. J. Dudney, D. C. Lubben, G. R. Gruzalski, B. S. Kwak, X. Yu, R. A. Zuhr, 'Thin-film rechargeable lithium batteries', J. Power Sources, 54, 58 (1995). https://doi.org/10.1016/0378-7753(94)02040-A
  6. K. S. Han, P. Krtil, M. Yoshimura, 'Soft solution processing for fabrication of lithiated thin-film electrodes in a single synthetic step', J. Mater. Chem., 8, 2043 (1998). https://doi.org/10.1039/a804791j
  7. J. M. Macak, S. Albu, D. H. Kim, I. Paramasivam, S. Aldabergerova, P. Schmuki, 'Multilayer $TiO_2$-Nanotube Formation by Two-Step Anodization', Electrochemical and Solid-state Letters, 10, K28 (2007). https://doi.org/10.1149/1.2737544
  8. J. M. Macak, H. Tsuchiya, P. Schmuki, 'High-Aspect-Ratio $TiO_2$ Nanotubes by Anodization of Titanium', Angew. Chem., Int. Ed., 44, 2100 (2005). https://doi.org/10.1002/anie.200462459
  9. S. P. Albu, A. Ghicov, J. M. Macak, R. Hahn, P. Schmuki, 'Self-organized, free-standing $TiO_2$ nanotube membrane for flow-through photocatalytic applications', Nano Lett., 7, 1286 (2007). https://doi.org/10.1021/nl070264k
  10. G. K. Mor, K. Shankar,M. Paulose, O. K. Varghese, C. A. Grimes, 'Use of Highly-Ordered $TiO_2$ Nanotube Arrays in Dye-Sensitized Solar Cells', Nano Lett., 6, 215 (2006). https://doi.org/10.1021/nl052099j
  11. Z. Wei, Y. Yao, T. Huang, A. Yu, 'Solvothermal Growth of Well-Aligned $TiO_2$ Nanowire Arrays for Dye-Sensitized Solar Cell: Dependence of Morphology and Vertical Orientation Upon Substrate Pretreatment', Int. J. Electrochem. Sci., 6, 1871 (2011).
  12. H. Furukawa, M. Hibino, I. Honma, 'Electrochemical Properties of Nanostructured Amorphous, Sol-gel-Synthesized $TiO_2$/Acetylene Black Composite Electrodes', J. Electrochem. Soc., 151 A527 (2004). https://doi.org/10.1149/1.1649747
  13. H. Yamada, T. Yamato, I. Moriguchi, T. Kudo, 'Porous $TiO_2$ (anatase) Electrodes for High-Power Batteries', Chem. Lett., 33 1548 (2004). https://doi.org/10.1246/cl.2004.1548
  14. Z. Y. Wang, S. Z. Liu, G. Chen, D. G. Xia, 'Preparation and Li-Intercalation Properties of Mesoporous Anatase-$TiO_2$ Sphere', Electrochem. Solid-State Lett., 10, A77 (2007). https://doi.org/10.1149/1.2430567
  15. A. Hagfeldt, N. Vlachopoulos, M. Gratzel, 'Fast electrochromic switching with nanocrystalline oxide semiconductor films', J. Electrochem. Soc., 141, L82 (1994). https://doi.org/10.1149/1.2055045

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