한국산학기술학회논문지 (Journal of the Korea Academia-Industrial cooperation Society)

  • 제15권1호
  • /
  • Pages.39-46
  • /
  • 2014
  • /
  • 1975-4701(pISSN)
  • /
  • 2288-4688(eISSN)
한국산학기술학회 (The Korea Academia-Industrial cooperation Society)
권호 표지
DOI QR코드

DOI QR Code

미얀마와 타산지 녹색 투어말린의 특성비교 분석

Characteristic comparison analysis of the green tourmalines from Myanmar and other deposits

  • 김경진 (공주대학교 예술대학 조형디자인학부) ;
  • 정재민 (공주대학교 예술대학 조형디자인학부) ;
  • 안용길 (한양대학교 공과대학 신소재공학부)
  • Kim, Kyung-Jin (Division of Crafts Design, Kongju National University) ;
  • Chung, Chae-Min (Division of Crafts Design, Kongju National University) ;
  • Ahn, Yong-Kil (Department of Materials Science and Engineering, Hanyang University)
  • 투고 : 2013.12.06
  • 심사 : 2014.01.09
  • 발행 : 2014.01.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

미얀마 Kayah산 녹색 투어말린의 특성을 X-선 형광분석, 자외선-가시광선 그리고 중적외선 분광분석을 통하여 타산지의 녹색 투어말린과 비교하였다. 화학성분 분류에 의해 미얀마 투어말린이 속한 그룹을 조사 하였다. 미얀마 투어말린은 V 원소를 많이 함유하고 있었고 X 사이트에 Ca 원소를 반 이상 함유한 Calcic 그룹에 속했고 우바이트 (Uvite)로 명명되었다. 자외선-가시광선 분석결과 $V^{3+}$ 이온에 의한 415와 611 nm에 강한 흡수밴드가 나타나 녹색 투어말린의 원인이 되었다. $Fe^{2+}$ 이나 $Cu^{2+}$ 이온에 의해 녹색이 나타나는 타산지의 녹색 투어말린과 차이가 있었다. 중적외선 분석에서는 수산기와 금속들 간의 진동에 의한 흡수가 일어났는데 1100 $cm^{-1}$ 근처에서 스트레칭 모드, 3500 $cm^{-1}$ 주변에서 벤딩 모드 그리고 4600과 4200 $cm^{-1}$ 사이에서 스트레칭과 벤딩 모드의 혼합 밴드가 나타났다.

The green tourmalines from Kayah state, Myanmar were investigated by WD X-ray fluorescence, UV-vis, and mid-infrared spectroscopy for comparison to tourmalines of other deposits. The group of tourmaline was calculated and classified by chemical analysis. The samples belonged to the Calcic group and Uvite. The green tourmalines showed a strong absorption band at 415 and 611 nm. The presence of $V^{3+}$ ions is responsible for these absorption bands. Combination of the stretching and bending mode by the vibration between cationic and hydroxyl units (metal-OH) are observed in the 4600 ~ 4200 $cm^{-1}$.

키워드

참고문헌

  1. C. Castaneda, E. F. Oliveira, N. Gomes, A. C. P. Soares, "Infrared study of OH sites in tourmaline from the elbaite-schorl series", Am. Mineral., 85, pp. 1503-1507, 2000. https://doi.org/10.2138/am-2000-1021
  2. K. krambrock, M.V.B. Pinheiro, S.M. Medeiros, K.J. Guedes, S. Schweizer, J.M. Spaeth, "Investigation of radiation-induced yellow color in tourmaline by magnetic resonance", Nucl. Instrum. Methods B 191, pp. 241-245, 2002. DOI: http://dx.doi.org/10.1016/S0168-583X(02)00568-2
  3. Y.K. Ahn, J.G. Seo, J.W. Park, "Electronic and vibrational spectra of tourmaline - The impact of electron beam irradiation and heat treatment" Vib. Spectrosc., 65, pp. 165-175, 2013. DOI: http://dx.doi.org/10.1016/j.vibspec.2013.01.002
  4. A. Socquet, M. Pubellier, "Cenozoic deformation in western Yunnan (China-Myanmar border)', J. of Asian Earth Science, 24, pp .495-515, 2005. https://doi.org/10.1016/j.jseaes.2004.03.006
  5. M. P. Searle, S. R. Noble, J. M. Cottle, D. J. Waters, A. H. G. Mitchell, T. Hlaing, M. S. A. Horstwood, "Tectonic evolution of the Mogok metamorphic belt, Burma(myanmar) constrained by U-Th-Pb dating of metamorphic and magmatic rocks", Tectonics, 26, pp. 1-24, 2007. DOI: http://dx.doi.org/10.1029/2006TC002083
  6. Andy Tindle-Free Software, Mineral Recalculation Software http://www.open.ac.uk/earth-research/tindle/AGTWebPages/AGTSoft.html
  7. E. Boehm, Gem Newe International: Canary tourmaline from Malawi, Gems & Gemology, 27, 2, pp. 151-152, 2001.
  8. H.A. Hanni, E. Frank, G. Bosshart, "Goldemn yellow tourmaline of gem quality from Kenya', J. of Gemmology, 17, 7, pp. 437-442, 1981. https://doi.org/10.15506/JoG.1981.17.7.437
  9. M.L. Johnson, J.I. Koivula, "Gem News: Golden tourmaline from Kenya" Gems & Gemology", 32, 2, pp. 135-136, 1996.
  10. C. Simonet, "Geology of the yellow mine (Taita-Taveta District, Kenya) and other yellow tourmaline deposits in East Africa", J. of Gemmology, 27, 1, pp. 11-29, 2000. https://doi.org/10.15506/JoG.2000.27.1.11
  11. B.M. Laurs, J.C. Zwaan, C.M. Breeding, W.B. Simmons, D. Beaton, K.F. Rijsdijk, R. Befi, A.U. Falster, "Copper-bearing (Paraiba-type) tourmaline from Mozambique"' Gems & Gemology, 44, 1, pp. 4-30, 2008. DOI: http://dx.doi.org/10.5741/GEMS.44.1.4
  12. S. Lee, Y.K. Ahn, J.G. Seo, J.W. Park, "Spectrooscopic characteristics of tourmalines from Antandrokomby, Madagascar", J. Miner. Soc. Korea, 22, 4, pp. 385-393, 2009.
  13. K. Schemetzer, H. J. Bernhardt, C. Dunaigre, M. S. Krzemnicki, "Vanadium-bearing gem-quality tourmalines from Madagascar", The Gemmological Association of Great Britain, 30, 7/8, pp. 413-433, 2007.
  14. M L. .Brendan, J. C. Zwaan, M. B. Christopher, B. S. William, B. Donna, F. R. Kenneth, B. Riccardo, U. F. Alexander, Copper-bearing (Paraiba-type) tourmaline from Mozambique, Gems & Gemology, 44, 1, pp.4-30, 2008. https://doi.org/10.5741/GEMS.44.1.4
  15. B. M. Paul, M. B. Christopher, Spectral differentiation between copper and iron colorants in gem tourmalines, Gems & Gemology, 45, 2, pp.112-119, 2009. DOI: http://dx.doi.org/10.5741/GEMS.45.2.112
  16. B.N. Figgis, M.A. Hitchiman, " Ligand field theory and its applications", p.206-207, Wiley-VCH, 2000.